{"paper_id":"17cc400f-0ea8-40de-9fcb-1fae82e0a1fe","body_text":"Investigating the improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwaves radiation during acidizing based on hydrochloric acid | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Article Investigating the improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwaves radiation during acidizing based on hydrochloric acid Hadi Tanhaei, Amir Hossein Saeedi Dehaghani This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-5327813/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 03 Mar, 2025 Read the published version in Scientific Reports → Version 1 posted 10 You are reading this latest preprint version Abstract Acidizing boosts well production, while microwave radiation techniques and hybrid methods are emerging to enhance hydrocarbon extraction and oil production efficiency. In this research, the interaction between microwave radiation and working acid on crude oil was systematically investigated. Crude oil samples were positioned adjacent to an acid solution and subsequently subjected to microwave radiation at power levels of 1300 watt(100% Microwave) and 780 watt (60% Microwave) for durations of 1, 2, and 3 minutes. A comprehensive suite of analyses was performed, including viscometric assessments, interfacial tension measurements, density measurements, asphaltene quantification via extraction tests, sludge analysis, nuclear magnetic resonance (NMR) spectroscopy, pH measurements, and Fourier transform infrared spectroscopy (FTIR). The results indicate that the polarity of both the crude oil and the acid solution enhances the absorption of microwave radiation. FTIR analysis revealed an increase in polar functional groups relative to non-polar groups, suggesting significant molecular interactions, which NMR test also proves this trend. Furthermore, viscometric and surface tension tests demonstrated that increased polarity correlates with enhanced microwave absorption. The combined method, which is characterized by the simultaneous presence of polar acid solution and an electromagnetic field, led to alternating fluctuations (increase and decrease) of surface tension, viscosity, density, pH, and sludge during the tested process. It also caused a decrease in the concentration of asphaltene hydrocarbons, The reason for these intermittent changes is the simultaneous effects of changes in the strength of acid solutions and increasing or decreasing the power of microwave radiation at a certain time. Physical sciences/Engineering Physical sciences/Engineering/Chemical engineering Acidizing production efficiency microwave radiation hybrid method asphaltene hydrocarbons Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 6 Figure 7 Figure 8 Figure 9 Figure 10 Figure 11 Figure 12 Figure 13 Figure 14 Figure 15 Figure 16 Figure 17 Figure 18 Figure 19 1. Introduction Upon contact between the acid and crude oil, asphaltene becomes unstable within the crude oil, leading to coagulation and precipitation, potentially blocking formation pores. The rapid reaction between the injected acid and crude oil initiates the formation of an initial layer of acid sludge, followed by its growth. This sludge, comprising paraffin, resin, asphaltene, and other materials like wax and solid particles, forms complex structures with molecules strongly bonded to each other. The quantity of sludge formed is not solely dependent on the asphaltene content. While typically associated with asphaltene, sludge can also form in crude oils without asphaltene, known as non-asphaltic sludge. Asphaltic sludge particles are small but aggregate into larger entities that can block perforations due to swelling from water, acid, and oil presence (Al-Mubarak et al., 2015; Knobloch et al., 1978; Suzuki, 1993; Mohammadzadeh Shirazi et al., 2019; Rietjens, 1997 ; Rietjens and Nieuwpoort, 1999). Chemical analysis of the sludge indicates acid without the necessity of water molecules. Factors affecting acid sludge formation include acid type and concentration, temperature, gaseous components, total base number (TBN), SARA components of crude oil, and the presence of ferric and ferrous ions. Heavier crude oils may not produce acid sludge unless certain conditions, like iron ion presence in an acidic medium, are met (Pourakaberian et al., 2021). Initially, asphaltene molecules in crude oil interact with hydrogen ions from the acid, leading to their attraction to the interface between the acid and crude oil phases. Acid-base reactions occur at this interface based on the chemistry of asphaltene molecules and their heteroatoms (O, N, S), causing the migration of asphaltenes and their accumulation at the interface. This process results in the formation of a strong layer around the acid droplets, preventing their contact. The layer continues to grow, increasing in thickness and compactness over time (Al-Mubarak et al., 2015; Hinojosa, 1996; Jacobs and Thorne, 1986 ;Houchin et al., 1990; Jacobs, 1989 ). Silin et al. (2022) investigated various problems that may arise in the acidification of oil reservoirs due to the incompatibility of acid with reservoir rocks and fluids. One of these problems is the formation of acid emulsions in the oil, which leads to the blocking of pores and prevents the interaction between the surface of the acid and the stone. The conventional \"bottle test\" method lacks comprehensive characterization of these emulsions and is only used for rapid reagent selection. Silin et al.(2022) introduced a new method to evaluate emulsion formation and possible damage during acid treatment using visual observation, viscosity measurement, surface tension, and voltage stability analysis. While HCl-based emulsions are usually more viscous, thinner, and more stable, high acid strength can lead to emulsion breakdown. Emulsions stable under static conditions may disintegrate under mechanical stress; this feature is observed in emulsions based on sulfamic acid. Although the emulsions can be separated visually, an emulsion column may exhibit a water content gradient. These findings highlight the relationship between acid and oil parameters in emulsion formation. In reservoirs with low permeability and heat transfer, electromagnetic (EM) methods are more effective in reducing viscosity and enhancing oil mobility than other techniques. Electromagnetic waves with frequencies ranging from 300 MHz to 300 GHz, known as microwaves, create a field from which materials with a high dielectric coefficient absorb energy. In the oil industry, microwaves are primarily used in oil shale reservoirs. Microwave heating is achieved using an antenna near the production zone. To utilize microwaves as an Enhanced Oil Recovery (EOR) method, an antenna is placed in a drilled hole close to the producing well (Vakhin Khelkhal et al., 2021; Butts Lewis et al., 1983; Chanaa Lallemant et al., 1994). The microwave energy heats the oil in the reservoir, moving toward the producing well. As a result, microwaves are used for oil upgrading, viscosity alteration, temperature increase, wettability enhancement, and enhanced oil recovery (EOR). The absorption of energy varies depending on the sample composition and dielectric properties. Consequently, certain components within the oil begin to heat up because of microwave radiation. Elements in crude oil with a high dielectric coefficient, such as sulfur, nitrogen, and oxygen, exhibit better microwave absorption. The dielectric properties of the materials cause them to align with the microwave field pole in a manner similar to polarity. Sulfoxides, amines, ketones, and aldehydes are the most common functional groups found in asphaltene structures (Karami Dehaghani et al., 2020; Li Hou et al., 2014; Mozafari and Nasri, 2017; Taheri-Shakib Shekarifard et al., 2017; Hanyong Kexin et al., 2018; Taheri-Shakib Shekarifard et al., 2018 Sheu, 2002; Joonaki Hassanpouryouzband et al., 2020; Karami and Dehaghani, 2022). Microwaves increased the temperature of oil parts containing asphaltene particles more than other parts. Asphaltene, one of the heaviest components in crude oil, poses challenges in production and transportation in the oil industry. Understanding the behavior of asphaltene is crucial. Asphaltene precipitation is characterized by high polarity properties, including sulfur, nitrogen, and oxygen. Microwaves can crack these particles, causing them to turn into lighter hydrocarbons (Leontaritis and Mansoori, 1988; Yazdani and Saeedi Dehaghani, 2022). Taheri-Shakib Shekarifard et al. (2017, 2018, 2021) explored the impact of using microwaves for heating on asphaltene deposits in heavy oil. They found that microwave radiation duration plays a crucial role in comparison to conventional heating methods, leading to unpredictable changes at different time intervals. In addition, their research highlighted that compounds with sulfur, nitrogen, and oxygen elements exhibit better microwave absorption properties because of their high dielectric coefficient. As a result, asphaltene particles were observed to undergo cracking under microwave treatment, transforming into lighter hydrocarbons. The ATR-FTIR analysis provides valuable insights into the molecular interactions occurring at the rock-fluid interface during acid treatment. The data reveal that microwave radiation enhances the desorption of various organic compounds from the rock surface, including aromatic compounds, long-chain alkanes, and polar functional groups such as hydroxyl (O-H) and amine (N-H) bonds, as well as carbonyl (C = O) functional groups.The enhanced efficiency of desorption observed with microwave radiation suggests that this treatment facilitates the breakdown of complex hydrocarbon structures, promoting the removal of precipitated asphaltene sludge that often accumulates during acid treatment. Asphaltenes, being high molecular weight compounds, can significantly hinder fluid flow and reduce overall recovery efficiency. The ability of microwave radiation to assist in their desorption indicates a potential pathway for improving the effectiveness of acidizing operations. Moreover, the simultaneous application of microwave radiation during acid treatment appears to create a more favorable environment for the interaction between the acid and the rock surface. This environment may enhance the dissolution of minerals and organic compounds, further contributing to improved fluid mobility. The findings suggest that microwave treatment could serve as a complementary approach to traditional acidizing methods, potentially leading to increased oil recovery rates and more efficient reservoir management (Tanhaei et al., 2023). In this Research, the combined effects of microwaves and acid on heavy crude oil were investigated, focusing on changes in asphaltene concentration and the cracking of asphaltene hydrocarbons. Various basic petroleum and chemistry engineering tests were conducted, including changes in pH ,interfacial tension and viscometry tests, asphaltene extraction, densitometry, temperature changes, sludge amount, and optical tests such as Fourier transform infrared spectroscopy and Nuclear Magnetic Resonance. This comprehensive approach provides valuable insights into the behavior of heavy crude oil under these experimental conditions. 2. Materials and method Analytical techniques and rheological measurements were used to investigate the combined effects of microwave radiation and acid treatment on asphaltene concentration and fluid-fluid interactions. Heavy crude oil samples underwent treatment with microwaves and acid, followed by a series of tests including measurements of pH changes, interfacial tension, viscosity, asphaltene extraction, density, temperature variations, and sludge formation. Fourier Transform Infrared Spectroscopy (FTIR) was employed to analyze the samples. After assessing the changes in asphaltene concentration, the treated asphaltenes were further characterized using Nuclear Magnetic Resonance (NMR) and FTIR techniques. 2.1 Materials 2.1.1 Oil sample The oil sample was obtained from an oil field in the south of Iran. The API, viscosity, acid number, and asphaltene content of the oil sample are shown in Table 1 . Table 1 Physical properties of the oil sample Physical properties API Viscosity (cP) (@ temperature26 ͦ C) Acid number Asphaltene content (%) Crude oil 20.65 ˚ 377 0.6 16 2.2 Acid solution Acidic solutions at a concentration of 15% were prepared to mimic the crude oil-acid interaction at the beginning of the injection. Distilled water, sea water, and formation water were used for the synthesis of acidic solutions. The composition of seawater shown in Table 2 is taken from Persian Gulf seawater. In addition, the formation water was designed according to the chemistry of water produced from the same field where crude oil was sampled. Table 2 The composition of brine water compositions (formation water and sea water) Composition Concentration(ppm) Distilled water Seawater Formation water NaCl 0 28323 177465 Na 2 SO 4 0 4936 0 CaCl 2 0 1630 28036 MgCl 2 . 6H 2 O 0 10510 6561 KCl 0 1032 3440 TDS 0 46431 215502 2.2 Methods 2.2.1 Microwave treatment According to Fig. 1 , the microwave oven operates at a frequency of 2.45 GHz with adjustable radiation power from 260 to 1300 W (Tanhaei et al, 2023). The internal dimensions of the microwave oven are 10* 17* 20 cm. Heavy crude oil was placed in the vicinity of different acid solutions and then treated with microwave radiation at 780 and 1300 watts for 1,2 and 3 minutes. The surface temperature of the heavy crude oil under treatment was measured using a digital thermometer with an accuracy of ± 1°C. The temperature of the untreated crude oil is approximately 26°C (Tanhaei et al, 2023). 2.2.2 Asphaltene extraction To study the changes in the molecular structure of the asphaltenes, the asphaltenes were extracted using the IP-143 standard method. To do this, the oil mixtures were combined with normal heptane (Merck, Germany) to separate the asphaltene, wax, and other heavy fractions. The mixture was then heated to 80 ℃ for 30 min and left to stand in the dark for 24 hr. Subsequently, the mixture underwent filtration using Whatman filter paper #42 to separate the solid precipitates. The filter paper was rinsed with normal heptane in a soxhlet setup to isolate the wax and saturated hydrocarbons. Subsequently, the paper was washed with toluene in the soxhlet setup, causing the asphaltene fraction to dissolve. Finally, the asphaltenes were obtained by evaporating the toluene. To determine the amount of asphaltene in oil samples, an IP-143 test was performed. As mentioned in the sample preparation phase, after the samples were prepared, the IP-143 test was performed on them after a few days. We will explain the working method below: First step: First, for every 1 cc of the oil sample taken in the previous step, 30 cc of normal heptane was poured into the round-bottomed balloon, placed on the heater, and refluxed for 1 hr. Close the lid of the balloon and place it in a cool, dry, and dark place for 24 hr. After 24 hr, it was observed that some asphaltene had been deposited and stuck to the balloon wall. Then, using Whatman #42 filter paper with 0.7-micron holes, we filtered the sample in the balloon. It can be seen that particles higher than 0.7 microns do not pass through the paper and remain on the paper. Liquids passing through the filter paper cannot be used. We kept this balloon in place because there was some asphaltene deposit stuck to the wall of the balloon, which we will need in the next step. The materials deposited on the filter paper are asphaltene and wax. The second step: the filter paper was placed inside the sale, and the reflux operation was repeated with normal heptane. Normal heptane was used because of its saturation, which caused the waxes to wash off the filter paper. We continued the reflux operation until the solution returned to the balloon became colorless. The filter paper will be with asphaltene and some sulfur or impurity. Third step: We placed the filter paper with asphaltene inside the saxule, poured some toluene into the primary balloon, and repeated the reflux operation. Note that the smaller the amount of toluene used, the easier it will be to proceed, because all the toluene present must be evaporated after the reflux operation; It should also be noted that due to the volatility of toluene and the presence of heat, the asphaltene may burn at the bottom of the balloon, in which case the test will not be acceptable. We continued the reflux operation as in the previous step until the liquid returned to the balloon became colorless. Then, we placed the balloon under the laboratory hood to evaporate the toluene. After the complete evaporation of toluene, the substances in the balloon are asphaltene. We then weighed the balloon containing asphaltene. This weight indicates the amount of asphaltene. Note that before starting the test, we should also have the weight of the balloon used. Using the following relationship, we can determine the percentage of asphaltene. $$\\% Asphaltene=\\frac{{{\\text{ }}weight{\\text{ }}of{\\text{ }}asphaltene}}{{weight{\\text{ }}of{\\text{ }}oil}}*100$$ 1 2.2.3 FTIR spectroscopy FTIR spectroscopy was employed to analyze changes in the concentration of functional groups in the asphaltene molecular structure. Asphaltene powders were combined with Potassium bromide at a ratio of 1:40 to create a pellet for testing. The FTIR spectrum of the resulting pellet was examined in the 400–4000 cm-1 range with a resolution of 1cm − 1 using the PerkinElmer Frontier. By calculating the integral areas of the absorbance spectra, measured from valley to valley, we could determine the concentration of functional groups present in the heavy crude oil and asphaltene structures. Although these comparisons, represented as indexes, do not provide quantitative concentration data, they do indicate changes in functional group concentrations. Unlike FTIR spectroscopy, NMR spectroscopy directly correlates the integral area of chemical shifts with the concentration of specific functional groups. Therefore, the asphaltene structural data were derived from NMR spectroscopic analysis. the deconvoluted FTIR peaks, obtained through a Gaussian form using \"residual after 1st derivative,\" displayed consistent indices. 2.2.4 NMR spectroscopy The molecular structure of asphaltene was analyzed using NMR spectroscopy. For the HNMR test, 5 mg of asphaltene powder was dissolved in 0.7 ml of deuterated chloroform, whereas 40 mg of asphaltene powder was used for the CNMR test. A Bruker spectrometer operating at a wave frequency of 500 MHz was utilized, with the pulse width and recycle delay set at 128 and 16µs respectively. Mestrenova software was employed to analyze the data, including identifying shifts, applying corrections, and calculating the spectrum integral areas. The aromaticity and shape factors were determined on the basis of the integral areas of aromatic, aliphatic, and peripheral carbons in the CNMR spectra. In addition, the average carbon number of the alkyl chains was calculated using the integral areas of α, β, and γ alkyl hydrogen and the Dickson equation. On the basis of the NMR data, a hypothetical molecular structure of asphaltene was proposed. 2.2.5 Rheological tests The Anton Par rheometer is a device used for conducting viscometric tests that employs a CC27 spindle to measure viscosity. The machine has a maximum spindle rotation speed of 1200 rpm and can calculate viscosity up to a cutting rate of 1400 s − 1 . Its components include a spindle connected to an internal motor, a chamber for holding the fluid, mechanical sensors for detecting force, a thermometer linked to the fluid chamber’s temperature, and a monitor for data collection. As the motor spins, the spindle interacts with the fluid, experiencing resistance that is translated into data by the sensors. By recording the force parameters of the fluid, the rheometer can determine the viscosity of the fluid in the chamber. In an experiment studying the combined effects of acid and microwaves on treated crude oil viscosity, 18 cc of the oil was placed in the chamber, and its viscosity was measured by adjusting the temperature. 2.2.6 Interfacial tension Interfacial tension (IFT) is the energy between two immiscible fluids. This parameter is an important factor for any harvesting process. The materials used in the processes of increased extraction, such as surfactants, alkalis, and polymers, tend to reduce the interfacial tension between oil and water. As a result, capillary forces are reduced and more residual oil is produced. Drop shape analysis (hanging drop method) is a suitable method for measuring surface tension. Hanging drop surface tension by image analysis, has been considered a very accurate method for measuring IFT for various values. In this method, video images of hanging drops are analyzed and the IFT is measured by solving the Young–Laplace equation. The wettability of the reservoir rock and the interfacial tensions between the reservoir fluids play a vital role in oil recovery efficiency. 2.2.7 Density measurement Density measurement is a crucial aspect of material analysis in various industries, and one of the commonly used methods for determining the density of a substance is through the use of a pycnometer. A pycnometer is a specialized glassware that is designed to accurately measure the density of liquids and solids. The process of density measurement with a pycnometer involves several steps to ensure precision and accuracy. Firstly, the pycnometer is thoroughly cleaned and dried to eliminate any potential contaminants that could affect the measurement. Once cleaned, the pycnometer is weighed to obtain its empty weight, which serves as a reference for the subsequent measurements. To measure the density of a liquid, the pycnometer is filled with the liquid of interest, ensuring that no air bubbles are trapped inside. The filled pycnometer is then weighed again to determine the combined weight of the pycnometer and the liquid. The difference between the combined weight and the empty weight of the pycnometer provides the mass of the liquid. By knowing the volume of the pycnometer (10 cc), the density of the liquid can be calculated using the formula density = mass / volume. It is important to note that temperature plays a significant role in density measurements, as the density of a substance can vary with temperature changes. Therefore, it is essential to conduct density measurements at a consistent and controlled temperature (@ 26 ˚C) to ensure accurate results. 2.2.8 Sludge measurement To measure the amount of sludge, we pour the created third phase (emulsion) on the mesh 300 and then after passing the acid solution, we measure the weight remaining on the mesh. 2.2.9 Sample preparation The acidic solutions used are acidic formation water, acidic sea water, and acidic distilled water, which are denoted by the abbreviations AFW, ASW, and ADW, respectively. Acidic water means the water used to dilute the mother hydrochloric acid. After preparing the acid solutions, the desired oil and acid solution were poured into Blue Cap containers with a capacity of 100 cc and a ratio of 1:1 and were rotated by hand for 5 minutes to form the third phase (coagulated asphaltene emulsion). From the preparation of acidic solutions, oil and the desired acidic solution were poured into Blue Cap containers with a capacity of 100 cc and rotated by hand for 5 minutes to form the third phase (coagulated asphaltene emulsion). (asphaltene coagulated emulsion). Then, to better combine the materials and create a water-oil emulsion phase between the water phase and the oil phase, the emulsion was heated on a magnetic stirrer for 3 hr at a temperature of 26 0 C. After performing these steps, in addition to the oil and water phases, a third phase was formed on the surface of the water-oil joint (asphaltic sludge). This is the first step to check the state of the working acid in the vicinity of the fluid alone and without the presence of microwaves. In the second neighborhood, the acid solutions made in the above-mentioned order are first placed in the vicinity of crude oil with the same stated percentage, and then they are directed to the microwave (MW) chamber. At this stage, by applying 1300 W(100% microwave) and 780 W(60% microwave) for 1, 2 and 3 minute, the crude oil is simultaneously placed in the vicinity of the acid solution and microwaves. Finally, to check the changes, the oil sample was taken from the top of the test tube, and tests of viscosity, interfacial tension, FTIR, densitometry, pH meter, IP-143 asphaltene deposition extraction, and NMR were performed on the oil/asphaltene. In addition, the amount of asphaltic sludge resulting from the mixing of two phases was investigated. 