{"paper_id":"4e696e4f-5de8-4e1d-a0cd-3bcecf48e4f6","body_text":"Thermochemical Conversion of Bovine Fleshings into Jet Fuel-Range Hydrocarbons: Reaction Study and Proposed Mechanism | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Thermochemical Conversion of Bovine Fleshings into Jet Fuel-Range Hydrocarbons: Reaction Study and Proposed Mechanism HELVIA NANCY FUZER LIRA, Gisely Luzia Stroher, Antônio Edmilson Canesin, and 2 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-8096247/v1 This work is licensed under a CC BY 4.0 License Status: Posted Version 1 posted You are reading this latest preprint version Abstract This study investigates the thermochemical conversion of bovine fleshings, a low-value by-product of the leather industry, into hydrocarbons within the aviation fuel range. Fat extracted through wet processing was rendered and than transesterified to determine its composition. The samples were characterized and quantified by gas chromatography coupled with mass spectrometry (GC–MS), revealing a predominance of saturated and mostly monoun-saturated hydrocarbon chains. In parallel, a thermal cracking reaction was performed to determine the operational conditions required for producing hydrocarbons in the aviation kerosene range. Six fractions were evaluated, yielding approximately 70–80% bio-oil composed mainly of medium-chain alkanes and alkenes (C9–C17), along with oxygenated compounds. Fractions collected between 290–310 °C exhibited chemical profiles closely resembling commercial aviation kerosene (Jet-A). Notably, Sample 6 contained about 76% hydrocarbons in the C9–C14 range (vs. 85% in Jet-A) and 23% in the C15–C17 range (vs. 15% in Jet-A), confirming its similarity to sustainable aviation fuel (SAF). Unlike previous studies that employed refined bovine tallow or residual oils, this work utilizes fat rendered directly from fleshings as feedstock. The explicit comparison of hydrocarbon fractions with Jet-A underscores the potential of tannery residues for SAF production. Defining optimal parameters for thermal cracking demonstrated the dual benefits of waste valorization and renewable fuel generation, establishing bovine fleshings as a promising source of low-carbon aviation fuels and contributing to the diversification and sustainability of the energy matrix. Renewable Resources Bovine fleshings Waste valorization Thermochemical conversion Thermal cracking Sustainable aviation fuel (SAF) Hydrocarbons Full Text Additional Declarations The authors declare no competing interests. Supplementary Files Fig1GCMS.pdf Fig2GCMS.pdf Fig3GCMS.pdf Fig4Averagepercentagedistributionofcondensed.pdf Fig4GCMS.pdf Fig10Relativearea234.pdf Fig11Comparisonoftherelativearea56.pdf Fig12comparisonb12Jetasp6.pdf Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. 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Mechanism\\u003c/p\\u003e\",\"fulltext\":[],\"fulltextSource\":\"\",\"fullText\":\"\",\"funders\":[],\"hasAdminPriorityOnWorkflow\":false,\"hasManuscriptDocX\":false,\"hasOptedInToPreprint\":true,\"hasPassedJournalQc\":\"\",\"hasAnyPriority\":true,\"hideJournal\":true,\"highlight\":\"\",\"institution\":\"UTFPR\",\"isAcceptedByJournal\":false,\"isAuthorSuppliedPdf\":true,\"isDeskRejected\":\"\",\"isHiddenFromSearch\":false,\"isInQc\":false,\"isInWorkflow\":false,\"isPdf\":true,\"isPdfUpToDate\":true,\"isWithdrawnOrRetracted\":false,\"journal\":{\"display\":true,\"email\":\"info@researchsquare.com\",\"identity\":\"researchsquare\",\"isNatureJournal\":false,\"hasQc\":true,\"allowDirectSubmit\":true,\"externalIdentity\":\"\",\"sideBox\":\"\",\"snPcode\":\"\",\"submissionUrl\":\"/submission\",\"title\":\"Research 