{"paper_id":"492d17aa-4d15-4ef9-9330-87837bf3ba01","body_text":"Submitting author affiliation:\nQinghai Normal University, Xining, China\nBeilstein Arch. 2025, 202551. https://doi.org/10.3762/bxiv.2025.51.v1\nPublished 18 Aug 2025\nThis preprint has not been peer-reviewed. When a peer-reviewed version is available, this information\nwill be updated.\nShow All Preprints\nNanotechnology\nOrganic chemistry\nBioorganic chemistry / chemical biology\nCatalysis\nChemical methods and reactions\nFlow and process chemistry\nGreen and sustainable chemistry\nMaterials chemistry\nMedicinal and pharmaceutical chemistry\nNano- and molecular-scale electronics\nNano-biomaterials and bioscience\nNanomagnetics\nNanomaterials, thin films and nanointerfaces\nNanomedicine\nNanometrology and nanomechanics\nNano-optics\nNanopatterning, self-assembly and nanofabrication\nNanostructures for energy and sensing applications\nNatural products chemistry\nOrgano main group chemistry\nOther nanotechnology (unclassified)\nOther organic chemistry (unclassified)\nPhotochemistry and photovoltaics\nPhysical organic chemistry\nSupramolecular chemistry\nThe synthesis of allyl-substituted functional aryl compounds is one of the challenges existing in organic chemistry. Herein, we report a method for constructing allyl-substituted aryl boron compounds through nickel-catalyzed reductive allyl-aryl coupling between borylated aryl triflates and allyl alcohols. The method exhibits good substrate applicability under mild conditions. The synthetic utility of the method is highlighted by its gram-scale reaction, modification of complex molecules, and diverse transformation of the products.\nKeywords: Nickel, boron, allyl alcohols, cross-coupling, reductive coupling\n| Format: DOCX | Size: 4.5 MB | Download |\nWhen a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:\nLiu, T.; Liu, M.; Han, M.; Xu, G.; Han, H. Beilstein Arch. 2025, 202551. doi:10.3762/bxiv.2025.51.v1\nCitation data can be downloaded as file using the \"Download\" button or used for copy/paste from the text window below.\nCitation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and\nZotero.\n© 2025 Liu et al.; licensee Beilstein-Institut.\nThis is an open access work licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-archives.org/xiv/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this work could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material.","source_license":"CC-BY-4.0","license_restricted":false}