3. Results and Discussions 3.1 Measurement of the hydrogen potential The pH is a quantitative measure of the acidity or basicity of an aqueous solution, defined as the negative logarithm of the activity of the hydrogen ion (H + ) in the solution. The pH scale ranges from 0 to 14, with a pH of 7 being neutral, values below 7 being acidic, and values above 7 being basic or alkaline. The pH is mathematically defined as: $$pH=~ - Log\\left( {\\left[ {{H^+}} \\right]} \\right)~~~~~~~$$ 2 Where [H + ] is the equilibrium molar concentration (mol/L) of hydrogen ions in the solution. This logarithmic scale means that each unit change in pH corresponds to a ten-fold change in the hydrogen ion concentration. At 25°C (77°F), solutions with a pH less than 7 are considered acidic, as they have a higher concentration of H + ions than hydroxide (OH − ) ions. Solutions with a pH greater than 7 are basic or alkaline, as they have a higher concentration of OH − ions than H + ions. A pH of 7 at 25°C indicates a neutral solution, where the concentrations of H + and OH − ions are equal, as in pure water. It's important to note that the neutral pH value of 7 can shift depending on temperature. As the temperature increases above 25°C, the neutral pH value decreases, as the dissociation of water (H 2 O ⇌ H + + OH − ) is favored towards the products at higher temperatures. The pH of the different solutions increased compared to the pure mother acid, but the increase was not significant, and the pH values remained relatively close to each other. This suggests that the application of different acid strength conditions did not dramatically affect the pH, and the acid strength was largely preserved. In the acidic solutions, the pH changes with temperature are negligible compared to basic and neutral solutions. This is because in acidic solutions, the concentration of H + ions is much higher than the concentration of OH − ions, and the small changes in the water dissociation equilibrium due to temperature have a minimal impact on the overall H + concentration and the resulting pH. The electromagnetic field can cause the dissociation of water molecules, leading to an increase in the concentration of hydroxide ions (OH − ) and a corresponding decrease in the concentration of hydrogen ions (H + ). This results in an increase in the pH of the solution, which is proportional to the flow rate of the solution through the electromagnetic field. Figure 2 shows initial fluctuations in pH levels, which may be attributed to the dynamic nature of chemical reactions during treatments.These fluctuations could indicate the breakdown of certain hydrocarbon fractions and the subsequent release of acidic compounds into the solution. Over time, the pH values appear to stabilize, suggesting that the treatments reach a state of chemical equilibrium. This stabilization is crucial as it indicates that the reactions have proceeded to a point where the acidity of the crude oil remains consistent under the given treatment conditions, allowing for predictable outcomes in oil recovery processes. The mechanism behind this pH increase can be explained by the dipole nature of the water molecule. The electromagnetic field can interact with the dipole moment of water, causing the water molecules to dissociate more readily, releasing more OH − ions and absorbing more H + ions. This shift in the water dissociation equilibrium leads to the observed increase in pH. Microwave radiation serves as a powerful tool in enhancing the effectiveness of chemical treatments. The application of microwave energy can lead to localized heating, which facilitates chemical reactions and enhances mass transfer processes. The graph's inclusion of different microwave intensities (100% mw vs. 60% mw) allows for a comparative analysis of how energy input affects the chemical behavior of the crude oil. Higher microwave intensities typically result in increased thermal agitation, which can break down complex hydrocarbon structures and promote the release of acidic components within the oil. This thermal effect may lead to a more significant alteration in pH levels, reflecting the efficiency of the treatment. The use of acidified water treatments is critical in modifying the chemical composition of heavy crude oil. Acids, such as hydrochloric acid, can help break down asphaltene and other high molecular weight hydrocarbons, which are known to contribute to the viscosity and stability of crude oil. By reducing the viscosity, these treatments can enhance the flow properties of the oil, making it easier to extract and process. The effectiveness of these acid treatments is reflected in the resulting pH changes observed in the graph. A significant reduction in pH after treatment indicates successful acidification, which can lead to improved oil recovery outcomes. The influence of the electromagnetic field on the electrical conductivity is revealed and confirmed. This method has many applications, such as increasing the pH of the solution (to reduce the corrosiveness of the water flow), creating a local increase in the concentration of ions in the local volume of the solution, and improving the activity of the solution. 3.2 Temperature changes Polar/nonpolar molecules absorb microwave energy to accelerate the rate of chemical reaction, and microwave energy is considered nonionizing radiation. Molecular motion is affected by microwaves, but they cannot change the molecular structure. The spin effect of microwaves excites polar materials and therefore heats polar materials but not nonpolar materials. Permanent dipole (combined polar) - change of dipole occurs during rotation, thus interaction with radiation; therefore, heteronuclear diatomic molecules are microwave active. Microwaves only transfer energy to polar molecules Microwave energy is too low to directly activate or break molecular bonds. Therefore, microwaves cannot cause molecules to undergo chemical reactions by directly absorbing energy, as high energy visible and ultraviolet light can in photochemical reactions. Microwaves heat polar molecules because they can oscillate in response to a microwave electromagnetic field. These oscillations create thermal energy in the polar molecules and increase their temperature. On the other hand, nonpolar molecules do not have the same ability to oscillate and are therefore not easily heated in microwaves. The temperature of crude oil in the vicinity of acid solutions and microwaves was recorded using a digital laser thermometer (GM-320, Benetech) with an accuracy of ± 1°C. Considering that the digital thermometer measures the temperature of the material based on the beam reflected from the surface of the sample, it is not possible to continuously measure the temperature. To measure the temperature of the treated crude oil during microwave irradiation, it was necessary to stop the irradiation every 30 s. Because of the short treatment time (3 minutes), stopping the treatment even for a short time will disrupt the treatment. To avoid this problem, another batch of acid solutions was prepared to record the temperature characteristics. For example, to obtain a temperature curve with six data points, six acid solutions were treated at six time periods. It should be mentioned that to compare the increase in temperature between crude oil and treated crude oil, the crude oil sample has a temperature of approximately 26 0 C and this temperature is defined at time 0. It is clear that the measured temperature is proportional to the irradiation time and gradually increases with increasing irradiation time based on the types of additions. The measured temperature of crude oil without addition is lower than that when using different types of H + donors at both concentrations due to the weak microwave absorption characteristics of heavy crude oil, as noted by several researchers, and the measured temperature. According to Fig. 3 at 1 min, the irradiation time was 41°C, and then the increase was continued until reaching 68°C in 3 min. The separation reaction is strongly dependent on the irradiation time, and it was observed that only heavy oil with respect to the lower temperature, the percentage of viscosity reduction is lower and the viscosity is proportional to the asphaltene content due to the lower degree of fragmentation and hydrogenation saturation of the fragments to produce the lower temperature fraction. Percentage concentration of H + donors At the beginning of microwave irradiation, all H + donors had approximately temperature values. However, it increased very quickly to approximately 55°C in only 2 min, and then each kind of trend was different during the irradiation time from 2 min to 3 min. Therefore, the curves of formation water and sea water had almost similar trends such that the gradual increase in their temperature as a function of irradiation time had almost similar numerical values in this time interval (2–3 minutes). Percentage concentration of H + donors at 1min irradiation time, all H + donors had almost temperature values of 31–41°C. During the irradiation time, it increased between 1 min and 3 min, and each type had a different trend. According to Fig. 3 all oil samples commence at a baseline temperature of approximately 26°C. This uniform starting point establishes a controlled environment for assessing the impact of microwave treatment on each sample. The initial temperature serves as a reference for evaluating the effectiveness of the heating process. As time progresses, all treatment conditions exhibit a consistent upward trend in temperature, indicative of the energy absorption characteristics of heavy crude oils when subjected to microwave irradiation. This trend is crucial for understanding how quickly the oils can be heated, which is vital for various applications in the oil industry. Notably, the rate of temperature increase varies significantly between the two power levels. The 100MW treatments consistently achieve higher temperatures compared to the 60MW treatments at equivalent time intervals. For example, at the 3-minute mark, the temperature for the 100%MW-ADW oil reaches approximately 80°C, while the 60%MW-ADW oil peaks around 60°C. This difference highlights the relationship between microwave power and thermal efficiency. Within each power category, the temperature responses of the different oil types (ADW, ASW, AFW) appear closely aligned, suggesting that the thermal conductivity and dielectric properties of these oils are similar under microwave treatment. This observation indicates that the inherent properties of the oils do not significantly alter the heating dynamics when subjected to microwave energy. The consistent temperature profiles across different oil types imply that the type of oil may not significantly influence the heating efficiency within the tested parameters. This characteristic allows for broader applicability of the microwave heating method across various heavy crude oils, simplifying operational protocols in industrial settings. The observed temperature increases can be attributed to the dielectric heating mechanism inherent to microwave technology. Microwaves induce molecular agitation, primarily affecting polar molecules and leading to increased kinetic energy and, consequently, higher temperatures. This phenomenon is essential for understanding how energy is transferred to the oil during treatment. The disparity in temperature rise between the two power levels suggests that higher microwave power not only accelerates the rate of heating but also enhances the penetration depth of microwaves into the oil matrix. This improved penetration depth results in more efficient energy transfer, which is critical for maximizing the effectiveness of the heating process. The results underscore the potential of microwave heating as an effective method for enhancing thermal recovery processes in heavy crude oil extraction. The ability to rapidly elevate temperatures could facilitate the reduction of oil viscosity, thereby improving flow characteristics and extraction efficiency. This reduction in viscosity is particularly important for heavy crude oils, which are often more challenging to extract due to their high density and viscosity. The findings advocate for further exploration into the optimization of microwave parameters, such as power levels and treatment durations, to maximize the benefits of this technology in real-world applications. Understanding how different parameters interact will be crucial for developing effective heating protocols tailored to specific operational needs. As mentioned in the scope of these results, these results showed that the increase in concentration leads to an increase in temperature, especially the water temperature. The percentage of distilled water leads to an increase in the degree of temperature because of the polar nature of the solvent, which creates good absorption properties for microwave radiation. The use of H + donors increases. 3.3 interfacial tension The resulting solution is a combination of acid with three types of polar water; therefore, this solution will have a positive effect on the polar compounds of crude oil and increase the polarity of the polar compounds of crude oil. The above will decrease for the polar compounds of crude oil. In general, according to the explanations given, microwaves in the presence of three types of water with acid, which are generally considered polar solutions, will cause changes in the amount of asphaltene with the help of acid solution and three types of water, which are generally considered polar. At high energies (1300 Watt) will cause the separation of light compounds and part of the asphaltene along with the polar solution will occur, which causes the interfacial tension to decrease due to the presence of some asphaltene and the polar solution, but this decrease will be less compared to the lower energy (780 W). At low microwave energy (780 W), a small amount of asphaltene and polar solution will be destroyed, and therefore a large amount of asphaltene with polar solution remains in the composition of crude oil, which increases the surface tension according to the mentioned cases compared to high energy waves of 1300 W. In the early times and with the effect of microwaves on polar materials and the intensification of the polarity of the polar compounds of crude oil by acid and formation water and sea and distilled water, the surface tension will decrease, but with the passage of time and the reduction of the effect of acid and various types of water, the polarity will be affected. will decrease, and the effect of microwaves will cause the destruction of most of the polar compounds, and as a result, the interfacial tension will increase. It is necessary to explain that the decrease and increase due to different salinity in the three types of water will be different. In formation water, in a period of 2–3 min, we will experience a decrease in interfacial tension due to the recrystallization of sodium chloride salt, which will further intensify the effect of polarity. In some cases, due to the short time and the lack of full onset of the effects of microwaves and polar solvents, we will not observe a significant increase in the interfacial tension, but the trend of the graph will be toward stability and then increase. Note that the interfacial tension is measured between the tested oil and distilled water. In addition, the interfacial tension will decrease between two polar compounds and increase between polar and non-polar compounds. In summary, it can be said that, by mixing acidic solutions with crude oil, some of the polar compounds of crude oil will react with polar acidic solutions from the asphaltene coating. As a result, the polarity of crude oil will increase a bit, and finally, the tension of the interfacial area decreases. According to Fig. 4 , the IFT values for untreated crude oil (at 0 min) are significantly higher than those for treated samples, indicating that the treatments effectively reduce interfacial tension. This reduction is essential for improving the separation of oil and water phases, which can enhance oil recovery processes. The decrease in IFT can lead to a more efficient extraction process, as lower IFT values typically correlate with improved flow characteristics of the oil. Among the treated samples, ADW-mw100% and AFW-mw100%show the lowest IFT values, indicating that these treatment conditions are particularly effective at reducing interfacial tension. This suggests that higher microwave power combined with acidic solutions leads to more efficient emulsification and separation. The significant drop in IFT under these conditions indicates that the treatment effectively alters the physical properties of the oil, making it easier to separate from water. Conversely, the treatments at 60% power (e.g., AFW-mw60%, ADW-mw60%) generally exhibit higher IFT values compared to their 100% counterparts. This indicates that lower microwave power may not provide sufficient energy to effectively alter the interfacial properties of the oil. The insufficient energy at lower power levels may limit the effectiveness of the treatment, resulting in higher IFT values and potentially less efficient recovery processes. The type of acidic solution used plays a significant role in the effectiveness of the treatment. For instance, ADW consistently shows lower IFT values compared to AFW and ASW across both power levels. This suggests that the ionic composition and pH of the acidic distilled water may enhance its ability to reduce interfacial tension more effectively than the other solutions. The unique properties of distilled water, such as its purity and specific ion content, likely contribute to its superior performance in this context. The differences in IFT can be attributed to the varying chemical compositions of the acidic solutions. Distilled water may contain fewer impurities and a different ionic strength than fresh or sea water, leading to more favorable interactions with the oil. The presence of specific ions in the acidic solutions can significantly influence the emulsification process, impacting the overall effectiveness of the treatment. The IFT values tend to decrease with longer treatment durations, particularly for the 100% microwave treatments. For example, treatments at 3 minutes generally yield lower IFT values than those at 1 minute. This trend indicates that prolonged exposure to microwave energy enhances the interaction between the oil and the acidic solutions, leading to greater reductions in interfacial tension. The extended treatment time allows for more thorough mixing and 3.4 Viscosity In the analysis of the above results, it should be said that in the first few minutes, because the acid has still maintained its pH at the beginning of the test, and the microwave waves will just start working, so at this stage, the effect of the acid will be greater than that of the microwave waves, and as a result, because The time is low and the pH is lower and more acidic, so the thickness of the emulsion layer will increase and the resulting emulsion will be stable, so it will not be able to separate into water and oil phase, and as a result, by taking an oil sample from the oil layer, which will be accompanied by some emulsion to The reason for the high thickness and the error in removing the oil from the oil layer (which will increase the viscosity of the oil compared to the oil before the test), with the passage of time and the reduction of the effect of acid and the increase of R, as well as the reduction of the emulsion layer and the beginning of the effect of microwave waves and microwave heat, which directly It will affect the composition of crude oil. The viscosity of the oil layer, which has some emulsion, will decrease because both the increase in pH and the start of the effect of microwave waves and the concentrated heat of the waves on the composition of the oil layer, which also has some emulsion, will make the emulsion easier to The water and oil phases are transformed and broken in some way, and as a result, the viscosity of the oil layer decreases. Over time, in the next stage, the effect of acid and microwave waves will reach a balance, which causes the viscosity of the oil layer to remain almost constant. However, over time, the effect of pH and acidity will completely disappear, and microwave waves will overcome the acid and the property of acidic pH. The concentrated heat of microwave waves with a direct effect on the composition of the oil layer, which also has a negligible amount of emulsion, will increase the viscosity of the oil layer compared with the previous oil tested. The above compounds and molecules will cause the movement of these molecules and atoms and will have very little loss compared to normal heat because normal heat starts from heating the container and then heat transfer, but microwave heat is concentrated on molecules and compounds. By focusing on the molecules and increasing the movement of the molecules, the microwave waves make it easier for the lighter components to be separated from the oil layer and also reduce the amount of sulfur in the oil, thus causing the heavier components to remain, and as a result, the viscosity of the oil layer increases. The effect of microwave waves on increasing the viscosity of crude oil is greater than that of acid with a lower pH. Over long periods of time, microwave waves will overcome the acid. The presence of acid and salt will increase the efficiency of microwave waves; however, if both salt and acid factors are involved, this efficiency will not increase to a great extent; however, if each factor is present separately, the efficiency of microwave waves will increase. Regarding the distilled water that was used to dilute the acid and was placed in the vicinity of the microwave waves (780 and 1300 watts) along with the crude oil, it should be said that in this mixing, due to the absence of salt and solutes in the water and the mixing of the acid with only the distilled water in the vicinity of the oil Crude in low times due to the onset of acidity and low pH, oil viscosity increase will be higher compared to formation water (acid dilution) and sea water (acid dilution) in the vicinity of crude oil. This increase in viscosity at low times and high acidity with lower pH will be more at low power (780 watts) and the reason for this is because at lower powers of microwave waves at low times with a fresh start of effect and focus of heat on the molecules And the compounds cause the properties of each substance to change slowly, that is, at low powers and short times, microwave waves cause the acid to lose its properties step by step, and in the early times, the acidic effect is still maintained and the waves cause changes to begin, if in the waves with a percentage Above, at the beginning of the work, when we are dealing with distilled water and acid, it causes the acidic property to immediately change and increase, and as a result, the oil zone becomes more viscous and decreases. Therefore, at the initial stage of work, regarding distilled water and acid in the vicinity of crude oil, the final analysis is It will be the case that at the power of 780 W, because the microwave waves are at low times, so they will not immediately affect the acid, and the acid will still maintain its acid strength and increase the viscosity of the oil layer. However, at a power of 1300 W, with the greater effect of microwave waves, the acid will lose its acidic property, and as a result, with a lower amount of acid power, it will increase the viscosity of the oil layer, and this increase in viscosity will be less compared to the power of 780 W. According to Fig. 5 , the viscosity of crude oil treated under different conditions shows significant variations. In general, the viscosity tends to increase with the application of microwave treatment, particularly at 100% power. This implies that the microwave energy facilitates the interaction between the oil and the acidic solutions, potentially leading to changes in the oil's molecular structure and flow properties. Higher microwave power likely enhances the thermal energy available to the system, promoting more effective mixing and interaction. For example, the highest viscosities are observed for treatments at ADW-MW100% and AFW-MW100%, indicating that higher microwave power combined with acidic solutions leads to a more substantial increase in viscosity compared to lower power settings. This trend suggests that the treatment is more effective at higher energy levels, possibly due to increased molecular agitation and interaction. The type of acidic solution used has a noticeable effect on the viscosity of the treated oil. Treatments with ADW (Acidic Distilled Water) generally result in higher viscosity values compared to those with AFW (Acidic Fresh Water) and ASW (Acidic Sea Water). This suggests that the chemical composition of the acidic solution plays a crucial role in modifying the oil's properties. The presence of different ions and compounds in the solutions can significantly influence the emulsification and stability of oil-water mixtures, affecting the overall viscosity. The differences in viscosity can be attributed to factors such as pH, ionic strength, and the presence of specific ions or organic compounds in the acidic solutions. For instance, distilled water may have a different ionic composition compared to fresh or sea water, which can lead to varying interactions with the oil. These The viscosity values tend to increase with longer treatment durations. For instance, treatments at 3 minutes generally yield higher viscosity than those at 1 minute. This trend indicates that prolonged exposure to microwave energy enhances the interaction between the oil and the acidic solutions, leading to greater changes in viscosity. The increase in viscosity over time suggests that the microwave treatment promotes the coalescence of oil droplets and the breakdown of emulsions, resulting in a thicker oil phase. The longer treatment times allow for more extensive molecular interactions, which can lead to increased viscosity as the oil becomes more concentrated with heavier components. This is particularly important for optimizing oil recovery processes, as higher viscosity can impede flow but may also indicate a more concentrated oil phase that could enhance recovery efficiency. The untreated crude oil serves as a baseline for comparison, showing significantly lower viscosity values than those observed with treated samples. This indicates that the treatment process effectively alters the viscosity of the oil, likely enhancing its properties for separation and recovery. The untreated crude oil’s viscosity is substantially lower than that of all treated samples, highlighting the impact of the microwave treatment and acidic solutions on the oil's physical characteristics. The untreated crude oil's viscosity being lower suggests that the treatment process not only modifies the viscosity but may also improve the oil's separation characteristics. Understanding how these treatments affect viscosity can help refine extraction techniques and improve overall recovery rates. The changes in viscosity due to microwave treatment are significant for oil recovery processes. Higher viscosity values may indicate a greater concentration of heavier hydrocarbons or emulsified solids, affecting the efficiency of separation and transport. Understanding these dynamics can inform better operational strategies for oil extraction and processing. For instance, knowing the optimal viscosity range can help in designing equipment and processes that maximize flow rates and minimize energy consumption. The relationship between microwave treatment and viscosity changes underscores the potential for using microwave technology as a method for enhancing oil recovery. This could lead to more efficient processes that minimize waste and maximize yield. The ability to control viscosity through treatment parameters can provide operators with a powerful tool for optimizing extraction. The findings suggest that both the microwave power level and the type of acidic solution should be carefully optimized to enhance the viscosity reduction process, which can contribute to improved oil recovery rates. Identifying the most effective combinations of treatment conditions will allow operators to streamline their processes and improve overall efficiency. This optimization can lead to cost savings and reduced environmental impacts by minimizing the need for additional processing steps. Additionally, the results indicate that the treatment duration plays a significant role in achieving the desired viscosity outcomes. Future studies could focus on determining the optimal treatment times for various combinations of microwave power and acidic solutions. This will help establish guidelines for industrial applications, ensuring that operators can achieve the best results with minimal energy expenditure. 