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Fat extracted through wet processing was rendered and than transesterified to determine its composition. The samples were characterized and quantified by gas chromatography coupled with mass spectrometry (GC–MS), revealing a predominance of saturated and mostly monoun-saturated hydrocarbon chains. In parallel, a thermal cracking reaction was performed to determine the operational conditions required for producing hydrocarbons in the aviation kerosene range. Six fractions were evaluated, yielding approximately 70–80% bio-oil composed mainly of medium-chain alkanes and alkenes (C9–C17), along with oxygenated compounds. Fractions collected between 290–310 °C exhibited chemical profiles closely resembling commercial aviation kerosene (Jet-A). Notably, Sample 6 contained about 76% hydrocarbons in the C9–C14 range (vs. 85% in Jet-A) and 23% in the C15–C17 range (vs. 15% in Jet-A), confirming its similarity to sustainable aviation fuel (SAF). Unlike previous studies that employed refined bovine tallow or residual oils, this work utilizes fat rendered directly from fleshings as feedstock. The explicit comparison of hydrocarbon fractions with Jet-A underscores the potential of tannery residues for SAF production. Defining optimal parameters for thermal cracking demonstrated the dual benefits of waste valorization and renewable fuel generation, establishing bovine fleshings as a promising source of low-carbon aviation fuels and contributing to the diversification and sustainability of the energy matrix.\\u003c/p\\u003e\",\"manuscriptTitle\":\"Thermochemical Conversion of Bovine Fleshings into Jet Fuel-Range Hydrocarbons: Reaction Study and Proposed Mechanism\",\"msid\":\"\",\"msnumber\":\"\",\"nonDraftVersions\":[{\"code\":1,\"date\":\"2025-11-13 02:18:32\",\"doi\":\"10.21203/rs.3.rs-8096247/v1\",\"editorialEvents\":[{\"type\":\"communityComments\",\"content\":0}],\"status\":\"published\",\"journal\":{\"display\":true,\"email\":\"info@researchsquare.com\",\"identity\":\"researchsquare\",\"isNatureJournal\":false,\"hasQc\":true,\"allowDirectSubmit\":true,\"externalIdentity\":\"\",\"sideBox\":\"\",\"snPcode\":\"\",\"submissionUrl\":\"/submission\",\"title\":\"Research Square\",\"twitterHandle\":\"researchsquare\",\"acdcEnabled\":true,\"dfaEnabled\":false,\"editorialSystem\":\"\",\"reportingPortfolio\":\"\",\"inReviewEnabled\":false,\"inReviewRevisionsEnabled\":true}}],\"origin\":\"\",\"ownerIdentity\":\"3a23dd67-7500-4538-9193-d99a55d1657d\",\"owner\":[],\"postedDate\":\"November 13th, 2025\",\"published\":true,\"recentEditorialEvents\":[],\"rejectedJournal\":[],\"revision\":\"\",\"amendment\":\"\",\"status\":\"posted\",\"subjectAreas\":[{\"id\":57890011,\"name\":\"Renewable Resources\"}],\"tags\":[],\"updatedAt\":\"2025-11-13T02:18:33+00:00\",\"versionOfRecord\":[],\"versionCreatedAt\":\"2025-11-13 02:18:32\",\"video\":\"\",\"vorDoi\":\"\",\"vorDoiUrl\":\"\",\"workflowStages\":[]},\"version\":\"v1\",\"identity\":\"rs-8096247\",\"journalConfig\":\"researchsquare\"},\"__N_SSP\":true},\"page\":\"/article/[identity]/[[...version]]\",\"query\":{\"redirect\":\"/article/rs-8096247\",\"identity\":\"rs-8096247\",\"version\":[\"v1\"]},\"buildId\":\"8U1c8b4HqxoKbykW_rLl7\",\"isFallback\":false,\"isExperimentalCompile\":false,\"dynamicIds\":[84888],\"gssp\":true,\"scriptLoader\":[]}","source_license":"CC-BY-4.0","license_restricted":false}