3.5 Density In general, there was no decrease in the density of oil due to changes in the composition. In the samples that showed a decrease in viscosity, the density remained unchanged or increased. In the samples where the oil viscosity increased, the density also increased. The highest measured density was at a power of 780 W and in a period of 2 min in the vicinity of the acid solution and distilled water, which is compatible with viscometric tests because we do not have salt in distilled water and only acid, which is the absence of all kinds of salts. The low energy of microwaves causes the heavy compounds of crude oil to be placed next to other compounds, and because the absence of salt and solutes does not increase microwave heating, so in this power and in this type of solution, with the loss of light components, heavy compounds even A much smaller amount does not change. It can be said that the effect of removing light gasses by microwaves is greater than the effect of breaking heavy particles such as asphaltene, because in cases where we saw a decrease in viscosity, the density did not change. Of course, the breaking of molecules and heavy particles changes (reduces) the density of oil, but according to the tests performed, the pycnometer is not a precise tool for observing the decrease in density caused by the breaking of heavy particles suspended in oil. According to Fig. 6 , The graph indicates that the density of the treated oil generally increases with the application of microwave treatment, particularly at higher power settings (100%) compared to lower settings (60%). This suggests that higher microwave energy facilitates better separation of oil from water and solids, leading to a denser product. The increase in density could be attributed to the effective breakdown of emulsions and the aggregation of solid particles, which are critical processes in oil recovery. The density values for oil treated with acidic solutions show variation based on both the type of acidic solution and the duration of treatment. For instance, treatments using acidic distilled water (ADW) at 100% power appear to produce higher density values than those using acidic fresh water (AFW) or acidic sea water (ASW). This difference highlights the influence of the chemical composition of the acidic solutions on the treatment's effectiveness. The density of the oil tends to increase with longer treatment durations. For example, the bars representing 3 minutes of treatment generally show higher density values compared to those for 1 minute, indicating that prolonged exposure to microwave energy enhances the separation process. This trend underscores the importance of optimizing treatment time to achieve desired density characteristics in oil recovery. It suggests that longer treatment times allow for more complete emulsification breakdown and solid separation. Different types of acidic solutions yield varying density results, suggesting that the chemical composition of the water plays a significant role in the treatment's effectiveness. For example, the use of acidic distilled water (ADW) consistently leads to higher density values across different treatment times compared to acidic sea water (ASW) and acidic fresh water (AFW). This may be attributed to the purity and specific ionic properties of distilled water, which can enhance the separation of oil from impurities. The presence of specific ions or organic compounds in ASW and AFW may hinder the separation process, leading to lower density outcomes. The graph also includes a reference point for the density of oil at 0 minutes, which serves as a baseline for evaluating the effects of the treatments. This initial density value provides context for understanding how much the density changes as a result of the treatments. By comparing the treated The results imply that microwave treatment is an effective method for enhancing oil separation from water and solids. The increase in density suggests that the process may effectively reduce the volume of emulsified water and solids in the oil, which is critical for improving oil recovery rates. The ability to manipulate microwave settings and treatment duration opens avenues for optimizing the separation process in real-world applications.The findings highlight the potential of microwave-assisted separation techniques in the oil industry, particularly in enhancing the efficiency of operations where oil-water emulsions are prevalent. This technology could lead to reduced operational costs and improved recovery rates, making it a valuable tool for petroleum engineers and operators. The differences observed between the types of acidic solutions suggest that their chemical properties significantly impact the behavior of oil-water emulsions. Understanding how various acidic solutions interact with crude oil can inform the development of more effective treatments tailored to specific oil types and recovery scenarios. This knowledge is essential for designing processes that maximize oil recovery while minimizing waste and environmental impact. 3.6 Amount of sludge Regarding the sludge resulting from the waves in the presence of acid and acid solution, it should be said that in the presence of distilled water and acid solution, the waves will increase with the passage of time as well as the increase in power, with the loss of heavy and light compounds of crude oil and the creation of new compounds that have They are also of high density, the possibility of sludge formation increases over a long time. It should be noted that this increase in sludge is greater in lower capacities because the heavy components of crude oil are still stored and new compounds are created at the same time. The proximity of formation water due to high salinity and the effect on microwave heating of the resulting sludge will be less than that of other solutions, and at 780 watts of power, it will generally be in a decreasing manner regarding the reductions of acid solution and sea water and distilled water and acid solution in time. These reductions occur due to the increase in microwave power and the effect of temperature on the heavy compounds of crude oil. The data suggest that treatments conducted at 100% microwave power generally produce more sludge than those at 60% power. This indicates that higher microwave intensity enhances the breakdown of oil-water emulsions, leading to more effective separation and increased sludge formation. The increased energy input from the higher power setting likely facilitates more vigorous agitation and heating of the mixture. This phenomenon can be attributed to the enhanced thermal and mechanical effects of microwave radiation, which promotes better interaction between the oil and the acidic solution. The higher energy levels may lead to increased molecular agitation, resulting in more effective emulsification and subsequent separation of sludge from the liquid phase. The results of Fig. 7 show a clear trend where longer treatment durations (3 minutes) yield more sludge compared to shorter durations (1 minute). This suggests that extended exposure to microwave energy allows for greater emulsification or breakdown of crude oil, resulting in increased sludge generation. The time-dependent nature of sludge production highlights the importance of optimizing treatment duration to maximize efficiency while minimizing energy consumption. The correlation between treatment time and sludge production underscores the necessity for careful timing in operational protocols. Longer treatment times may allow for more complete reactions and interactions within the emulsion, leading to improved separation outcomes. However, there is a balance to be struck, as excessively long treatment times may not yield proportionately higher sludge production and could lead to diminishing returns. The type of acidic solution used significantly impacts the amount of sludge produced. For instance, different solutions (AFW, ADW, ASW) may yield varying sludge quantities due to their distinct chemical compositions. The presence of different ions, organic compounds, or impurities in these acidic solutions can influence the emulsification process, affecting the interaction between the oil and water. Acidic Sea Water (ASW) may contain salts and minerals that alter the physical properties of the emulsion compared to Acidic Distilled Water (ADW), which is more purified. This variation in chemical composition can lead to differences in how effectively the oil is broken down and separated, resulting in varying amounts of sludge production. Understanding these differences is crucial for optimizing treatment processes based on the specific characteristics of the water being used. 3.7 Asphaltene extraction The content of asphaltenes during acid treatment has various responses. In this case, the asphaltene content is increased, which is caused by the loss of light hydrocarbons (less than C 5 ) produced by fragmentation, which leads to the concentration of high molecular weight hydrocarbons (asphaltenes). This increase is evidence of fragmentation of asphaltene molecules into condensable aromatics, which leads to the recombination reaction. In the vicinity of microwave waves, the amount of asphaltene will decrease drastically. The reason for this is the direct effect of the waves on the polar compounds of crude oil. Thus, the crude oil will be fragmented and reduced by the radiation of asphaltene waves. In the vicinity of acidic solutions and waves, the amount of asphaltene will be slightly reduced, which is due to the reaction of the acidic solution with the polar components of crude oil and the loss of light components of crude oil due to microwave heating, as well as the direct effect of microwave heating on It is a polar compound, in this way that with the reaction of acid solutions with crude oil asphaltene and the radiation of waves, the resulting polar components will begin to break under the direct influence of microwaves, but due to the presence of acid solutions with high polarities and helping to maintain Crude oil asphaltene will be lower because of crude oil asphaltene reduction. Acidic solutions will help maintain the polarity of crude oil asphaltene and it will be partially preserved, and as a result, the amount of asphaltene will increase in the vicinity of constant temperature and acidic solution, which is due to maintaining the amount of asphaltene by acidic solutions. One side is the effect of temperature on the creation of new compound reactions or the fragmentation of heavy compounds and the creation of new polar heavy bonds. In general, it can be said that because the concentration decreases with increasing temperature, by applying microwaves without the presence of acidic solutions, the heating will break the polar components and reduce the asphaltene. Regarding microwaves in the vicinity of acidic solutions, acidic substances react with oil and polar components of crude oil, and when the effect of microwaves begins, polar compounds and new bonds are broken again, and asphaltene is partially reduced, but only in the presence of crude oil next to acidic solutions. The reaction of acidic solutions with polar compounds, such as crude oil asphaltene, increases the amount (falseness) of asphaltene. The Fig. 8 displays a clear downward trend in asphaltene content from crude oil to the treated samples. This suggests that the treatments applied to the oils effectively reduce the concentration of asphaltenes. Crude Oil has the highest asphaltene content at 16.0%. This indicates that the raw crude oil contains a significant amount of heavy fractions, which can complicate its processing and transport. ADW-100%mw-1min shows a reduction to 15.7%, indicating that the treatment with Acidic Distilled Water (ADW) and microwave energy for one minute has a minor but noticeable effect. ASW-100%mw-1min, further reduces the asphaltene content to 14.7%, suggesting that the treatment with Acidic Sea Water (ASW) is slightly more effective. AFW-100%mw-1min, treated with Acidic Fresh Water (AFW), exhibits the lowest asphaltene content at 14.5%. This indicates that the specific conditions of this treatment were most effective in reducing asphaltenes. Asphaltenes are large, complex molecules composed of carbon, hydrogen, sulfur, nitrogen, and oxygen. They are typically characterized by their solubility in toluene but insolubility in lighter alkanes. Their presence in crude oil can lead to several challenges, including increased viscosity, instability, and potential clogging of pipelines .High asphaltene content can also complicate refining processes, leading to lower yields and increased operational costs. The reduction in asphaltene content as observed in the graph suggests that the treatments (ADW, ASW, and AFW) are effective methods for improving oil quality. These treatments may involve various physical and chemical processes, including solvent extraction, thermal treatment, or the application of microwave energy, which can enhance the separation of lighter fractions from heavier asphaltenes. The effectiveness of these treatments can be attributed to the specific interactions between the acidic solutions and the asphaltenes, which may alter the solubility and stability of these compounds. 3.8 FTIR spectra Use of Fourier-Transform Infrared (FTIR) spectroscopy discusses to analyze the structural changes in the functional groups of a treated asphaltene sample (Taheri, Mollabagher and Seyed Mousavi, 2021). Asphaltene is a complex, high molecular weight fraction of petroleum that is known to contain a variety of functional groups, such as alkanes, aromatics, alcohols, and carbonyls. FTIR spectroscopy is a widely used analytical technique in chemistry and materials science that provides information about the molecular structure of a sample by detecting the characteristic vibrational frequencies of the chemical bonds within the molecules. Each functional group or chemical compound exhibits unique vibrational modes that appear as distinct peaks in the FTIR spectrum. The key findings from the FTIR analysis of the treated asphaltene sample are: 1. Absence of new peaks: The lack of any new peaks in the FTIR spectrum of the treated asphaltene indicates that the treatment did not result in the formation of new functional groups or chemical compounds within the asphaltene structure. 2. Identification of functional groups: a. Alkane compounds: The peaks at 2962, 2921, 2851, 1455, 1374, and 727 cm − 1 correspond to the asymmetric and symmetric stretching vibrations of the C-H bonds in the methyl (CH 3 ) and methylene (CH 2 ) groups, as well as the C-H bending and rocking modes. These are characteristic of the aliphatic hydrocarbon chains present in the asphaltene structure. b. Aromatic compounds: The peaks in the range of 3000–3100, 1601, 864, 801, and 750 cm − 1 are associated with the C-H stretching and bending vibrations of the aromatic rings within the asphaltene structure. c. Amine and alcoholic groups: The broad peak observed in the range of 3100–3500 cm − 1 is attributed to the N-H and O-H stretching vibrations of amine and alcoholic functional groups, respectively. d. Carbonyl group (C = O): The peak at 1700 cm − 1 corresponds to the C = O stretching vibration, which is characteristic of carbonyl-containing functional groups, such as ketones, aldehydes, or carboxylic acids. e. C-O stretching: The peaks at 1262 and 1096 cm − 1 are associated with the C-O stretching vibrations, which are common in various oxygen-containing functional groups, such as alcohols, ethers, or esters. f. Sulfoxide functional group: The peak at 1022 cm − 1 is characteristic of the S = O stretching vibration of the sulfoxide functional group. The absence of new peaks in the FTIR spectrum suggests that the treatment did not introduce any structural changes or the generation of new functional groups within the asphaltene. The observed peaks are consistent with the functional groups and chemical compounds that were already present in the asphaltene before the treatment. This FTIR analysis provides valuable insights into the chemical composition and structural integrity of the asphaltene sample after the treatment, which is important for understanding the changes in the physical and chemical properties of the asphaltene (Rochdi and Landais, 1991; Scotti and Montanari, 1998; Hemmati-Sarapardeh et al. , 2018; Karami, Saeedi Dehaghani and Hossein Seyed Mousavi, 2020; Karami, Saeedi Dehaghani and Haghighi, 2021; Taherian et al. , 2021). As shown in Table 3 , the alkane compounds vibrate at peaks of 2962, 2921, 2851, 1455, 1374, and 727 cm − 1 , which represent the asymmetric stretch of CH 3 , the asymmetric stretch of CH 2 , the symmetric stretch of CH 2 , C–H bend or scissoring, C–H rock, and C-H in long-chain alkane, respectively. Table 3 FTIR assignments of crude and treated asphaltene spectra (Rochdi and Landais, 1991; Scotti and Montanari, 1998; Hemmati-sarapardeh and Dabir, 2018; Karami, Saeedi Dehaghani and Hossein Seyed Mousavi, 2020; Karami, Saeedi Dehaghani and Haghighi, 2021; Taherian et al. , 2021; Karami, Hossein and Dehaghani, 2022a .) Wavelengths Assignments 4000 − 3500 Hydrogen-bonded O-H 3730 − 3100 N-H, O-H 3100 − 3000 C–H stretch in aromatics 3000 − 2943 CH3 asymmetric stretch 2943 − 2877 CH2 asymmetric stretch 2877 − 2769 CH2 symmetric Stretch 1613–1800 C = O stretch in ketones, aldehydes, and carboxylic acids 1613 − 1500 Aromatic C-C stretch 1500 − 1400 C–H bend or scissoring in alkanes 1400 − 1340 C–H rock in Alkane 1340 − 1200 C-O stretching 1200 − 1060 C–N stretch in aliphatic amines/C-O-C stretching in ether 1060 − 910 Stretching of the S = O bond in sulfoxides 910 − 840 C-H bending in an aromatic ring with 1 H 840 − 765 C-H bending in an aromatic ring with 2 H 765 − 730 C-H bending in an aromatic ring with 3H 730 − 710 C-H in long-chain alkanes The integral areas of the peaks were calculated from valley to valley in the FTIR spectrum. By knowing the integral areas, the condensing, aliphaticity, sulfoxide, carbonyl, polar, and aliphatic chain length indexes can be calculated using Eqs. 3–6 (Hemmati-sarapardeh and Dabir, 2018; Zojaji, Esfandiarian and Taheri-shakib, 2020; Karami, Hossein and Dehaghani, 2022a, Tanhaei et al, 2023). The characteristic indices are shown in Table 4 . \\(Aliphatic{\\text{ }}length{\\text{ }}index{\\text{ }}=~\\frac{{{A_{2948 - 2990}}}}{{{A_{2948 - 2877}}}}\\) (3) \\(\\:(S=O)\\:index=\\frac{{A}_{1000-1069}}{Total\\:area}\\) (4) \\(\\:(C=O)\\:index=\\frac{{A}_{1656-1816}}{Total\\:area}\\) (5) \\(\\:Polar\\:index=\\frac{{A}_{3100-3450}}{Total\\:area}\\) (6) 3.8.1 FTIR spectra of oil The FTIR spectrum of crude oil and oil treatment under microwave and acid is depicted in Fig. 9 – 14 . According to the findings in Table 4 , the synchronization of microwave irradiation and acid-oil emulsification did not lead to a consistent change in the CH 3 /CH 2 index. This suggests that the processes of cracking, emulsification, and the release of light compounds all play a role in determining this index. It was observed that the most polar indices are present in the petroleum phase in contact with the acid in the presence of distilled water. This indicates that distilled water generally has a lower ability to emulsify and absorb polar compounds in the emulsion, particularly the asphaltene sludge. Furthermore, the trend of changes in the carbonyl index mirrored the slope of the polar index. However, the sulfoxide index exhibited a decrease, indicating the breaking of these compounds from the oil phase and their subsequent cracking. This phenomenon can be attributed to the presence of heavy compounds in the sludge without microwaves, which leads to an increase in their concentration. In conclusion, the FTIR spectrum analysis of crude oil and oil treatment under microwave and acid reveals valuable insights into the processes of cracking, emulsification, and compound release. The interaction between microwave irradiation, acid-oil emulsification, and the composition of the crude oil has significant implications for understanding the behavior of polar and non-polar compounds in the emulsion. These findings contribute to our understanding of the complex chemical processes involved in oil treatment and have implications for optimizing treatment strategies in the petroleum industry. According to the findings in Table 4 ,the untreated crude oil has an aliphatic index of 0.567903, indicating a relatively high proportion of aliphatic hydrocarbons. This suggests that the crude oil is primarily composed of simpler hydrocarbon structures, which are typically easier to refine.The polar index is measured at 0.005365, reflecting a low concentration of polar compounds. This low value indicates that the crude oil is likely stable and less prone to issues related to polar compound interactions during processing. ASW Treatments (100% mw-1 min, 100% mw-2 min, 100% mw-3 min): The aliphatic indices of these samples decrease from 0.487206 to 0.503384 as treatment time increases. This trend suggests that longer treatment durations may lead to a breakdown of larger aliphatic hydrocarbons into smaller, more complex molecules. Correspondingly, the polar indices increase from 0.007277 to 0.007629, indicating that longer microwave treatments result in higher concentrations of polar compounds. This increase may enhance the oil's reactivity but could also complicate its processing characteristics. ADW Treatments (100% mw-1 min, 100% mw-2 min, 100% mw-3 min): The aliphatic indices for ADW treatments show a more pronounced decrease, ranging from 0.472078 to 0.491329. This significant reduction suggests that the ADW treatment effectively breaks down aliphatic hydrocarbons, possibly converting them into smaller, more polar molecules. The polar indices for these samples are notably higher, ranging from 0.103866 to 0.131546. This substantial increase in polar compounds indicates that the ADW treatment significantly alters the chemical composition of the crude oil, potentially impacting its stability and processing characteristics. AFW Treatments (100% mw-1 min, 100% mw-2 min, 100% mw-3 min): The aliphatic indices for AFW treatments are relatively low, ranging from 0.481883 to 0.492344. This suggests that the AFW treatment is effective in modifying the aliphatic structure of the crude oil, although not as dramatically as the ADW treatments.The polar indices show variability but are generally lower than those for ADW treatments, indicating that AFW may lead to a more balanced composition of aliphatic and polar compounds. This balance could be advantageous for certain refining processes, allowing for better separation and processing of the crude oil. The trends observed in the 100% microwave power treatments are also evident in the 60% power treatments. The aliphatic indices are consistently lower across all treatments compared to the untreated crude oil, indicating that the application of microwave energy, regardless of power level, leads to a breakdown of larger hydrocarbon structures. The polar indices exhibit variability, but the overall trend suggests that lower microwave power may result in less effective extraction of polar compounds compared to full power treatments. This indicates the importance of optimizing microwave power levels to achieve the desired balance between aliphatic and polar components. The treatments significantly alter the chemical composition of the crude oil. The observed decrease in aliphatic indices suggests that the treatment processes, particularly with ADW, effectively break down larger hydrocarbons into smaller, more polar molecules. This transformation can enhance the oil's reactivity and stability, potentially making it more suitable for subsequent refining processes. The data indicate that different acidic solutions and microwave conditions yield varying results in terms of aliphatic and polar content. The ADW treatments appear to be the most effective at increasing polar compound content, which may be beneficial for certain refining processes that require a higher concentration of reactive species. However, this increase in polar compounds can also complicate processing, necessitating careful consideration of treatment conditions. Table 4 FTIR spectrum indices for oil under microwaves and in the vicinity of acidic solutions Index Subject aliphatic(CH 3 /CH 2 ) polar index (c = o,index) (s = o,index) Crude oil 0.567903 0.005365 0.007131 0.006405 (ASW-100%mw-1min) 0.487206 0.007277 0.0055 0.00326 (ASW-100%mw-2min) 0.503384 0.007629 0.00121 0.002743 (ASW-100%mw-3min) 0.55366 0.131546 0.011163 0.00327 (ADW-100%mw-1min) 0.472078 0.103866 0.020497 0.001828 (ADW-100%mw-2min) 0.491329 0.121529 0.013404 0.004203 (ADW-100%mw-3min) 0.481883 0.13086 0.012683 0.003997 (AFW-100%mw-1min) 0.502835 0.061398 0.009965 0.003186 (AFW-100%mw-2min) 0.492344 0.00489 0.008059 0.003236 (AFW-100%mw-3min) 0.517598 0.117343 0.015434 0.009777 (ASW-60%mw-1min) 0.539851 0.027009 0.008421 0.005201 (ASW-60%mw-2min) 0.596916 0.020592 0.011101 0.005239 (ASW-60%mw-3min) 0.508658 0.057809 0.004753 0.004957 (ADW-60%mw-1min) 0.525673 0.107264 0.023441 0.001964 (ADW-60%mw-2min) 0.487454 0.158595 0.017412 0.001976 (ADW-60%mw-3min) 0.510906 0.055617 0.01409 0.003235 (AFW-60%mw-1min 0.511516 0.023575 0.006214 0.004648 (AFW-60%mw-2min) 0.514863 0.025613 0.011029 0.003029 (AFW-60%mw-3min) 0.484872 0.027389 0.005484 0.00495 3.8.2 FTIR spectra of asphaltene The coincidence of microwave radiation and the presence of acidic solutions has regularly increased the CH 3 /CH 2 index for asphaltene samples. This means that all three processes of cracking, emulsification, and keeping heavy compounds in parallel with each other were involved in determining this index. The trend of changes in sulfoxide and carbonyl index was an increase, which is due to the decrease of light aliphatic and aromatic compounds, which leads to an increase in the concentration of heavy polar compounds. The polar index, unlike carbonyl and sulfoxide, decreased because of the preservation of light aliphatic and aromatic compounds, which led to a decrease in the concentration of heavy polar compounds. Based on the CH 3 /CH 2 index in crude oil and oil asphaltenes under microwave radiation, which is increasing, microwave radiation mainly leads to the lengthening of alkane chains. This is due to the release of lighter alkanes from the oil due to the increase in temperature. The decrease in the polar index of asphaltene samples under microwave conditions is due to the retention of light aliphatic and aromatic compounds, which leads to a decrease in the concentration of heavy polar compounds. The increase in carbonyl and sulfoxide indices after microwave irradiation can be explained by this. According to the Table 5 and Fig. 15 , CH 3 /CH 2 index of petroleum asphaltenes under acidic solutions is increasing, and the presence of acidic solutions under constant temperature mainly leads to longer alkane chains. This issue is due to the release of lighter alkanes from the oil due to polarity and temperature. Polarity indices have decreased; as a result, more polar compounds participate more in the emulsion phase. According to the carbonyl index, this index has increased, so the carbonyl hydrocarbons are spread less in the emulsion (sludge). In the same way, the sulfoxide indices also changed. An increase in the sulfoxide index indicates a greater tendency of sulfur-containing compounds to be present in the sludge phase, whereas an increase in the carbonyl index indicates a lower tendency of carbonyl compounds to be present in the sludge phase. The increase in the aliphatic length index indicates the tendency of longer aliphatic compounds to be present in asphaltene sludge. The values for the crude oil indicate a relatively low density (s = 0 index) and low polarity (polar index). This suggests that the crude oil is composed primarily of non-polar hydrocarbons, which are less reactive and more stable. The moderate aliphatic index indicates that while there are some lighter hydrocarbons present, the overall composition leans towards heavier fractions. This combination of indices implies that the crude oil is likely to flow well under standard conditions but may not be ideal for processes requiring high reactivity or compatibility with polar solvents. In this sample(100% mw-ASW-1min), the (s = 0 index) shows an increase, indicating a higher density, which may be due to the interaction with salt water. The (c = 0 index) also increases, suggesting a greater complexity in the hydrocarbon mixture. The polar index is lower than that of the crude oil, indicating that the treatment with salt water may have reduced the number of polar compounds present. However, the significant increase in the aliphatic index suggests that the treatment has enriched the sample with lighter aliphatic hydrocarbons, which can enhance the fluidity and flow characteristics of the oil. This could be beneficial for processes requiring easier transportation and handling. The results for this sample (100% mw-AFW-1min) show a slight decrease in the (s = 0 index) compared to the ASW treatment, indicating a reduction in density. However, the polar index has increased significantly, suggesting that the interaction with fresh water has introduced more polar compounds into the oil. This could imply that the treatment has extracted or transformed certain components of the crude oil, leading to a more complex mixture. The aliphatic index remains high, indicating that the sample still retains a substantial amount of lighter hydrocarbons, which may aid in maintaining good flow properties despite the increased polarity. This sample(100% mw-ADW-1min) exhibits the lowest (s = 0 index) and (c = 0 index) values, suggesting a decrease in both density and complexity. The substantial increase in the polar index indicates that the treatment with distilled water has led to a significant incorporation of polar compounds, which could be due to the extraction of acidic or functional groups from the oil. The aliphatic index is lower than in previous samples, indicating a potential reduction in lighter aliphatic hydrocarbons. This could suggest that the distillation process may have removed some of the lighter fractions, resulting in a heavier, more polar oil that may be less suitable for applications requiring low viscosity and high fluidity. The choice of treatment (salt water, fresh water, or distilled water) has a considerable influence on the oil's properties. Salt water seems to enhance the fluidity by increasing the proportion of lighter aliphatic hydrocarbons, while fresh water and distilled water treatments lead to more polar compositions, which may complicate processing.The increase in polar indices in fresh and distilled water treatments indicates that these processes may introduce more reactive functional groups, which can affect the oil’s behavior in chemical processes, refining, and potential environmental interactions. Table 5 FTIR spectrum indices for asphaltene samples under microwave and acidic solution Subject Index Crude oil 100%mw-ASW-1min 100%mw-AFW-1min 100%mw-ADW-1min (s = o,index) 0.058274 0.071687 0.061325 0.050453 (c = o,index) 0.000826 0.057284 0.019678 0.011443 polar index 0.111074 0.069199 0.13096 0.233213 aliphatic(CH 3 /CH 2 ) 0.416867 0.621257 0.634509 0.388494 3.9 NMR spectroscopy of asphaltene As shown in Table 8 , aromaticity is a parameter used to describe the concentration of aromatic rings in the total asphaltene. The shape factor of the asphaltene molecules, which can be calculated by dividing the ambient aromatic carbons by the total aromatic carbons, approximates the number of destroyed/vaporized aromatic rings. According to these observations, microwaves in the vicinity of acidic solutions weaken the potential for breaking aromatic rings. and acidic solutions alone are not able to break aromatic rings. Cracking of the aromatic nucleus in asphaltenes modified by microwaves in the vicinity of acidic solutions, including distilled water, is usually high. The average number of carbons in the linked alkyl chains was calculated using Dickinson’s equation. In general, by using microwaves in the vicinity of acidic solutions, the length of carbon-containing aliphatic chains increases to the center of the core of aromatic rings, and the accumulation of carbons increases in some way around the aromatic rings, indicating that the length of aliphatic chains is the asphaltene structure. Both the aliphatic and aromatic parts of asphaltene are cracked due to microwaves and acidic solutions. According to the total number of aliphatic carbon, radiation and acidic solutions will not change this process. Note that the asphaltene mass decreased after modification with microwaves and acid solutions, which indicates the cracking of some of the asphaltene molecules into lighter hydrocarbons. These observations are somewhat consistent with the structural parameters calculated from the NMR and FTIR spectra. As mentioned earlier, electromagnetic waves are composed of electric and magnetic fields that fluctuate on the basis of wave frequency, and microwaves are attributed to a part of the electromagnetic spectrum that has a wave frequency between 300 MHz and 300 GHz. Because of the electrical origin of microwaves, functional groups/materials with higher polarity are better candidates for absorbing microwave energy. While the dielectric constant of the asphaltene fraction is in the range of 4–5, the dielectric constant of alkanes is in the range of 1–2. Therefore, asphaltene is the best candidate for absorbing microwave radiation. In Fig. 16 – 19 , we observe that the chemical shifts of crude, acid-treated, and microwave-treated asphaltenes are remarkably similar. Although both the HNMR and CNMR spectra of asphaltenes exhibit comparable peaks, slight differences in the integral area suggest changes in the concentration of specific compounds within the asphaltene molecules. Within the CNMR spectra, the peaks within certain ranges indicate various carbon types: 3-18.5 ppm for terminal CH 3 , 18.5–23 ppm for α methyl carbons near aromatic rings, and 23–50 ppm for CH/CH 2 paraffinic carbons. Amines and sulfur groups are evident in the 50–60 ppm range, while α carbons near OH groups fall within 60–76 ppm. Ethers, alcohols, and esters are represented by carbons within 78–100 ppm, and aromatic carbons span 100–170 ppm. These ranges help determine the asphaltene shape factor by estimating the average number of fused aromatic rings. Peripheral aromatic carbons typically shift within 100–129 ppm, whereas quaternary aromatic carbon signals lie in the 129–170 ppm range. Carbonyl compounds exhibit distinctive shifts, C = O bonds in carboxylic acids (170–190 ppm), Quinolinic carbons (190–200 ppm), and C = O bonds in aldehydes and ketones (> 200 ppm). NMR shifts suggest the presence of amine and alcohol functional groups in the asphaltene structure, corroborated by FTIR spectra showing C-O vibration from ethers, esters, and alcohols. For a detailed breakdown of chemical shifts in the HNNMR and CNMR spectra, please refer to Tables 6 – 7 . (Scotti and Montanari, 1998; Ancheyta et al., 2002; Sheremata et al., 2004; Mullins et al., 2012; Poveda J., 2016; Molina, Ariza and Poveda, 2017; Joonaki et al., 2018; Karami, Hossein and Dehaghani, 2022a). Based on the NMR chemical shifts, the C-O vibration in the FTIR spectrum could be attributed to ethers, esters, and alcoholic compounds. According to the NMR shifts, both amine and alcoholic functional groups are expected in the asphaltene structure, a fact that was also shown in the FTIR spectra. More detailed information about the chemical shifts in the HNMR and CNMR spectra is shown in Tables 6 and 7 . Table 6 The assignments of chemical shifts in CNMR of crude, microwave-treated, and ultrasonic-treated asphaltenes (Scotti and Montanari, 1998; Ancheyta et al. , 2002; Sheremata et al. , 2004; Mullins et al. , 2012; Poveda J., 2016; Molina, Ariza and Poveda, 2017; Joonaki et al. , 2018; Karami, Hossein and Dehaghani, 2022a). Chemical shifts (ppm) Assignments 3-18.5 Terminal CH3 at the alkyl chains 18.5–23 Methyl carbons in α position to aromatic rings. 23–50 CH2 and CH-type naphthenic and paraffinic carbons 50–60 CH and C in paraffinic carbons; C-N in amine groups; C-S; C-S = O 60–76 Paraffinic and naphthenic carbon α to OH 78–100 Ether/alcohol/ester 100–129 Peripheral aromatics 129–170 Quaternary aromatic carbon 170–190 C = O in Carboxylic acid 190–200 Quinolinic carbons > 200 C = O in the aldehyde and ketone Table 7 The assignments of chemical shifts in HNMR of crude, microwave-treated, and ultrasonic-treated asphaltenes (Scotti and Montanari, 1998; Ancheyta et al. , 2002; Sheremata et al. , 2004; Mullins et al. , 2012; Poveda J., 2016; Molina, Ariza and Poveda, 2017; Joonaki et al. , 2018). Chemical shifts (ppm) Assignments 0.1-1 Paraffinic hydrogens, γ and more aromatics, CH 3 groups. 1–2 Paraffinic hydrogens, β to aromatics, CH 3 , and CH 2 groups. 2-4.5 CH, CH 2 , and CH 3 type, α to aromatics. 4.5–6.2 Olefinic carbons in CH and CH 2 6.2-9 Hydrogens in the aromatic 9–12 Aldehyde and carboxylic hydrogens. According to the investigations of FTIR tests, the increase in the aliphatic index is consistent with the increase in the length parameter of aliphatic chains obtained from NMR. Therefore, the proposed asphaltene structure in the hybrid method has more aliphatic chains. In other words, it can be said that by applying the hybrid method, Aliphatic chains increase. According to Table 8 , the increase in the average length apart from cracking of the aromatic core indicates that the ring opening probably occurred due to radiation and the presence of acidic solutions. Note that cracking of the aliphatic chain cannot be fixed using the length of the aliphatic chain. This is because the length of the aliphatic chain does not provide information about the cracking of the aliphatic chain. To check whether the aliphatic chains are cracked or not, the total aliphatic carbon number should be considered. By knowing the number of aromatic rings destroyed, the number of aromatic carbons can be approximated. According to Table 8 ,Tthe asphaltene sample (crude oil) shows a moderate aliphatic chain length of 4.93, accompanied by a significant fraction of aromatic carbon (fa = 0.52356). The presence of 7 fused rings suggests a complex structure that likely contributes to its stability and reactivity. The high aromatic content (Car = 0.91) indicates that this asphaltene may have strong interactions with other aromatic compounds, potentially affecting its solubility in various solvents. The average diameter (Ø = 0.637363) suggests that these molecules or aggregates are relatively large, which can impact their behavior in petroleum systems, particularly in terms of flow and separation processes. This compound (100%MW-ADW-1min) exhibits a longer aliphatic chain (6.886364) compared to the asphaltene sample, suggesting enhanced hydrophobicity. The fraction of aromatic carbon (fa = 0.515464) remains significant, indicating a robust aromatic character. The presence of 7 fused rings, similar to the asphaltene, suggests stability and potential for strong intermolecular interactions. The average diameter (Ø = 0.585106) indicates a slightly smaller size than the asphaltene, which may influence its flow characteristics in mixtures. The high aromatic content (Car = 0.94) suggests that this compound may also exhibit strong interactions with other aromatic materials, which could affect its solubility and reactivity. This sample(100% MW -ASW-1min) features the longest aliphatic chain (7.097561) among the analyzed compounds, indicating a potential for increased hydrophobicity and solubility challenges in polar solvents. The fraction of aromatic carbon is the highest at fa = 0.581395, suggesting a strong aromatic character that could enhance stability. The presence of 6 fused rings indicates a slightly less complex structure compared to the previous samples, which may influen ce its reactivity. The average diameter (Ø = 0.513889) is smaller than that of the asphaltene and MW100-ADW-1min, which could result in different behavior in terms of aggregation and flow characteristics. The lower contribution of non-aromatic carbon (Cp = 0.37) suggests a more aromatic-rich structure, which may enhance interactions with other aromatic compounds. This sample (MW100-AFW-1min ) also shows a significant aliphatic chain length (6.651163) and the highest fraction of aromatic carbon (fa = 0.588235) among the analyzed compounds. The presence of 6 fused rings suggests a stable structure, although slightly less complex than the asphaltene (crude) and 100%MW-ADW-1min. The average diameter (Ø = 0.514286) indicates a size that may facilitate different interactions in mixtures. The relatively lower contribution of non-aromatic carbon (Cp = 0.36) further emphasizes the aromatic nature of this compound, which may affect its stability and interactions with other hydrocarbons. The data presented in the table provides significant insights into the structural characteristics of asphaltenes and related compounds. All samples exhibit substantial aromatic character, which is crucial for predicting behavior in petroleum systems. The higher the fraction of aromatic carbon, the more stable and reactive the compound may be. The length of the aliphatic chains influences solubility and hydrophobicity. Compounds with longer chains may exhibit different behaviors in solvent interactions, potentially complicating extraction and refining processes. The number of fused rings is a critical factor in determining the stability and reactivity of these compounds. Higher numbers of fused rings generally correlate with increased stability, which is essential for understanding how these materials will behave during processing and in environmental contexts. The average diameter of the molecules or aggregates can significantly impact their flow characteristics and separation behavior in mixtures. Larger aggregates may settle or separate more readily, while smaller ones may remain suspended. Calculation of the integral areas in Table 8 provides clues for interpreting any alteration to the asphaltene structural parameters (Poveda J., 2016; Joonaki et al. , 2018). Eqs. 7 – 9 were used to characterize the molecular structure of the asphaltenes. Eq. 7 describes the shape factor of the asphaltene molecules by dividing the peripheral aromatic carbons, which cover the chemical shifts of 100–129 ppm, by the whole aromatic carbons, which lie in the range of 100–170 ppm (Sheremata et al. , 2004). Eq. 8 describes the aromaticity of the asphaltene molecules by dividing the aromatic carbons by all of the aromatic and aliphatic carbons, which lie in the range of 3–60 ppm (Poveda J., 2016). Eq. 9 , which is the Dickson equation, employs α, β, and γ hydrogens (respect to the aromatic rings) to approximate the length of the associated alkyl group attaching to the fused aromatic rings. $$\\varphi =\\frac{{{C_p}}}{{{C_a}}}$$ 7 $${f_a}=\\frac{{{C_{ar}}}}{{{C_{ar}}+{C_{al}}}}$$ 8 $$n=\\frac{{{H_1}\\left( {0.1 - 1} \\right)+{H_2}\\left( {1 - 2} \\right)+{H_3}\\left( {2 - 4.5} \\right)~}}{{{H_3}\\left( {2 - 4.5} \\right)~}}~$$ 9 Table 8 parameters calculated from the NMR spectra Parameters Subject Aliphatic chain length Aliphatic chain length f a Fused ring number Ø C al C p C ar Aliphatic chain length asphaltene(oil) 4.932432 0. 52356 7 0.637363 1 0.58 0.91 MW100-ADW-1min 6.886364 0.515464 7 0.585106 1 0.55 0.94 MW100-ASW-1min 7.097561 0.581395 6 0.513889 1 0.37 0.72 MW100-AFW-1min 6.651163 0.588235 6 0.514286 1 0.36 0.7 4. Conclusion 1- According to FTIR tests, polar functional groups increase compared to other crude oil compounds, and the reason for this is the direct effect of microwaves on polar compounds, as well as the effect of acidic solutions through reaction with polar components of crude oil. 2- The tests related to fluid and fluid (surface tension and densitometry, etc.) will be by hybrid method alternately (increasing and decreasing) and the reason for that is the direct effect of microwave waves as well as the polarity of the waves. The solution is acidic and the pH fluctuates, but over time, this trend generally increases. 3- The amount of asphaltene resulting from the above hybrid method will decrease, but this decrease will be minor. Moreover, according to the NMR experiment, there are more carbons attached to aromatic rings in the asphaltene structure compared to carbons attached to aliphatic chains. 4- The results show that microwave radiation in the vicinity of acid solutions causes the cutting of carbon chains with high molecular weight, but after a long period of radiation, it seems that the lower hydrocarbon chains are recombined and the carbon chains are larger, longer and more branched. form. Asphalt sludge is reduced under microwaves. 5- With increasing salinity, the amount of water ions increases, which leads to a further increase in the absorption capacity of microwaves, which is different according to the dielectric of the target solutions. 6- Microwaves in the vicinity of acid solutions can change the viscosity of heavy oil. This change increases completely at some power levels and decreases at others during a certain period of radiation. There are no general rules for predicting this behavior. 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Cite Share Download PDF Status: Published Journal Publication published 03 Mar, 2025 Read the published version in Scientific Reports → Version 1 posted Editorial decision: Revision requested 23 Dec, 2024 Reviews received at journal 12 Dec, 2024 Reviews received at journal 23 Nov, 2024 Reviewers agreed at journal 19 Nov, 2024 Reviewers agreed at journal 19 Nov, 2024 Reviewers invited by journal 19 Nov, 2024 Editor assigned by journal 16 Nov, 2024 Editor invited by journal 12 Nov, 2024 Submission checks completed at journal 12 Nov, 2024 First submitted to journal 24 Oct, 2024 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. 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Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {\"props\":{\"pageProps\":{\"initialData\":{\"identity\":\"rs-5327813\",\"acceptedTermsAndConditions\":true,\"allowDirectSubmit\":false,\"archivedVersions\":[],\"articleType\":\"Article\",\"associatedPublications\":[],\"authors\":[{\"id\":381795222,\"identity\":\"5f2416c7-47c4-476e-8639-a5b6b1db739b\",\"order_by\":0,\"name\":\"Hadi Tanhaei\",\"email\":\"\",\"orcid\":\"\",\"institution\":\"Tarbiat Modares University\",\"correspondingAuthor\":false,\"prefix\":\"\",\"firstName\":\"Hadi\",\"middleName\":\"\",\"lastName\":\"Tanhaei\",\"suffix\":\"\"},{\"id\":381795223,\"identity\":\"e7d29898-c9e8-43a9-8458-b4f2d19c3bf2\",\"order_by\":1,\"name\":\"Amir Hossein Saeedi 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19\",\"display\":\"\",\"copyAsset\":false,\"role\":\"figure\",\"size\":134240,\"visible\":true,\"origin\":\"\",\"legend\":\"\\u003cp\\u003eHNMR and CNMR spectra of crude oil (asphaltene)\\u003c/p\\u003e\",\"description\":\"\",\"filename\":\"19.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-5327813/v1/bf6c42166e836f95cc0f3efe.png\"},{\"id\":78191470,\"identity\":\"7f3e649a-9bf9-40a0-b92a-1520602030fb\",\"added_by\":\"auto\",\"created_at\":\"2025-03-10 20:03:10\",\"extension\":\"pdf\",\"order_by\":0,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"manuscript-pdf\",\"size\":3706768,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"manuscript.pdf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-5327813/v1/61b530ac-8f20-475c-a112-04cffaf4e7b5.pdf\"}],\"financialInterests\":\"No competing interests reported.\",\"formattedTitle\":\"Investigating the improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwaves radiation during acidizing based on hydrochloric acid\",\"fulltext\":[{\"header\":\"1. Introduction\",\"content\":\"\\u003cp\\u003eUpon contact between the acid and crude oil, asphaltene becomes unstable within the crude oil, leading to coagulation and precipitation, potentially blocking formation pores. The rapid reaction between the injected acid and crude oil initiates the formation of an initial layer of acid sludge, followed by its growth. This sludge, comprising paraffin, resin, asphaltene, and other materials like wax and solid particles, forms complex structures with molecules strongly bonded to each other. The quantity of sludge formed is not solely dependent on the asphaltene content. While typically associated with asphaltene, sludge can also form in crude oils without asphaltene, known as non-asphaltic sludge. Asphaltic sludge particles are small but aggregate into larger entities that can block perforations due to swelling from water, acid, and oil presence (Al-Mubarak et al., 2015; Knobloch et al., 1978; Suzuki, 1993; Mohammadzadeh Shirazi et al., 2019; Rietjens, 1997 ; Rietjens and Nieuwpoort, 1999).\\u003c/p\\u003e \\u003cp\\u003eChemical analysis of the sludge indicates acid without the necessity of water molecules. Factors affecting acid sludge formation include acid type and concentration, temperature, gaseous components, total base number (TBN), SARA components of crude oil, and the presence of ferric and ferrous ions. Heavier crude oils may not produce acid sludge unless certain conditions, like iron ion presence in an acidic medium, are met (Pourakaberian et al., 2021).\\u003c/p\\u003e \\u003cp\\u003eInitially, asphaltene molecules in crude oil interact with hydrogen ions from the acid, leading to their attraction to the interface between the acid and crude oil phases. Acid-base reactions occur at this interface based on the chemistry of asphaltene molecules and their heteroatoms (O, N, S), causing the migration of asphaltenes and their accumulation at the interface. This process results in the formation of a strong layer around the acid droplets, preventing their contact. The layer continues to grow, increasing in thickness and compactness over time (Al-Mubarak et al., 2015; Hinojosa, 1996; Jacobs and Thorne, 1986 ;Houchin et al., 1990; Jacobs, 1989 ).\\u003c/p\\u003e \\u003cp\\u003eSilin et al. (2022) investigated various problems that may arise in the acidification of oil reservoirs due to the incompatibility of acid with reservoir rocks and fluids. One of these problems is the formation of acid emulsions in the oil, which leads to the blocking of pores and prevents the interaction between the surface of the acid and the stone. The conventional \\\"bottle test\\\" method lacks comprehensive characterization of these emulsions and is only used for rapid reagent selection. Silin et al.(2022) introduced a new method to evaluate emulsion formation and possible damage during acid treatment using visual observation, viscosity measurement, surface tension, and voltage stability analysis. While HCl-based emulsions are usually more viscous, thinner, and more stable, high acid strength can lead to emulsion breakdown. Emulsions stable under static conditions may disintegrate under mechanical stress; this feature is observed in emulsions based on sulfamic acid. Although the emulsions can be separated visually, an emulsion column may exhibit a water content gradient. These findings highlight the relationship between acid and oil parameters in emulsion formation.\\u003c/p\\u003e \\u003cp\\u003eIn reservoirs with low permeability and heat transfer, electromagnetic (EM) methods are more effective in reducing viscosity and enhancing oil mobility than other techniques. Electromagnetic waves with frequencies ranging from 300 MHz to 300 GHz, known as microwaves, create a field from which materials with a high dielectric coefficient absorb energy. In the oil industry, microwaves are primarily used in oil shale reservoirs. Microwave heating is achieved using an antenna near the production zone. To utilize microwaves as an Enhanced Oil Recovery (EOR) method, an antenna is placed in a drilled hole close to the producing well (Vakhin Khelkhal et al., 2021; Butts Lewis et al., 1983; Chanaa Lallemant et al., 1994).\\u003c/p\\u003e \\u003cp\\u003eThe microwave energy heats the oil in the reservoir, moving toward the producing well. As a result, microwaves are used for oil upgrading, viscosity alteration, temperature increase, wettability enhancement, and enhanced oil recovery (EOR). The absorption of energy varies depending on the sample composition and dielectric properties. Consequently, certain components within the oil begin to heat up because of microwave radiation. Elements in crude oil with a high dielectric coefficient, such as sulfur, nitrogen, and oxygen, exhibit better microwave absorption. The dielectric properties of the materials cause them to align with the microwave field pole in a manner similar to polarity. Sulfoxides, amines, ketones, and aldehydes are the most common functional groups found in asphaltene structures (Karami Dehaghani et al., 2020; Li Hou et al., 2014; Mozafari and Nasri, 2017; Taheri-Shakib Shekarifard et al., 2017; Hanyong Kexin et al., 2018; Taheri-Shakib Shekarifard et al., 2018 Sheu, 2002; Joonaki Hassanpouryouzband et al., 2020; Karami and Dehaghani, 2022).\\u003c/p\\u003e \\u003cp\\u003eMicrowaves increased the temperature of oil parts containing asphaltene particles more than other parts. Asphaltene, one of the heaviest components in crude oil, poses challenges in production and transportation in the oil industry. Understanding the behavior of asphaltene is crucial. Asphaltene precipitation is characterized by high polarity properties, including sulfur, nitrogen, and oxygen. Microwaves can crack these particles, causing them to turn into lighter hydrocarbons (Leontaritis and Mansoori, 1988; Yazdani and Saeedi Dehaghani, 2022).\\u003c/p\\u003e \\u003cp\\u003eTaheri-Shakib Shekarifard et al. (2017, 2018, 2021) explored the impact of using microwaves for heating on asphaltene deposits in heavy oil. They found that microwave radiation duration plays a crucial role in comparison to conventional heating methods, leading to unpredictable changes at different time intervals. In addition, their research highlighted that compounds with sulfur, nitrogen, and oxygen elements exhibit better microwave absorption properties because of their high dielectric coefficient. As a result, asphaltene particles were observed to undergo cracking under microwave treatment, transforming into lighter hydrocarbons.\\u003c/p\\u003e \\u003cp\\u003eThe ATR-FTIR analysis provides valuable insights into the molecular interactions occurring at the rock-fluid interface during acid treatment. The data reveal that microwave radiation enhances the desorption of various organic compounds from the rock surface, including aromatic compounds, long-chain alkanes, and polar functional groups such as hydroxyl (O-H) and amine (N-H) bonds, as well as carbonyl (C\\u0026thinsp;=\\u0026thinsp;O) functional groups.The enhanced efficiency of desorption observed with microwave radiation suggests that this treatment facilitates the breakdown of complex hydrocarbon structures, promoting the removal of precipitated asphaltene sludge that often accumulates during acid treatment. Asphaltenes, being high molecular weight compounds, can significantly hinder fluid flow and reduce overall recovery efficiency. The ability of microwave radiation to assist in their desorption indicates a potential pathway for improving the effectiveness of acidizing operations. Moreover, the simultaneous application of microwave radiation during acid treatment appears to create a more favorable environment for the interaction between the acid and the rock surface. This environment may enhance the dissolution of minerals and organic compounds, further contributing to improved fluid mobility. The findings suggest that microwave treatment could serve as a complementary approach to traditional acidizing methods, potentially leading to increased oil recovery rates and more efficient reservoir management (Tanhaei et al., 2023).\\u003c/p\\u003e \\u003cp\\u003eIn this Research, the combined effects of microwaves and acid on heavy crude oil were investigated, focusing on changes in asphaltene concentration and the cracking of asphaltene hydrocarbons. Various basic petroleum and chemistry engineering tests were conducted, including changes in pH ,interfacial tension and viscometry tests, asphaltene extraction, densitometry, temperature changes, sludge amount, and optical tests such as Fourier transform infrared spectroscopy and Nuclear Magnetic Resonance. This comprehensive approach provides valuable insights into the behavior of heavy crude oil under these experimental conditions.\\u003c/p\\u003e\"},{\"header\":\"2. Materials and method\",\"content\":\"\\u003cp\\u003eAnalytical techniques and rheological measurements were used to investigate the combined effects of microwave radiation and acid treatment on asphaltene concentration and fluid-fluid interactions. Heavy crude oil samples underwent treatment with microwaves and acid, followed by a series of tests including measurements of pH changes, interfacial tension, viscosity, asphaltene extraction, density, temperature variations, and sludge formation. Fourier Transform Infrared Spectroscopy (FTIR) was employed to analyze the samples. After assessing the changes in asphaltene concentration, the treated asphaltenes were further characterized using Nuclear Magnetic Resonance (NMR) and FTIR techniques.\\u003c/p\\u003e \\u003cdiv id=\\\"Sec3\\\" class=\\\"Section2\\\"\\u003e \\u003ch2\\u003e2.1 Materials\\u003c/h2\\u003e \\u003cdiv id=\\\"Sec4\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.1.1 Oil sample\\u003c/h2\\u003e \\u003cp\\u003eThe oil sample was obtained from an oil field in the south of Iran. The API, viscosity, acid number, and asphaltene content of the oil sample are shown in Table\\u0026nbsp;\\u003cspan refid=\\\"Tab1\\\" class=\\\"InternalRef\\\"\\u003e1\\u003c/span\\u003e.\\u003c/p\\u003e \\u003cp\\u003e \\u003cdiv class=\\\"gridtable\\\"\\u003e\\u003ctable float=\\\"Yes\\\" id=\\\"Tab1\\\" border=\\\"1\\\"\\u003e \\u003ccaption language=\\\"En\\\"\\u003e \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 1\\u003c/div\\u003e \\u003cdiv class=\\\"CaptionContent\\\"\\u003e \\u003cp\\u003ePhysical properties of the oil sample\\u003c/p\\u003e \\u003c/div\\u003e \\u003c/caption\\u003e \\u003ccolgroup cols=\\\"5\\\"\\u003e \\u003cdiv align=\\\"left\\\" class=\\\"colspec\\\" colname=\\\"c1\\\" colnum=\\\"1\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"left\\\" class=\\\"colspec\\\" colname=\\\"c2\\\" colnum=\\\"2\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"left\\\" class=\\\"colspec\\\" colname=\\\"c3\\\" colnum=\\\"3\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"left\\\" class=\\\"colspec\\\" colname=\\\"c4\\\" colnum=\\\"4\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"left\\\" class=\\\"colspec\\\" colname=\\\"c5\\\" colnum=\\\"5\\\"\\u003e\\u003c/div\\u003e \\u003cthead\\u003e \\u003ctr\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003ePhysical properties\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003eAPI\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003eViscosity (cP)\\u003c/p\\u003e \\u003cp\\u003e(@ temperature26 ͦ C)\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003eAcid number\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c5\\\"\\u003e \\u003cp\\u003eAsphaltene content (%)\\u003c/p\\u003e \\u003c/th\\u003e \\u003c/tr\\u003e \\u003c/thead\\u003e \\u003ctbody\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eCrude oil\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e20.65 ˚\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e377\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e0.6\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c5\\\"\\u003e \\u003cp\\u003e16\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003c/tbody\\u003e \\u003c/colgroup\\u003e \\u003c/table\\u003e\\u003c/div\\u003e \\u003c/p\\u003e \\u003c/div\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec5\\\" class=\\\"Section2\\\"\\u003e \\u003ch2\\u003e2.2 Acid solution\\u003c/h2\\u003e \\u003cp\\u003eAcidic solutions at a concentration of 15% were prepared to mimic the crude oil-acid interaction at the beginning of the injection. Distilled water, sea water, and formation water were used for the synthesis of acidic solutions. The composition of seawater shown in Table\\u0026nbsp;\\u003cspan refid=\\\"Tab2\\\" class=\\\"InternalRef\\\"\\u003e2\\u003c/span\\u003e is taken from Persian Gulf seawater. In addition, the formation water was designed according to the chemistry of water produced from the same field where crude oil was sampled.\\u003c/p\\u003e \\u003cp\\u003e \\u003cdiv class=\\\"gridtable\\\"\\u003e\\u003ctable float=\\\"Yes\\\" id=\\\"Tab2\\\" border=\\\"1\\\"\\u003e \\u003ccaption language=\\\"En\\\"\\u003e \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 2\\u003c/div\\u003e \\u003cdiv class=\\\"CaptionContent\\\"\\u003e \\u003cp\\u003eThe composition of brine water compositions (formation water and sea water)\\u003c/p\\u003e \\u003c/div\\u003e \\u003c/caption\\u003e \\u003ccolgroup cols=\\\"4\\\"\\u003e \\u003cdiv align=\\\"left\\\" class=\\\"colspec\\\" colname=\\\"c1\\\" colnum=\\\"1\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"char\\\" char=\\\".\\\" class=\\\"colspec\\\" colname=\\\"c2\\\" colnum=\\\"2\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"char\\\" char=\\\".\\\" class=\\\"colspec\\\" colname=\\\"c3\\\" colnum=\\\"3\\\"\\u003e\\u003c/div\\u003e \\u003cdiv align=\\\"char\\\" char=\\\".\\\" class=\\\"colspec\\\" colname=\\\"c4\\\" colnum=\\\"4\\\"\\u003e\\u003c/div\\u003e \\u003cthead\\u003e \\u003ctr\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c1\\\" morerows=\\\"1\\\" rowspan=\\\"2\\\"\\u003e \\u003cp\\u003eComposition\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colspan=\\\"3\\\" nameend=\\\"c4\\\" namest=\\\"c2\\\"\\u003e \\u003cp\\u003eConcentration(ppm)\\u003c/p\\u003e \\u003c/th\\u003e \\u003c/tr\\u003e \\u003ctr\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003eDistilled water\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003eSeawater\\u003c/p\\u003e \\u003c/th\\u003e \\u003cth align=\\\"left\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003eFormation water\\u003c/p\\u003e \\u003c/th\\u003e \\u003c/tr\\u003e \\u003c/thead\\u003e \\u003ctbody\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eNaCl\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e28323\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e177465\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eNa\\u003csub\\u003e2\\u003c/sub\\u003eSO\\u003csub\\u003e4\\u003c/sub\\u003e\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e4936\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eCaCl\\u003csub\\u003e2\\u003c/sub\\u003e\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e1630\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e28036\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eMgCl\\u003csub\\u003e2\\u003c/sub\\u003e. 6H\\u003csub\\u003e2\\u003c/sub\\u003eO\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e10510\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e6561\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eKCl\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e1032\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e3440\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003ctr\\u003e \\u003ctd align=\\\"left\\\" colname=\\\"c1\\\"\\u003e \\u003cp\\u003eTDS\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c2\\\"\\u003e \\u003cp\\u003e0\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c3\\\"\\u003e \\u003cp\\u003e46431\\u003c/p\\u003e \\u003c/td\\u003e \\u003ctd align=\\\"char\\\" char=\\\".\\\" colname=\\\"c4\\\"\\u003e \\u003cp\\u003e215502\\u003c/p\\u003e \\u003c/td\\u003e \\u003c/tr\\u003e \\u003c/tbody\\u003e \\u003c/colgroup\\u003e \\u003c/table\\u003e\\u003c/div\\u003e \\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec6\\\" class=\\\"Section2\\\"\\u003e \\u003ch2\\u003e2.2 Methods\\u003c/h2\\u003e \\u003cdiv id=\\\"Sec7\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.1 Microwave treatment\\u003c/h2\\u003e \\u003cp\\u003eAccording to Fig.\\u0026nbsp;\\u003cspan refid=\\\"Fig1\\\" class=\\\"InternalRef\\\"\\u003e1\\u003c/span\\u003e, the microwave oven operates at a frequency of 2.45 GHz with adjustable radiation power from 260 to 1300 W (Tanhaei et al, 2023). The internal dimensions of the microwave oven are 10* 17* 20 cm. Heavy crude oil was placed in the vicinity of different acid solutions and then treated with microwave radiation at 780 and 1300 watts for 1,2 and 3 minutes.\\u003c/p\\u003e \\u003cp\\u003eThe surface temperature of the heavy crude oil under treatment was measured using a digital thermometer with an accuracy of \\u0026plusmn;\\u0026thinsp;1\\u0026deg;C. The temperature of the untreated crude oil is approximately 26\\u0026deg;C (Tanhaei et al, 2023).\\u003c/p\\u003e \\u003cp\\u003e \\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec8\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.2 Asphaltene extraction\\u003c/h2\\u003e \\u003cp\\u003eTo study the changes in the molecular structure of the asphaltenes, the asphaltenes were extracted using the IP-143 standard method. To do this, the oil mixtures were combined with normal heptane (Merck, Germany) to separate the asphaltene, wax, and other heavy fractions. The mixture was then heated to 80 ℃ for 30 min and left to stand in the dark for 24 hr. Subsequently, the mixture underwent filtration using Whatman filter paper #42 to separate the solid precipitates. The filter paper was rinsed with normal heptane in a soxhlet setup to isolate the wax and saturated hydrocarbons. Subsequently, the paper was washed with toluene in the soxhlet setup, causing the asphaltene fraction to dissolve. Finally, the asphaltenes were obtained by evaporating the toluene.\\u003c/p\\u003e \\u003cp\\u003eTo determine the amount of asphaltene in oil samples, an IP-143 test was performed. As mentioned in the sample preparation phase, after the samples were prepared, the IP-143 test was performed on them after a few days. We will explain the working method below:\\u003c/p\\u003e \\u003cp\\u003eFirst step: First, for every 1 cc of the oil sample taken in the previous step, 30 cc of normal heptane was poured into the round-bottomed balloon, placed on the heater, and refluxed for 1 hr. Close the lid of the balloon and place it in a cool, dry, and dark place for 24 hr. After 24 hr, it was observed that some asphaltene had been deposited and stuck to the balloon wall. Then, using Whatman #42 filter paper with 0.7-micron holes, we filtered the sample in the balloon. It can be seen that particles higher than 0.7 microns do not pass through the paper and remain on the paper.\\u003c/p\\u003e \\u003cp\\u003eLiquids passing through the filter paper cannot be used. We kept this balloon in place because there was some asphaltene deposit stuck to the wall of the balloon, which we will need in the next step. The materials deposited on the filter paper are asphaltene and wax.\\u003c/p\\u003e \\u003cp\\u003eThe second step: the filter paper was placed inside the sale, and the reflux operation was repeated with normal heptane. Normal heptane was used because of its saturation, which caused the waxes to wash off the filter paper. We continued the reflux operation until the solution returned to the balloon became colorless. The filter paper will be with asphaltene and some sulfur or impurity.\\u003c/p\\u003e \\u003cp\\u003eThird step: We placed the filter paper with asphaltene inside the saxule, poured some toluene into the primary balloon, and repeated the reflux operation. Note that the smaller the amount of toluene used, the easier it will be to proceed, because all the toluene present must be evaporated after the reflux operation; It should also be noted that due to the volatility of toluene and the presence of heat, the asphaltene may burn at the bottom of the balloon, in which case the test will not be acceptable. We continued the reflux operation as in the previous step until the liquid returned to the balloon became colorless. Then, we placed the balloon under the laboratory hood to evaporate the toluene.\\u003c/p\\u003e \\u003cp\\u003eAfter the complete evaporation of toluene, the substances in the balloon are asphaltene. We then weighed the balloon containing asphaltene. This weight indicates the amount of asphaltene. Note that before starting the test, we should also have the weight of the balloon used. Using the following relationship, we can determine the percentage of asphaltene.\\u003cdiv id=\\\"Equ1\\\" class=\\\"Equation\\\"\\u003e\\u003cdiv format=\\\"TEX\\\" class=\\\"mathdisplay\\\" id=\\\"FileID_Equ1\\\" name=\\\"EquationSource\\\"\\u003e\\n$$\\\\% Asphaltene=\\\\frac{{{\\\\text{ }}weight{\\\\text{ }}of{\\\\text{ }}asphaltene}}{{weight{\\\\text{ }}of{\\\\text{ }}oil}}*100$$\\u003c/div\\u003e\\u003cdiv class=\\\"EquationNumber\\\"\\u003e1\\u003c/div\\u003e\\u003c/div\\u003e\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec9\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.3 FTIR spectroscopy\\u003c/h2\\u003e \\u003cp\\u003eFTIR spectroscopy was employed to analyze changes in the concentration of functional groups in the asphaltene molecular structure. Asphaltene powders were combined with Potassium bromide at a ratio of 1:40 to create a pellet for testing. The FTIR spectrum of the resulting pellet was examined in the 400\\u0026ndash;4000 cm-1 range with a resolution of 1cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e using the PerkinElmer Frontier. By calculating the integral areas of the absorbance spectra, measured from valley to valley, we could determine the concentration of functional groups present in the heavy crude oil and asphaltene structures. Although these comparisons, represented as indexes, do not provide quantitative concentration data, they do indicate changes in functional group concentrations. Unlike FTIR spectroscopy, NMR spectroscopy directly correlates the integral area of chemical shifts with the concentration of specific functional groups. Therefore, the asphaltene structural data were derived from NMR spectroscopic analysis. the deconvoluted FTIR peaks, obtained through a Gaussian form using \\\"residual after 1st derivative,\\\" displayed consistent indices.\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec10\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.4 NMR spectroscopy\\u003c/h2\\u003e \\u003cp\\u003eThe molecular structure of asphaltene was analyzed using NMR spectroscopy. For the HNMR test, 5 mg of asphaltene powder was dissolved in 0.7 ml of deuterated chloroform, whereas 40 mg of asphaltene powder was used for the CNMR test. A Bruker spectrometer operating at a wave frequency of 500 MHz was utilized, with the pulse width and recycle delay set at 128 and 16\\u0026micro;s respectively. Mestrenova software was employed to analyze the data, including identifying shifts, applying corrections, and calculating the spectrum integral areas. The aromaticity and shape factors were determined on the basis of the integral areas of aromatic, aliphatic, and peripheral carbons in the CNMR spectra. In addition, the average carbon number of the alkyl chains was calculated using the integral areas of α, β, and γ alkyl hydrogen and the Dickson equation. On the basis of the NMR data, a hypothetical molecular structure of asphaltene was proposed.\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec11\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.5 Rheological tests\\u003c/h2\\u003e \\u003cp\\u003eThe Anton Par rheometer is a device used for conducting viscometric tests that employs a CC27 spindle to measure viscosity. The machine has a maximum spindle rotation speed of 1200 rpm and can calculate viscosity up to a cutting rate of 1400 s\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e. Its components include a spindle connected to an internal motor, a chamber for holding the fluid, mechanical sensors for detecting force, a thermometer linked to the fluid chamber\\u0026rsquo;s temperature, and a monitor for data collection. As the motor spins, the spindle interacts with the fluid, experiencing resistance that is translated into data by the sensors. By recording the force parameters of the fluid, the rheometer can determine the viscosity of the fluid in the chamber. In an experiment studying the combined effects of acid and microwaves on treated crude oil viscosity, 18 cc of the oil was placed in the chamber, and its viscosity was measured by adjusting the temperature.\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec12\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.6 Interfacial tension\\u003c/h2\\u003e \\u003cp\\u003eInterfacial tension (IFT) is the energy between two immiscible fluids. This parameter is an important factor for any harvesting process. The materials used in the processes of increased extraction, such as surfactants, alkalis, and polymers, tend to reduce the interfacial tension between oil and water. As a result, capillary forces are reduced and more residual oil is produced. Drop shape analysis (hanging drop method) is a suitable method for measuring surface tension. Hanging drop surface tension by image analysis, has been considered a very accurate method for measuring IFT for various values. In this method, video images of hanging drops are analyzed and the IFT is measured by solving the Young\\u0026ndash;Laplace equation. The wettability of the reservoir rock and the interfacial tensions between the reservoir fluids play a vital role in oil recovery efficiency.\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec13\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.7 Density measurement\\u003c/h2\\u003e \\u003cp\\u003eDensity measurement is a crucial aspect of material analysis in various industries, and one of the commonly used methods for determining the density of a substance is through the use of a pycnometer. A pycnometer is a specialized glassware that is designed to accurately measure the density of liquids and solids. The process of density measurement with a pycnometer involves several steps to ensure precision and accuracy. Firstly, the pycnometer is thoroughly cleaned and dried to eliminate any potential contaminants that could affect the measurement. Once cleaned, the pycnometer is weighed to obtain its empty weight, which serves as a reference for the subsequent measurements.\\u003c/p\\u003e \\u003cp\\u003eTo measure the density of a liquid, the pycnometer is filled with the liquid of interest, ensuring that no air bubbles are trapped inside. The filled pycnometer is then weighed again to determine the combined weight of the pycnometer and the liquid. The difference between the combined weight and the empty weight of the pycnometer provides the mass of the liquid. By knowing the volume of the pycnometer (10 cc), the density of the liquid can be calculated using the formula density\\u0026thinsp;=\\u0026thinsp;mass / volume.\\u003c/p\\u003e \\u003cp\\u003eIt is important to note that temperature plays a significant role in density measurements, as the density of a substance can vary with temperature changes. Therefore, it is essential to conduct density measurements at a consistent and controlled temperature (@ 26 ˚C) to ensure accurate results.\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec14\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.8 Sludge measurement\\u003c/h2\\u003e \\u003cp\\u003eTo measure the amount of sludge, we pour the created third phase (emulsion) on the mesh 300 and then after passing the acid solution, we measure the weight remaining on the mesh.\\u003c/p\\u003e \\u003c/div\\u003e \\u003cdiv id=\\\"Sec15\\\" class=\\\"Section3\\\"\\u003e \\u003ch2\\u003e2.2.9 Sample preparation\\u003c/h2\\u003e \\u003cp\\u003eThe acidic solutions used are acidic formation water, acidic sea water, and acidic distilled water, which are denoted by the abbreviations AFW, ASW, and ADW, respectively. Acidic water means the water used to dilute the mother hydrochloric acid.\\u003c/p\\u003e \\u003cp\\u003eAfter preparing the acid solutions, the desired oil and acid solution were poured into Blue Cap containers with a capacity of 100 cc and a ratio of 1:1 and were rotated by hand for 5 minutes to form the third phase (coagulated asphaltene emulsion). From the preparation of acidic solutions, oil and the desired acidic solution were poured into Blue Cap containers with a capacity of 100 cc and rotated by hand for 5 minutes to form the third phase (coagulated asphaltene emulsion). (asphaltene coagulated emulsion). Then, to better combine the materials and create a water-oil emulsion phase between the water phase and the oil phase, the emulsion was heated on a magnetic stirrer for 3 hr at a temperature of 26 \\u003csup\\u003e0\\u003c/sup\\u003eC. After performing these steps, in addition to the oil and water phases, a third phase was formed on the surface of the water-oil joint (asphaltic sludge). This is the first step to check the state of the working acid in the vicinity of the fluid alone and without the presence of microwaves. In the second neighborhood, the acid solutions made in the above-mentioned order are first placed in the vicinity of crude oil with the same stated percentage, and then they are directed to the microwave (MW) chamber. At this stage, by applying 1300 W(100% microwave) and 780 W(60% microwave) for 1, 2 and 3 minute, the crude oil is simultaneously placed in the vicinity of the acid solution and microwaves. Finally, to check the changes, the oil sample was taken from the top of the test tube, and tests of viscosity, interfacial tension, FTIR, densitometry, pH meter, IP-143 asphaltene deposition extraction, and NMR were performed on the oil/asphaltene. In addition, the amount of asphaltic sludge resulting from the mixing of two phases was investigated.\\u003c/p\\u003e \\u003c/div\\u003e \\u003c/div\\u003e\"},{\"header\":\"3. Results and Discussions\",\"content\":\"\\u003cdiv id=\\\"Sec17\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.1 Measurement of the hydrogen potential\\u003c/h2\\u003e\\n \\u003cp\\u003eThe pH is a quantitative measure of the acidity or basicity of an aqueous solution, defined as the negative logarithm of the activity of the hydrogen ion (H\\u003csup\\u003e+\\u003c/sup\\u003e) in the solution. The pH scale ranges from 0 to 14, with a pH of 7 being neutral, values below 7 being acidic, and values above 7 being basic or alkaline. The pH is mathematically defined as:\\u003c/p\\u003e\\n \\u003cdiv id=\\\"Equ2\\\" class=\\\"Equation\\\"\\u003e\\n \\u003cdiv id=\\\"FileID_Equ2\\\" class=\\\"mathdisplay\\\"\\u003e$$pH=~ - Log\\\\left( {\\\\left[ {{H^+}} \\\\right]} \\\\right)~~~~~~~$$\\u003c/div\\u003e\\n \\u003cdiv class=\\\"EquationNumber\\\"\\u003e2\\u003c/div\\u003e\\n \\u003c/div\\u003e\\n \\u003cp\\u003eWhere [H\\u003csup\\u003e+\\u003c/sup\\u003e] is the equilibrium molar concentration (mol/L) of hydrogen ions in the solution. This logarithmic scale means that each unit change in pH corresponds to a ten-fold change in the hydrogen ion concentration. At 25\\u0026deg;C (77\\u0026deg;F), solutions with a pH less than 7 are considered acidic, as they have a higher concentration of H\\u003csup\\u003e+\\u003c/sup\\u003e ions than hydroxide (OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e) ions. Solutions with a pH greater than 7 are basic or alkaline, as they have a higher concentration of OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e ions than H\\u0026thinsp;+\\u0026thinsp;ions. A pH of 7 at 25\\u0026deg;C indicates a neutral solution, where the concentrations of H\\u003csup\\u003e+\\u003c/sup\\u003e and OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e ions are equal, as in pure water. It\\u0026apos;s important to note that the neutral pH value of 7 can shift depending on temperature. As the temperature increases above 25\\u0026deg;C, the neutral pH value decreases, as the dissociation of water (H\\u003csub\\u003e2\\u003c/sub\\u003eO ⇌ H\\u003csup\\u003e+\\u003c/sup\\u003e + OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e) is favored towards the products at higher temperatures. The pH of the different solutions increased compared to the pure mother acid, but the increase was not significant, and the pH values remained relatively close to each other. This suggests that the application of different acid strength conditions did not dramatically affect the pH, and the acid strength was largely preserved. In the acidic solutions, the pH changes with temperature are negligible compared to basic and neutral solutions. This is because in acidic solutions, the concentration of H\\u003csup\\u003e+\\u003c/sup\\u003e ions is much higher than the concentration of OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e ions, and the small changes in the water dissociation equilibrium due to temperature have a minimal impact on the overall H\\u003csup\\u003e+\\u003c/sup\\u003e concentration and the resulting pH. The electromagnetic field can cause the dissociation of water molecules, leading to an increase in the concentration of hydroxide ions (OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e) and a corresponding decrease in the concentration of hydrogen ions (H\\u003csup\\u003e+\\u003c/sup\\u003e). This results in an increase in the pH of the solution, which is proportional to the flow rate of the solution through the electromagnetic field.\\u003c/p\\u003e\\n \\u003cp\\u003eFigure \\u003cspan class=\\\"InternalRef\\\"\\u003e2\\u003c/span\\u003e shows initial fluctuations in pH levels, which may be attributed to the dynamic nature of chemical reactions during treatments.These fluctuations could indicate the breakdown of certain hydrocarbon fractions and the subsequent release of acidic compounds into the solution. Over time, the pH values appear to stabilize, suggesting that the treatments reach a state of chemical equilibrium. This stabilization is crucial as it indicates that the reactions have proceeded to a point where the acidity of the crude oil remains consistent under the given treatment conditions, allowing for predictable outcomes in oil recovery processes.\\u003c/p\\u003e\\n \\u003cp\\u003eThe mechanism behind this pH increase can be explained by the dipole nature of the water molecule. The electromagnetic field can interact with the dipole moment of water, causing the water molecules to dissociate more readily, releasing more OH\\u003csup\\u003e\\u0026minus;\\u003c/sup\\u003e ions and absorbing more H\\u003csup\\u003e+\\u003c/sup\\u003e ions. This shift in the water dissociation equilibrium leads to the observed increase in pH.\\u003c/p\\u003e\\n \\u003cp\\u003eMicrowave radiation serves as a powerful tool in enhancing the effectiveness of chemical treatments. The application of microwave energy can lead to localized heating, which facilitates chemical reactions and enhances mass transfer processes. The graph\\u0026apos;s inclusion of different microwave intensities (100% mw vs. 60% mw) allows for a comparative analysis of how energy input affects the chemical behavior of the crude oil. Higher microwave intensities typically result in increased thermal agitation, which can break down complex hydrocarbon structures and promote the release of acidic components within the oil. This thermal effect may lead to a more significant alteration in pH levels, reflecting the efficiency of the treatment.\\u003c/p\\u003e\\n \\u003cp\\u003eThe use of acidified water treatments is critical in modifying the chemical composition of heavy crude oil. Acids, such as hydrochloric acid, can help break down asphaltene and other high molecular weight hydrocarbons, which are known to contribute to the viscosity and stability of crude oil. By reducing the viscosity, these treatments can enhance the flow properties of the oil, making it easier to extract and process. The effectiveness of these acid treatments is reflected in the resulting pH changes observed in the graph. A significant reduction in pH after treatment indicates successful acidification, which can lead to improved oil recovery outcomes.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eThe influence of the electromagnetic field on the electrical conductivity is revealed and confirmed. This method has many applications, such as increasing the pH of the solution (to reduce the corrosiveness of the water flow), creating a local increase in the concentration of ions in the local volume of the solution, and improving the activity of the solution.\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec18\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e\\u003cstrong\\u003e3.2 Temperature changes\\u003c/strong\\u003e\\u003c/h2\\u003e\\n \\u003cp\\u003ePolar/nonpolar molecules absorb microwave energy to accelerate the rate of chemical reaction, and microwave energy is considered nonionizing radiation. Molecular motion is affected by microwaves, but they cannot change the molecular structure. The spin effect of microwaves excites polar materials and therefore heats polar materials but not nonpolar materials. Permanent dipole (combined polar) - change of dipole occurs during rotation, thus interaction with radiation; therefore, heteronuclear diatomic molecules are microwave active. Microwaves only transfer energy to polar molecules Microwave energy is too low to directly activate or break molecular bonds. Therefore, microwaves cannot cause molecules to undergo chemical reactions by directly absorbing energy, as high energy visible and ultraviolet light can in photochemical reactions. Microwaves heat polar molecules because they can oscillate in response to a microwave electromagnetic field. These oscillations create thermal energy in the polar molecules and increase their temperature. On the other hand, nonpolar molecules do not have the same ability to oscillate and are therefore not easily heated in microwaves.\\u003c/p\\u003e\\n \\u003cp\\u003eThe temperature of crude oil in the vicinity of acid solutions and microwaves was recorded using a digital laser thermometer (GM-320, Benetech) with an accuracy of \\u0026plusmn;\\u0026thinsp;1\\u0026deg;C. Considering that the digital thermometer measures the temperature of the material based on the beam reflected from the surface of the sample, it is not possible to continuously measure the temperature. To measure the temperature of the treated crude oil during microwave irradiation, it was necessary to stop the irradiation every 30 s. Because of the short treatment time (3 minutes), stopping the treatment even for a short time will disrupt the treatment. To avoid this problem, another batch of acid solutions was prepared to record the temperature characteristics. For example, to obtain a temperature curve with six data points, six acid solutions were treated at six time periods. It should be mentioned that to compare the increase in temperature between crude oil and treated crude oil, the crude oil sample has a temperature of approximately 26 \\u003csup\\u003e0\\u003c/sup\\u003eC and this temperature is defined at time 0. It is clear that the measured temperature is proportional to the irradiation time and gradually increases with increasing irradiation time based on the types of additions. The measured temperature of crude oil without addition is lower than that when using different types of H\\u003csup\\u003e+\\u003c/sup\\u003e donors at both concentrations due to the weak microwave absorption characteristics of heavy crude oil, as noted by several researchers, and the measured temperature. According to Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e3\\u003c/span\\u003e at 1 min, the irradiation time was 41\\u0026deg;C, and then the increase was continued until reaching 68\\u0026deg;C in 3 min. The separation reaction is strongly dependent on the irradiation time, and it was observed that only heavy oil with respect to the lower temperature, the percentage of viscosity reduction is lower and the viscosity is proportional to the asphaltene content due to the lower degree of fragmentation and hydrogenation saturation of the fragments to produce the lower temperature fraction. Percentage concentration of H\\u003csup\\u003e+\\u003c/sup\\u003e donors At the beginning of microwave irradiation, all H\\u003csup\\u003e+\\u003c/sup\\u003e donors had approximately temperature values. However, it increased very quickly to approximately 55\\u0026deg;C in only 2 min, and then each kind of trend was different during the irradiation time from 2 min to 3 min. Therefore, the curves of formation water and sea water had almost similar trends such that the gradual increase in their temperature as a function of irradiation time had almost similar numerical values in this time interval (2\\u0026ndash;3 minutes). Percentage concentration of H\\u003csup\\u003e+\\u003c/sup\\u003e donors at 1min irradiation time, all H\\u003csup\\u003e+\\u003c/sup\\u003e donors had almost temperature values of 31\\u0026ndash;41\\u0026deg;C. During the irradiation time, it increased between 1 min and 3 min, and each type had a different trend.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e3\\u003c/span\\u003e all oil samples commence at a baseline temperature of approximately 26\\u0026deg;C. This uniform starting point establishes a controlled environment for assessing the impact of microwave treatment on each sample. The initial temperature serves as a reference for evaluating the effectiveness of the heating process.\\u003c/p\\u003e\\n \\u003cp\\u003eAs time progresses, all treatment conditions exhibit a consistent upward trend in temperature, indicative of the energy absorption characteristics of heavy crude oils when subjected to microwave irradiation. This trend is crucial for understanding how quickly the oils can be heated, which is vital for various applications in the oil industry. Notably, the rate of temperature increase varies significantly between the two power levels. The 100MW treatments consistently achieve higher temperatures compared to the 60MW treatments at equivalent time intervals. For example, at the 3-minute mark, the temperature for the 100%MW-ADW oil reaches approximately 80\\u0026deg;C, while the 60%MW-ADW oil peaks around 60\\u0026deg;C. This difference highlights the relationship between microwave power and thermal efficiency.\\u003c/p\\u003e\\n \\u003cp\\u003eWithin each power category, the temperature responses of the different oil types (ADW, ASW, AFW) appear closely aligned, suggesting that the thermal conductivity and dielectric properties of these oils are similar under microwave treatment. This observation indicates that the inherent properties of the oils do not significantly alter the heating dynamics when subjected to microwave energy. The consistent temperature profiles across different oil types imply that the type of oil may not significantly influence the heating efficiency within the tested parameters. This characteristic allows for broader applicability of the microwave heating method across various heavy crude oils, simplifying operational protocols in industrial settings.\\u003c/p\\u003e\\n \\u003cp\\u003eThe observed temperature increases can be attributed to the dielectric heating mechanism inherent to microwave technology. Microwaves induce molecular agitation, primarily affecting polar molecules and leading to increased kinetic energy and, consequently, higher temperatures. This phenomenon is essential for understanding how energy is transferred to the oil during treatment. The disparity in temperature rise between the two power levels suggests that higher microwave power not only accelerates the rate of heating but also enhances the penetration depth of microwaves into the oil matrix. This improved penetration depth results in more efficient energy transfer, which is critical for maximizing the effectiveness of the heating process.\\u003c/p\\u003e\\n \\u003cp\\u003eThe results underscore the potential of microwave heating as an effective method for enhancing thermal recovery processes in heavy crude oil extraction. The ability to rapidly elevate temperatures could facilitate the reduction of oil viscosity, thereby improving flow characteristics and extraction efficiency. This reduction in viscosity is particularly important for heavy crude oils, which are often more challenging to extract due to their high density and viscosity. The findings advocate for further exploration into the optimization of microwave parameters, such as power levels and treatment durations, to maximize the benefits of this technology in real-world applications. Understanding how different parameters interact will be crucial for developing effective heating protocols tailored to specific operational needs.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eAs mentioned in the scope of these results, these results showed that the increase in concentration leads to an increase in temperature, especially the water temperature. The percentage of distilled water leads to an increase in the degree of temperature because of the polar nature of the solvent, which creates good absorption properties for microwave radiation. The use of H\\u003csup\\u003e+\\u003c/sup\\u003e donors increases.\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec19\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.3 interfacial tension\\u003c/h2\\u003e\\n \\u003cp\\u003eThe resulting solution is a combination of acid with three types of polar water; therefore, this solution will have a positive effect on the polar compounds of crude oil and increase the polarity of the polar compounds of crude oil. The above will decrease for the polar compounds of crude oil. In general, according to the explanations given, microwaves in the presence of three types of water with acid, which are generally considered polar solutions, will cause changes in the amount of asphaltene with the help of acid solution and three types of water, which are generally considered polar. At high energies (1300 Watt) will cause the separation of light compounds and part of the asphaltene along with the polar solution will occur, which causes the interfacial tension to decrease due to the presence of some asphaltene and the polar solution, but this decrease will be less compared to the lower energy (780 W).\\u003c/p\\u003e\\n \\u003cp\\u003eAt low microwave energy (780 W), a small amount of asphaltene and polar solution will be destroyed, and therefore a large amount of asphaltene with polar solution remains in the composition of crude oil, which increases the surface tension according to the mentioned cases compared to high energy waves of 1300 W.\\u003c/p\\u003e\\n \\u003cp\\u003eIn the early times and with the effect of microwaves on polar materials and the intensification of the polarity of the polar compounds of crude oil by acid and formation water and sea and distilled water, the surface tension will decrease, but with the passage of time and the reduction of the effect of acid and various types of water, the polarity will be affected. will decrease, and the effect of microwaves will cause the destruction of most of the polar compounds, and as a result, the interfacial tension will increase. It is necessary to explain that the decrease and increase due to different salinity in the three types of water will be different. In formation water, in a period of 2\\u0026ndash;3 min, we will experience a decrease in interfacial tension due to the recrystallization of sodium chloride salt, which will further intensify the effect of polarity. In some cases, due to the short time and the lack of full onset of the effects of microwaves and polar solvents, we will not observe a significant increase in the interfacial tension, but the trend of the graph will be toward stability and then increase. Note that the interfacial tension is measured between the tested oil and distilled water. In addition, the interfacial tension will decrease between two polar compounds and increase between polar and non-polar compounds. In summary, it can be said that, by mixing acidic solutions with crude oil, some of the polar compounds of crude oil will react with polar acidic solutions from the asphaltene coating. As a result, the polarity of crude oil will increase a bit, and finally, the tension of the interfacial area decreases.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e4\\u003c/span\\u003e, the IFT values for untreated crude oil (at 0 min) are significantly higher than those for treated samples, indicating that the treatments effectively reduce interfacial tension. This reduction is essential for improving the separation of oil and water phases, which can enhance oil recovery processes. The decrease in IFT can lead to a more efficient extraction process, as lower IFT values typically correlate with improved flow characteristics of the oil.\\u003c/p\\u003e\\n \\u003cp\\u003eAmong the treated samples, ADW-mw100% and AFW-mw100%show the lowest IFT values, indicating that these treatment conditions are particularly effective at reducing interfacial tension. This suggests that higher microwave power combined with acidic solutions leads to more efficient emulsification and separation. The significant drop in IFT under these conditions indicates that the treatment effectively alters the physical properties of the oil, making it easier to separate from water. Conversely, the treatments at 60% power (e.g., AFW-mw60%, ADW-mw60%) generally exhibit higher IFT values compared to their 100% counterparts. This indicates that lower microwave power may not provide sufficient energy to effectively alter the interfacial properties of the oil. The insufficient energy at lower power levels may limit the effectiveness of the treatment, resulting in higher IFT values and potentially less efficient recovery processes.\\u003c/p\\u003e\\n \\u003cp\\u003eThe type of acidic solution used plays a significant role in the effectiveness of the treatment. For instance, ADW consistently shows lower IFT values compared to AFW and ASW across both power levels. This suggests that the ionic composition and pH of the acidic distilled water may enhance its ability to reduce interfacial tension more effectively than the other solutions. The unique properties of distilled water, such as its purity and specific ion content, likely contribute to its superior performance in this context. The differences in IFT can be attributed to the varying chemical compositions of the acidic solutions. Distilled water may contain fewer impurities and a different ionic strength than fresh or sea water, leading to more favorable interactions with the oil. The presence of specific ions in the acidic solutions can significantly influence the emulsification process, impacting the overall effectiveness of the treatment.\\u003c/p\\u003e\\n \\u003cp\\u003eThe IFT values tend to decrease with longer treatment durations, particularly for the 100% microwave treatments. For example, treatments at 3 minutes generally yield lower IFT values than those at 1 minute. This trend indicates that prolonged exposure to microwave energy enhances the interaction between the oil and the acidic solutions, leading to greater reductions in interfacial tension. The extended treatment time allows for more thorough mixing and\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec20\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.4 Viscosity\\u003c/h2\\u003e\\n \\u003cp\\u003eIn the analysis of the above results, it should be said that in the first few minutes, because the acid has still maintained its pH at the beginning of the test, and the microwave waves will just start working, so at this stage, the effect of the acid will be greater than that of the microwave waves, and as a result, because The time is low and the pH is lower and more acidic, so the thickness of the emulsion layer will increase and the resulting emulsion will be stable, so it will not be able to separate into water and oil phase, and as a result, by taking an oil sample from the oil layer, which will be accompanied by some emulsion to The reason for the high thickness and the error in removing the oil from the oil layer (which will increase the viscosity of the oil compared to the oil before the test), with the passage of time and the reduction of the effect of acid and the increase of R, as well as the reduction of the emulsion layer and the beginning of the effect of microwave waves and microwave heat, which directly It will affect the composition of crude oil. The viscosity of the oil layer, which has some emulsion, will decrease because both the increase in pH and the start of the effect of microwave waves and the concentrated heat of the waves on the composition of the oil layer, which also has some emulsion, will make the emulsion easier to The water and oil phases are transformed and broken in some way, and as a result, the viscosity of the oil layer decreases. Over time, in the next stage, the effect of acid and microwave waves will reach a balance, which causes the viscosity of the oil layer to remain almost constant. However, over time, the effect of pH and acidity will completely disappear, and microwave waves will overcome the acid and the property of acidic pH. The concentrated heat of microwave waves with a direct effect on the composition of the oil layer, which also has a negligible amount of emulsion, will increase the viscosity of the oil layer compared with the previous oil tested. The above compounds and molecules will cause the movement of these molecules and atoms and will have very little loss compared to normal heat because normal heat starts from heating the container and then heat transfer, but microwave heat is concentrated on molecules and compounds. By focusing on the molecules and increasing the movement of the molecules, the microwave waves make it easier for the lighter components to be separated from the oil layer and also reduce the amount of sulfur in the oil, thus causing the heavier components to remain, and as a result, the viscosity of the oil layer increases. The effect of microwave waves on increasing the viscosity of crude oil is greater than that of acid with a lower pH. Over long periods of time, microwave waves will overcome the acid.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eThe presence of acid and salt will increase the efficiency of microwave waves; however, if both salt and acid factors are involved, this efficiency will not increase to a great extent; however, if each factor is present separately, the efficiency of microwave waves will increase. Regarding the distilled water that was used to dilute the acid and was placed in the vicinity of the microwave waves (780 and 1300 watts) along with the crude oil, it should be said that in this mixing, due to the absence of salt and solutes in the water and the mixing of the acid with only the distilled water in the vicinity of the oil Crude in low times due to the onset of acidity and low pH, oil viscosity increase will be higher compared to formation water (acid dilution) and sea water (acid dilution) in the vicinity of crude oil. This increase in viscosity at low times and high acidity with lower pH will be more at low power (780 watts) and the reason for this is because at lower powers of microwave waves at low times with a fresh start of effect and focus of heat on the molecules And the compounds cause the properties of each substance to change slowly, that is, at low powers and short times, microwave waves cause the acid to lose its properties step by step, and in the early times, the acidic effect is still maintained and the waves cause changes to begin, if in the waves with a percentage Above, at the beginning of the work, when we are dealing with distilled water and acid, it causes the acidic property to immediately change and increase, and as a result, the oil zone becomes more viscous and decreases. Therefore, at the initial stage of work, regarding distilled water and acid in the vicinity of crude oil, the final analysis is It will be the case that at the power of 780 W, because the microwave waves are at low times, so they will not immediately affect the acid, and the acid will still maintain its acid strength and increase the viscosity of the oil layer. However, at a power of 1300 W, with the greater effect of microwave waves, the acid will lose its acidic property, and as a result, with a lower amount of acid power, it will increase the viscosity of the oil layer, and this increase in viscosity will be less compared to the power of 780 W.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e5\\u003c/span\\u003e, the viscosity of crude oil treated under different conditions shows significant variations. In general, the viscosity tends to increase with the application of microwave treatment, particularly at 100% power. This implies that the microwave energy facilitates the interaction between the oil and the acidic solutions, potentially leading to changes in the oil\\u0026apos;s molecular structure and flow properties. Higher microwave power likely enhances the thermal energy available to the system, promoting more effective mixing and interaction. For example, the highest viscosities are observed for treatments at ADW-MW100% and AFW-MW100%, indicating that higher microwave power combined with acidic solutions leads to a more substantial increase in viscosity compared to lower power settings. This trend suggests that the treatment is more effective at higher energy levels, possibly due to increased molecular agitation and interaction.\\u003c/p\\u003e\\n \\u003cp\\u003eThe type of acidic solution used has a noticeable effect on the viscosity of the treated oil. Treatments with ADW (Acidic Distilled Water) generally result in higher viscosity values compared to those with AFW (Acidic Fresh Water) and ASW (Acidic Sea Water). This suggests that the chemical composition of the acidic solution plays a crucial role in modifying the oil\\u0026apos;s properties. The presence of different ions and compounds in the solutions can significantly influence the emulsification and stability of oil-water mixtures, affecting the overall viscosity. The differences in viscosity can be attributed to factors such as pH, ionic strength, and the presence of specific ions or organic compounds in the acidic solutions. For instance, distilled water may have a different ionic composition compared to fresh or sea water, which can lead to varying interactions with the oil. These\\u003c/p\\u003e\\n \\u003cp\\u003eThe viscosity values tend to increase with longer treatment durations. For instance, treatments at 3 minutes generally yield higher viscosity than those at 1 minute. This trend indicates that prolonged exposure to microwave energy enhances the interaction between the oil and the acidic solutions, leading to greater changes in viscosity. The increase in viscosity over time suggests that the microwave treatment promotes the coalescence of oil droplets and the breakdown of emulsions, resulting in a thicker oil phase. The longer treatment times allow for more extensive molecular interactions, which can lead to increased viscosity as the oil becomes more concentrated with heavier components. This is particularly important for optimizing oil recovery processes, as higher viscosity can impede flow but may also indicate a more concentrated oil phase that could enhance recovery efficiency.\\u003c/p\\u003e\\n \\u003cp\\u003eThe untreated crude oil serves as a baseline for comparison, showing significantly lower viscosity values than those observed with treated samples. This indicates that the treatment process effectively alters the viscosity of the oil, likely enhancing its properties for separation and recovery. The untreated crude oil\\u0026rsquo;s viscosity is substantially lower than that of all treated samples, highlighting the impact of the microwave treatment and acidic solutions on the oil\\u0026apos;s physical characteristics. The untreated crude oil\\u0026apos;s viscosity being lower suggests that the treatment process not only modifies the viscosity but may also improve the oil\\u0026apos;s separation characteristics. Understanding how these treatments affect viscosity can help refine extraction techniques and improve overall recovery rates.\\u003c/p\\u003e\\n \\u003cp\\u003eThe changes in viscosity due to microwave treatment are significant for oil recovery processes. Higher viscosity values may indicate a greater concentration of heavier hydrocarbons or emulsified solids, affecting the efficiency of separation and transport. Understanding these dynamics can inform better operational strategies for oil extraction and processing. For instance, knowing the optimal viscosity range can help in designing equipment and processes that maximize flow rates and minimize energy consumption. The relationship between microwave treatment and viscosity changes underscores the potential for using microwave technology as a method for enhancing oil recovery. This could lead to more efficient processes that minimize waste and maximize yield. The ability to control viscosity through treatment parameters can provide operators with a powerful tool for optimizing extraction.\\u003c/p\\u003e\\n \\u003cp\\u003eThe findings suggest that both the microwave power level and the type of acidic solution should be carefully optimized to enhance the viscosity reduction process, which can contribute to improved oil recovery rates. Identifying the most effective combinations of treatment conditions will allow operators to streamline their processes and improve overall efficiency. This optimization can lead to cost savings and reduced environmental impacts by minimizing the need for additional processing steps. Additionally, the results indicate that the treatment duration plays a significant role in achieving the desired viscosity outcomes. Future studies could focus on determining the optimal treatment times for various combinations of microwave power and acidic solutions. This will help establish guidelines for industrial applications, ensuring that operators can achieve the best results with minimal energy expenditure.\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec21\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.5 Density\\u003c/h2\\u003e\\n \\u003cp\\u003eIn general, there was no decrease in the density of oil due to changes in the composition. In the samples that showed a decrease in viscosity, the density remained unchanged or increased. In the samples where the oil viscosity increased, the density also increased. The highest measured density was at a power of 780 W and in a period of 2 min in the vicinity of the acid solution and distilled water, which is compatible with viscometric tests because we do not have salt in distilled water and only acid, which is the absence of all kinds of salts. The low energy of microwaves causes the heavy compounds of crude oil to be placed next to other compounds, and because the absence of salt and solutes does not increase microwave heating, so in this power and in this type of solution, with the loss of light components, heavy compounds even A much smaller amount does not change.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eIt can be said that the effect of removing light gasses by microwaves is greater than the effect of breaking heavy particles such as asphaltene, because in cases where we saw a decrease in viscosity, the density did not change. Of course, the breaking of molecules and heavy particles changes (reduces) the density of oil, but according to the tests performed, the pycnometer is not a precise tool for observing the decrease in density caused by the breaking of heavy particles suspended in oil.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e6\\u003c/span\\u003e, The graph indicates that the density of the treated oil generally increases with the application of microwave treatment, particularly at higher power settings (100%) compared to lower settings (60%). This suggests that higher microwave energy facilitates better separation of oil from water and solids, leading to a denser product. The increase in density could be attributed to the effective breakdown of emulsions and the aggregation of solid particles, which are critical processes in oil recovery. The density values for oil treated with acidic solutions show variation based on both the type of acidic solution and the duration of treatment. For instance, treatments using acidic distilled water (ADW) at 100% power appear to produce higher density values than those using acidic fresh water (AFW) or acidic sea water (ASW). This difference highlights the influence of the chemical composition of the acidic solutions on the treatment\\u0026apos;s effectiveness.\\u003c/p\\u003e\\n \\u003cp\\u003eThe density of the oil tends to increase with longer treatment durations. For example, the bars representing 3 minutes of treatment generally show higher density values compared to those for 1 minute, indicating that prolonged exposure to microwave energy enhances the separation process. This trend underscores the importance of optimizing treatment time to achieve desired density characteristics in oil recovery. It suggests that longer treatment times allow for more complete emulsification breakdown and solid separation. Different types of acidic solutions yield varying density results, suggesting that the chemical composition of the water plays a significant role in the treatment\\u0026apos;s effectiveness. For example, the use of acidic distilled water (ADW) consistently leads to higher density values across different treatment times compared to acidic sea water (ASW) and acidic fresh water (AFW). This may be attributed to the purity and specific ionic properties of distilled water, which can enhance the separation of oil from impurities. The presence of specific ions or organic compounds in ASW and AFW may hinder the separation process, leading to lower density outcomes. The graph also includes a reference point for the density of oil at 0 minutes, which serves as a baseline for evaluating the effects of the treatments. This initial density value provides context for understanding how much the density changes as a result of the treatments. By comparing the treated\\u003c/p\\u003e\\n \\u003cp\\u003eThe results imply that microwave treatment is an effective method for enhancing oil separation from water and solids. The increase in density suggests that the process may effectively reduce the volume of emulsified water and solids in the oil, which is critical for improving oil recovery rates. The ability to manipulate microwave settings and treatment duration opens avenues for optimizing the separation process in real-world applications.The findings highlight the potential of microwave-assisted separation techniques in the oil industry, particularly in enhancing the efficiency of operations where oil-water emulsions are prevalent. This technology could lead to reduced operational costs and improved recovery rates, making it a valuable tool for petroleum engineers and operators.\\u003c/p\\u003e\\n \\u003cp\\u003eThe differences observed between the types of acidic solutions suggest that their chemical properties significantly impact the behavior of oil-water emulsions. Understanding how various acidic solutions interact with crude oil can inform the development of more effective treatments tailored to specific oil types and recovery scenarios. This knowledge is essential for designing processes that maximize oil recovery while minimizing waste and environmental impact.\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec22\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.6 Amount of sludge\\u003c/h2\\u003e\\n \\u003cp\\u003eRegarding the sludge resulting from the waves in the presence of acid and acid solution, it should be said that in the presence of distilled water and acid solution, the waves will increase with the passage of time as well as the increase in power, with the loss of heavy and light compounds of crude oil and the creation of new compounds that have They are also of high density, the possibility of sludge formation increases over a long time. It should be noted that this increase in sludge is greater in lower capacities because the heavy components of crude oil are still stored and new compounds are created at the same time.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eThe proximity of formation water due to high salinity and the effect on microwave heating of the resulting sludge will be less than that of other solutions, and at 780 watts of power, it will generally be in a decreasing manner regarding the reductions of acid solution and sea water and distilled water and acid solution in time. These reductions occur due to the increase in microwave power and the effect of temperature on the heavy compounds of crude oil.\\u003c/p\\u003e\\n \\u003cp\\u003eThe data suggest that treatments conducted at 100% microwave power generally produce more sludge than those at 60% power. This indicates that higher microwave intensity enhances the breakdown of oil-water emulsions, leading to more effective separation and increased sludge formation. The increased energy input from the higher power setting likely facilitates more vigorous agitation and heating of the mixture. This phenomenon can be attributed to the enhanced thermal and mechanical effects of microwave radiation, which promotes better interaction between the oil and the acidic solution. The higher energy levels may lead to increased molecular agitation, resulting in more effective emulsification and subsequent separation of sludge from the liquid phase.\\u003c/p\\u003e\\n \\u003cp\\u003eThe results of Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e7\\u003c/span\\u003e show a clear trend where longer treatment durations (3 minutes) yield more sludge compared to shorter durations (1 minute). This suggests that extended exposure to microwave energy allows for greater emulsification or breakdown of crude oil, resulting in increased sludge generation. The time-dependent nature of sludge production highlights the importance of optimizing treatment duration to maximize efficiency while minimizing energy consumption. The correlation between treatment time and sludge production underscores the necessity for careful timing in operational protocols. Longer treatment times may allow for more complete reactions and interactions within the emulsion, leading to improved separation outcomes. However, there is a balance to be struck, as excessively long treatment times may not yield proportionately higher sludge production and could lead to diminishing returns.\\u003c/p\\u003e\\n \\u003cp\\u003eThe type of acidic solution used significantly impacts the amount of sludge produced. For instance, different solutions (AFW, ADW, ASW) may yield varying sludge quantities due to their distinct chemical compositions. The presence of different ions, organic compounds, or impurities in these acidic solutions can influence the emulsification process, affecting the interaction between the oil and water.\\u003c/p\\u003e\\n \\u003cp\\u003eAcidic Sea Water (ASW) may contain salts and minerals that alter the physical properties of the emulsion compared to Acidic Distilled Water (ADW), which is more purified. This variation in chemical composition can lead to differences in how effectively the oil is broken down and separated, resulting in varying amounts of sludge production. Understanding these differences is crucial for optimizing treatment processes based on the specific characteristics of the water being used.\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec23\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.7 Asphaltene extraction\\u003c/h2\\u003e\\n \\u003cp\\u003eThe content of asphaltenes during acid treatment has various responses. In this case, the asphaltene content is increased, which is caused by the loss of light hydrocarbons (less than C\\u003csub\\u003e5\\u003c/sub\\u003e) produced by fragmentation, which leads to the concentration of high molecular weight hydrocarbons (asphaltenes). This increase is evidence of fragmentation of asphaltene molecules into condensable aromatics, which leads to the recombination reaction. In the vicinity of microwave waves, the amount of asphaltene will decrease drastically. The reason for this is the direct effect of the waves on the polar compounds of crude oil. Thus, the crude oil will be fragmented and reduced by the radiation of asphaltene waves.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eIn the vicinity of acidic solutions and waves, the amount of asphaltene will be slightly reduced, which is due to the reaction of the acidic solution with the polar components of crude oil and the loss of light components of crude oil due to microwave heating, as well as the direct effect of microwave heating on It is a polar compound, in this way that with the reaction of acid solutions with crude oil asphaltene and the radiation of waves, the resulting polar components will begin to break under the direct influence of microwaves, but due to the presence of acid solutions with high polarities and helping to maintain Crude oil asphaltene will be lower because of crude oil asphaltene reduction. Acidic solutions will help maintain the polarity of crude oil asphaltene and it will be partially preserved, and as a result, the amount of asphaltene will increase in the vicinity of constant temperature and acidic solution, which is due to maintaining the amount of asphaltene by acidic solutions. One side is the effect of temperature on the creation of new compound reactions or the fragmentation of heavy compounds and the creation of new polar heavy bonds. In general, it can be said that because the concentration decreases with increasing temperature, by applying microwaves without the presence of acidic solutions, the heating will break the polar components and reduce the asphaltene. Regarding microwaves in the vicinity of acidic solutions, acidic substances react with oil and polar components of crude oil, and when the effect of microwaves begins, polar compounds and new bonds are broken again, and asphaltene is partially reduced, but only in the presence of crude oil next to acidic solutions. The reaction of acidic solutions with polar compounds, such as crude oil asphaltene, increases the amount (falseness) of asphaltene.\\u003c/p\\u003e\\n \\u003cp\\u003eThe Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e8\\u003c/span\\u003e displays a clear downward trend in asphaltene content from crude oil to the treated samples. This suggests that the treatments applied to the oils effectively reduce the concentration of asphaltenes. Crude Oil has the highest asphaltene content at 16.0%. This indicates that the raw crude oil contains a significant amount of heavy fractions, which can complicate its processing and transport.\\u003c/p\\u003e\\n \\u003cp\\u003eADW-100%mw-1min shows a reduction to 15.7%, indicating that the treatment with Acidic Distilled Water (ADW) and microwave energy for one minute has a minor but noticeable effect.\\u003c/p\\u003e\\n \\u003cp\\u003eASW-100%mw-1min, further reduces the asphaltene content to 14.7%, suggesting that the treatment with Acidic Sea Water (ASW) is slightly more effective.\\u003c/p\\u003e\\n \\u003cp\\u003eAFW-100%mw-1min, treated with Acidic Fresh Water (AFW), exhibits the lowest asphaltene content at 14.5%. This indicates that the specific conditions of this treatment were most effective in reducing asphaltenes.\\u003c/p\\u003e\\n \\u003cp\\u003eAsphaltenes are large, complex molecules composed of carbon, hydrogen, sulfur, nitrogen, and oxygen. They are typically characterized by their solubility in toluene but insolubility in lighter alkanes. Their presence in crude oil can lead to several challenges, including increased viscosity, instability, and potential clogging of pipelines .High asphaltene content can also complicate refining processes, leading to lower yields and increased operational costs.\\u003c/p\\u003e\\n \\u003cp\\u003eThe reduction in asphaltene content as observed in the graph suggests that the treatments (ADW, ASW, and AFW) are effective methods for improving oil quality. These treatments may involve various physical and chemical processes, including solvent extraction, thermal treatment, or the application of microwave energy, which can enhance the separation of lighter fractions from heavier asphaltenes. The effectiveness of these treatments can be attributed to the specific interactions between the acidic solutions and the asphaltenes, which may alter the solubility and stability of these compounds.\\u003c/p\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec24\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.8 FTIR spectra\\u003c/h2\\u003e\\n \\u003cp\\u003eUse of Fourier-Transform Infrared (FTIR) spectroscopy discusses to analyze the structural changes in the functional groups of a treated asphaltene sample (Taheri, Mollabagher and Seyed Mousavi, 2021). Asphaltene is a complex, high molecular weight fraction of petroleum that is known to contain a variety of functional groups, such as alkanes, aromatics, alcohols, and carbonyls. FTIR spectroscopy is a widely used analytical technique in chemistry and materials science that provides information about the molecular structure of a sample by detecting the characteristic vibrational frequencies of the chemical bonds within the molecules. Each functional group or chemical compound exhibits unique vibrational modes that appear as distinct peaks in the FTIR spectrum.\\u003c/p\\u003e\\n \\u003cp\\u003eThe key findings from the FTIR analysis of the treated asphaltene sample are:\\u003c/p\\u003e1. Absence of new peaks: The lack of any new peaks in the FTIR spectrum of the treated asphaltene indicates that the treatment did not result in the formation of new functional groups or chemical compounds within the asphaltene structure.\\u003cp\\u003e2. Identification of functional groups:\\u003c/p\\u003e\\n \\u003cp\\u003ea. Alkane compounds: The peaks at 2962, 2921, 2851, 1455, 1374, and 727 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e correspond to the asymmetric and symmetric stretching vibrations of the C-H bonds in the methyl (CH\\u003csub\\u003e3\\u003c/sub\\u003e) and methylene (CH\\u003csub\\u003e2\\u003c/sub\\u003e) groups, as well as the C-H bending and rocking modes. These are characteristic of the aliphatic hydrocarbon chains present in the asphaltene structure.\\u003c/p\\u003e\\n \\u003cp\\u003eb. Aromatic compounds: The peaks in the range of 3000\\u0026ndash;3100, 1601, 864, 801, and 750 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e are associated with the C-H stretching and bending vibrations of the aromatic rings within the asphaltene structure.\\u003c/p\\u003e\\n \\u003cp\\u003ec. Amine and alcoholic groups: The broad peak observed in the range of 3100\\u0026ndash;3500 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e is attributed to the N-H and O-H stretching vibrations of amine and alcoholic functional groups, respectively.\\u003c/p\\u003e\\n \\u003cp\\u003ed. Carbonyl group (C\\u0026thinsp;=\\u0026thinsp;O): The peak at 1700 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e corresponds to the C\\u0026thinsp;=\\u0026thinsp;O stretching vibration, which is characteristic of carbonyl-containing functional groups, such as ketones, aldehydes, or carboxylic acids.\\u003c/p\\u003e\\n \\u003cp\\u003ee. C-O stretching: The peaks at 1262 and 1096 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e are associated with the C-O stretching vibrations, which are common in various oxygen-containing functional groups, such as alcohols, ethers, or esters.\\u003c/p\\u003e\\n \\u003cp\\u003ef. Sulfoxide functional group: The peak at 1022 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e is characteristic of the S\\u0026thinsp;=\\u0026thinsp;O stretching vibration of the sulfoxide functional group.\\u003c/p\\u003e\\n \\u003cp\\u003eThe absence of new peaks in the FTIR spectrum suggests that the treatment did not introduce any structural changes or the generation of new functional groups within the asphaltene. The observed peaks are consistent with the functional groups and chemical compounds that were already present in the asphaltene before the treatment. This FTIR analysis provides valuable insights into the chemical composition and structural integrity of the asphaltene sample after the treatment, which is important for understanding the changes in the physical and chemical properties of the asphaltene (Rochdi and Landais, 1991; Scotti and Montanari, 1998; Hemmati-Sarapardeh \\u003cem\\u003eet al.\\u003c/em\\u003e, 2018; Karami, Saeedi Dehaghani and Hossein Seyed Mousavi, 2020; Karami, Saeedi Dehaghani and Haghighi, 2021; Taherian \\u003cem\\u003eet al.\\u003c/em\\u003e, 2021). As shown in Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e3\\u003c/span\\u003e, the alkane compounds vibrate at peaks of 2962, 2921, 2851, 1455, 1374, and 727 cm\\u003csup\\u003e\\u0026minus;\\u0026thinsp;1\\u003c/sup\\u003e, which represent the asymmetric stretch of CH\\u003csub\\u003e3\\u003c/sub\\u003e, the asymmetric stretch of CH\\u003csub\\u003e2\\u003c/sub\\u003e, the symmetric stretch of CH\\u003csub\\u003e2\\u003c/sub\\u003e, C\\u0026ndash;H bend or scissoring, C\\u0026ndash;H rock, and C-H in long-chain alkane, respectively.\\u003c/p\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Tab3\\\" border=\\\"1\\\"\\u003e\\n \\u003ccaption\\u003e\\n \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 3\\u003c/div\\u003e\\n \\u003cdiv class=\\\"CaptionContent\\\"\\u003e\\n \\u003cp\\u003eFTIR assignments of crude and treated asphaltene spectra (Rochdi and Landais, 1991; Scotti and Montanari, 1998; Hemmati-sarapardeh and Dabir, 2018; Karami, Saeedi Dehaghani and Hossein Seyed Mousavi, 2020; Karami, Saeedi Dehaghani and Haghighi, 2021; Taherian \\u003cem\\u003eet al.\\u003c/em\\u003e, 2021; Karami, Hossein and Dehaghani, 2022a .)\\u003c/p\\u003e\\n \\u003c/div\\u003e\\n \\u003c/caption\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eWavelengths\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAssignments\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e4000\\u0026thinsp;\\u0026minus;\\u0026thinsp;3500\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eHydrogen-bonded O-H\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e3730\\u0026thinsp;\\u0026minus;\\u0026thinsp;3100\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eN-H, O-H\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e3100\\u0026thinsp;\\u0026minus;\\u0026thinsp;3000\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026ndash;H stretch in aromatics\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e3000\\u0026thinsp;\\u0026minus;\\u0026thinsp;2943\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCH3 asymmetric stretch\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e2943\\u0026thinsp;\\u0026minus;\\u0026thinsp;2877\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCH2 asymmetric stretch\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e2877\\u0026thinsp;\\u0026minus;\\u0026thinsp;2769\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCH2 symmetric Stretch\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1613\\u0026ndash;1800\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026thinsp;=\\u0026thinsp;O stretch in ketones, aldehydes, and carboxylic acids\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1613\\u0026thinsp;\\u0026minus;\\u0026thinsp;1500\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAromatic C-C stretch\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1500\\u0026thinsp;\\u0026minus;\\u0026thinsp;1400\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026ndash;H bend or scissoring in alkanes\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1400\\u0026thinsp;\\u0026minus;\\u0026thinsp;1340\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026ndash;H rock in Alkane\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1340\\u0026thinsp;\\u0026minus;\\u0026thinsp;1200\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC-O stretching\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1200\\u0026thinsp;\\u0026minus;\\u0026thinsp;1060\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026ndash;N stretch\\u0026nbsp;in aliphatic amines/C-O-C stretching in ether\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1060\\u0026thinsp;\\u0026minus;\\u0026thinsp;910\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eStretching of the S\\u0026thinsp;=\\u0026thinsp;O bond in sulfoxides\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e910\\u0026thinsp;\\u0026minus;\\u0026thinsp;840\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC-H bending in an aromatic ring with 1 H\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e840\\u0026thinsp;\\u0026minus;\\u0026thinsp;765\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC-H bending in an aromatic ring with 2 H\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e765\\u0026thinsp;\\u0026minus;\\u0026thinsp;730\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC-H bending in an aromatic ring with 3H\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e730\\u0026thinsp;\\u0026minus;\\u0026thinsp;710\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC-H in long-chain alkanes\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n \\u003cp\\u003eThe integral areas of the peaks were calculated from valley to valley in the FTIR spectrum. By knowing the integral areas, the condensing, aliphaticity, sulfoxide, carbonyl, polar, and aliphatic chain length indexes can be calculated using Eqs.\\u0026nbsp;3\\u0026ndash;6 (Hemmati-sarapardeh and Dabir, 2018; Zojaji, Esfandiarian and Taheri-shakib, 2020; Karami, Hossein and Dehaghani, 2022a, Tanhaei et al, 2023). The characteristic indices are shown in Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e4\\u003c/span\\u003e.\\u003c/p\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Taba\\\" border=\\\"1\\\"\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e\\u003cspan class=\\\"InlineEquation\\\"\\u003e\\u003cspan class=\\\"mathinline\\\"\\u003e\\\\(Aliphatic{\\\\text{ }}length{\\\\text{ }}index{\\\\text{ }}=~\\\\frac{{{A_{2948 - 2990}}}}{{{A_{2948 - 2877}}}}\\\\)\\u003c/span\\u003e\\u003c/span\\u003e\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(3)\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e\\u003cspan class=\\\"InlineEquation\\\"\\u003e\\u003cspan class=\\\"mathinline\\\"\\u003e\\\\(\\\\:(S=O)\\\\:index=\\\\frac{{A}_{1000-1069}}{Total\\\\:area}\\\\)\\u003c/span\\u003e\\u003c/span\\u003e\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(4)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e\\u003cspan class=\\\"InlineEquation\\\"\\u003e\\u003cspan class=\\\"mathinline\\\"\\u003e\\\\(\\\\:(C=O)\\\\:index=\\\\frac{{A}_{1656-1816}}{Total\\\\:area}\\\\)\\u003c/span\\u003e\\u003c/span\\u003e\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(5)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e\\u003cspan class=\\\"InlineEquation\\\"\\u003e\\u003cspan class=\\\"mathinline\\\"\\u003e\\\\(\\\\:Polar\\\\:index=\\\\frac{{A}_{3100-3450}}{Total\\\\:area}\\\\)\\u003c/span\\u003e\\u003c/span\\u003e\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(6)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n \\u003cdiv id=\\\"Sec25\\\" class=\\\"Section3\\\"\\u003e\\n \\u003ch2\\u003e3.8.1 FTIR spectra of oil\\u003c/h2\\u003e\\n \\u003cp\\u003eThe FTIR spectrum of crude oil and oil treatment under microwave and acid is depicted in Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e9\\u003c/span\\u003e\\u0026ndash;\\u003cspan class=\\\"InternalRef\\\"\\u003e14\\u003c/span\\u003e. According to the findings in Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e4\\u003c/span\\u003e, the synchronization of microwave irradiation and acid-oil emulsification did not lead to a consistent change in the CH\\u003csub\\u003e3\\u003c/sub\\u003e/CH\\u003csub\\u003e2\\u003c/sub\\u003e index. This suggests that the processes of cracking, emulsification, and the release of light compounds all play a role in determining this index.\\u003c/p\\u003e\\n \\u003cp\\u003eIt was observed that the most polar indices are present in the petroleum phase in contact with the acid in the presence of distilled water. This indicates that distilled water generally has a lower ability to emulsify and absorb polar compounds in the emulsion, particularly the asphaltene sludge.\\u003c/p\\u003e\\n \\u003cp\\u003eFurthermore, the trend of changes in the carbonyl index mirrored the slope of the polar index. However, the sulfoxide index exhibited a decrease, indicating the breaking of these compounds from the oil phase and their subsequent cracking. This phenomenon can be attributed to the presence of heavy compounds in the sludge without microwaves, which leads to an increase in their concentration.\\u003c/p\\u003e\\n \\u003cp\\u003eIn conclusion, the FTIR spectrum analysis of crude oil and oil treatment under microwave and acid reveals valuable insights into the processes of cracking, emulsification, and compound release. The interaction between microwave irradiation, acid-oil emulsification, and the composition of the crude oil has significant implications for understanding the behavior of polar and non-polar compounds in the emulsion. These findings contribute to our understanding of the complex chemical processes involved in oil treatment and have implications for optimizing treatment strategies in the petroleum industry.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to the findings in Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e4\\u003c/span\\u003e ,the untreated crude oil has an aliphatic index of 0.567903, indicating a relatively high proportion of aliphatic hydrocarbons. This suggests that the crude oil is primarily composed of simpler hydrocarbon structures, which are typically easier to refine.The polar index is measured at 0.005365, reflecting a low concentration of polar compounds. This low value indicates that the crude oil is likely stable and less prone to issues related to polar compound interactions during processing.\\u003c/p\\u003e\\n \\u003cp\\u003eASW Treatments (100% mw-1 min, 100% mw-2 min, 100% mw-3 min): The aliphatic indices of these samples decrease from 0.487206 to 0.503384 as treatment time increases. This trend suggests that longer treatment durations may lead to a breakdown of larger aliphatic hydrocarbons into smaller, more complex molecules.\\u003c/p\\u003e\\n \\u003cp\\u003eCorrespondingly, the polar indices increase from 0.007277 to 0.007629, indicating that longer microwave treatments result in higher concentrations of polar compounds. This increase may enhance the oil\\u0026apos;s reactivity but could also complicate its processing characteristics.\\u003c/p\\u003e\\n \\u003cp\\u003eADW Treatments (100% mw-1 min, 100% mw-2 min, 100% mw-3 min): The aliphatic indices for ADW treatments show a more pronounced decrease, ranging from 0.472078 to 0.491329. This significant reduction suggests that the ADW treatment effectively breaks down aliphatic hydrocarbons, possibly converting them into smaller, more polar molecules. The polar indices for these samples are notably higher, ranging from 0.103866 to 0.131546. This substantial increase in polar compounds indicates that the ADW treatment significantly alters the chemical composition of the crude oil, potentially impacting its stability and processing characteristics.\\u003c/p\\u003e\\n \\u003cp\\u003eAFW Treatments (100% mw-1 min, 100% mw-2 min, 100% mw-3 min): The aliphatic indices for AFW treatments are relatively low, ranging from 0.481883 to 0.492344. This suggests that the AFW treatment is effective in modifying the aliphatic structure of the crude oil, although not as dramatically as the ADW treatments.The polar indices show variability but are generally lower than those for ADW treatments, indicating that AFW may lead to a more balanced composition of aliphatic and polar compounds. This balance could be advantageous for certain refining processes, allowing for better separation and processing of the crude oil.\\u003c/p\\u003e\\n \\u003cp\\u003eThe trends observed in the 100% microwave power treatments are also evident in the 60% power treatments. The aliphatic indices are consistently lower across all treatments compared to the untreated crude oil, indicating that the application of microwave energy, regardless of power level, leads to a breakdown of larger hydrocarbon structures. The polar indices exhibit variability, but the overall trend suggests that lower microwave power may result in less effective extraction of polar compounds compared to full power treatments. This indicates the importance of optimizing microwave power levels to achieve the desired balance between aliphatic and polar components.\\u003c/p\\u003e\\n \\u003cp\\u003eThe treatments significantly alter the chemical composition of the crude oil. The observed decrease in aliphatic indices suggests that the treatment processes, particularly with ADW, effectively break down larger hydrocarbons into smaller, more polar molecules. This transformation can enhance the oil\\u0026apos;s reactivity and stability, potentially making it more suitable for subsequent refining processes.\\u003c/p\\u003e\\n \\u003cp\\u003eThe data indicate that different acidic solutions and microwave conditions yield varying results in terms of aliphatic and polar content. The ADW treatments appear to be the most effective at increasing polar compound content, which may be beneficial for certain refining processes that require a higher concentration of reactive species. However, this increase in polar compounds can also complicate processing, necessitating careful consideration of treatment conditions.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Tab4\\\" border=\\\"1\\\"\\u003e\\n \\u003ccaption\\u003e\\n \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 4\\u003c/div\\u003e\\n \\u003cdiv class=\\\"CaptionContent\\\"\\u003e\\n \\u003cp\\u003eFTIR spectrum indices for oil under microwaves and in the vicinity of acidic solutions\\u003c/p\\u003e\\n \\u003c/div\\u003e\\n \\u003c/caption\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eIndex\\u003c/p\\u003e\\n \\u003cp\\u003eSubject\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003ealiphatic(CH\\u003csub\\u003e3\\u003c/sub\\u003e/CH\\u003csub\\u003e2\\u003c/sub\\u003e)\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003epolar index\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(c\\u0026thinsp;=\\u0026thinsp;o,index)\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(s\\u0026thinsp;=\\u0026thinsp;o,index)\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCrude oil\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.567903\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.005365\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.007131\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.006405\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ASW-100%mw-1min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.487206\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.007277\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.0055\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.00326\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ASW-100%mw-2min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.503384\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.007629\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.00121\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.002743\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ASW-100%mw-3min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.55366\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.131546\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.011163\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.00327\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ADW-100%mw-1min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.472078\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.103866\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.020497\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.001828\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ADW-100%mw-2min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.491329\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.121529\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.013404\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.004203\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ADW-100%mw-3min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.481883\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.13086\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.012683\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.003997\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(AFW-100%mw-1min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.502835\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.061398\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.009965\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.003186\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(AFW-100%mw-2min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.492344\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.00489\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.008059\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.003236\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(AFW-100%mw-3min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.517598\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.117343\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.015434\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.009777\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ASW-60%mw-1min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.539851\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.027009\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.008421\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.005201\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ASW-60%mw-2min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.596916\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.020592\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.011101\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.005239\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ASW-60%mw-3min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.508658\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.057809\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.004753\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.004957\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ADW-60%mw-1min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.525673\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.107264\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.023441\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.001964\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ADW-60%mw-2min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.487454\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.158595\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.017412\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.001976\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(ADW-60%mw-3min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.510906\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.055617\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.01409\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.003235\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(AFW-60%mw-1min\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.511516\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.023575\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.006214\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.004648\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(AFW-60%mw-2min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.514863\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.025613\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.011029\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.003029\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(AFW-60%mw-3min)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.484872\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.027389\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.005484\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.00495\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n \\u003c/div\\u003e\\n \\u003cdiv id=\\\"Sec26\\\" class=\\\"Section3\\\"\\u003e\\n \\u003ch2\\u003e3.8.2 FTIR spectra of asphaltene\\u003c/h2\\u003e\\n \\u003cp\\u003eThe coincidence of microwave radiation and the presence of acidic solutions has regularly increased the CH\\u003csub\\u003e3\\u003c/sub\\u003e/CH\\u003csub\\u003e2\\u003c/sub\\u003e index for asphaltene samples. This means that all three processes of cracking, emulsification, and keeping heavy compounds in parallel with each other were involved in determining this index. The trend of changes in sulfoxide and carbonyl index was an increase, which is due to the decrease of light aliphatic and aromatic compounds, which leads to an increase in the concentration of heavy polar compounds. The polar index, unlike carbonyl and sulfoxide, decreased because of the preservation of light aliphatic and aromatic compounds, which led to a decrease in the concentration of heavy polar compounds. Based on the CH\\u003csub\\u003e3\\u003c/sub\\u003e/CH\\u003csub\\u003e2\\u003c/sub\\u003e index in crude oil and oil asphaltenes under microwave radiation, which is increasing, microwave radiation mainly leads to the lengthening of alkane chains. This is due to the release of lighter alkanes from the oil due to the increase in temperature. The decrease in the polar index of asphaltene samples under microwave conditions is due to the retention of light aliphatic and aromatic compounds, which leads to a decrease in the concentration of heavy polar compounds. The increase in carbonyl and sulfoxide indices after microwave irradiation can be explained by this.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to the Table \\u003cspan class=\\\"InternalRef\\\"\\u003e5\\u003c/span\\u003e and Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e15\\u003c/span\\u003e, CH\\u003csub\\u003e3\\u003c/sub\\u003e/CH\\u003csub\\u003e2\\u003c/sub\\u003e index of petroleum asphaltenes under acidic solutions is increasing, and the presence of acidic solutions under constant temperature mainly leads to longer alkane chains. This issue is due to the release of lighter alkanes from the oil due to polarity and temperature. Polarity indices have decreased; as a result, more polar compounds participate more in the emulsion phase. According to the carbonyl index, this index has increased, so the carbonyl hydrocarbons are spread less in the emulsion (sludge). In the same way, the sulfoxide indices also changed. An increase in the sulfoxide index indicates a greater tendency of sulfur-containing compounds to be present in the sludge phase, whereas an increase in the carbonyl index indicates a lower tendency of carbonyl compounds to be present in the sludge phase. The increase in the aliphatic length index indicates the tendency of longer aliphatic compounds to be present in asphaltene sludge.\\u003c/p\\u003e\\n \\u003cp\\u003eThe values for the crude oil indicate a relatively low density (s\\u0026thinsp;=\\u0026thinsp;0 index) and low polarity (polar index). This suggests that the crude oil is composed primarily of non-polar hydrocarbons, which are less reactive and more stable. The moderate aliphatic index indicates that while there are some lighter hydrocarbons present, the overall composition leans towards heavier fractions. This combination of indices implies that the crude oil is likely to flow well under standard conditions but may not be ideal for processes requiring high reactivity or compatibility with polar solvents.\\u003c/p\\u003e\\n \\u003cp\\u003eIn this sample(100% mw-ASW-1min), the (s\\u0026thinsp;=\\u0026thinsp;0 index) shows an increase, indicating a higher density, which may be due to the interaction with salt water. The (c\\u0026thinsp;=\\u0026thinsp;0 index) also increases, suggesting a greater complexity in the hydrocarbon mixture. The polar index is lower than that of the crude oil, indicating that the treatment with salt water may have reduced the number of polar compounds present. However, the significant increase in the aliphatic index suggests that the treatment has enriched the sample with lighter aliphatic hydrocarbons, which can enhance the fluidity and flow characteristics of the oil. This could be beneficial for processes requiring easier transportation and handling.\\u003c/p\\u003e\\n \\u003cp\\u003eThe results for this sample (100% mw-AFW-1min) show a slight decrease in the (s\\u0026thinsp;=\\u0026thinsp;0 index) compared to the ASW treatment, indicating a reduction in density. However, the polar index has increased significantly, suggesting that the interaction with fresh water has introduced more polar compounds into the oil. This could imply that the treatment has extracted or transformed certain components of the crude oil, leading to a more complex mixture. The aliphatic index remains high, indicating that the sample still retains a substantial amount of lighter hydrocarbons, which may aid in maintaining good flow properties despite the increased polarity.\\u003c/p\\u003e\\n \\u003cp\\u003eThis sample(100% mw-ADW-1min) exhibits the lowest (s\\u0026thinsp;=\\u0026thinsp;0 index) and (c\\u0026thinsp;=\\u0026thinsp;0 index) values, suggesting a decrease in both density and complexity. The substantial increase in the polar index indicates that the treatment with distilled water has led to a significant incorporation of polar compounds, which could be due to the extraction of acidic or functional groups from the oil. The aliphatic index is lower than in previous samples, indicating a potential reduction in lighter aliphatic hydrocarbons. This could suggest that the distillation process may have removed some of the lighter fractions, resulting in a heavier, more polar oil that may be less suitable for applications requiring low viscosity and high fluidity.\\u003c/p\\u003e\\n \\u003cp\\u003eThe choice of treatment (salt water, fresh water, or distilled water) has a considerable influence on the oil\\u0026apos;s properties. Salt water seems to enhance the fluidity by increasing the proportion of lighter aliphatic hydrocarbons, while fresh water and distilled water treatments lead to more polar compositions, which may complicate processing.The increase in polar indices in fresh and distilled water treatments indicates that these processes may introduce more reactive functional groups, which can affect the oil\\u0026rsquo;s behavior in chemical processes, refining, and potential environmental interactions.\\u003c/p\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Tab5\\\" border=\\\"1\\\"\\u003e\\n \\u003ccaption\\u003e\\n \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 5\\u003c/div\\u003e\\n \\u003cdiv class=\\\"CaptionContent\\\"\\u003e\\n \\u003cp\\u003eFTIR spectrum indices for asphaltene samples under microwave and acidic solution\\u003c/p\\u003e\\n \\u003c/div\\u003e\\n \\u003c/caption\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eSubject\\u003c/p\\u003e\\n \\u003cp\\u003eIndex\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCrude oil\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e100%mw-ASW-1min\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e100%mw-AFW-1min\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e100%mw-ADW-1min\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(s\\u0026thinsp;=\\u0026thinsp;o,index)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.058274\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.071687\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.061325\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.050453\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e(c\\u0026thinsp;=\\u0026thinsp;o,index)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.000826\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.057284\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.019678\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.011443\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003epolar index\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.111074\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.069199\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.13096\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.233213\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003ealiphatic(CH\\u003csub\\u003e3\\u003c/sub\\u003e/CH\\u003csub\\u003e2\\u003c/sub\\u003e)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.416867\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.621257\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.634509\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.388494\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n \\u003c/div\\u003e\\n\\u003c/div\\u003e\\n\\u003cdiv id=\\\"Sec27\\\" class=\\\"Section2\\\"\\u003e\\n \\u003ch2\\u003e3.9 NMR spectroscopy of asphaltene\\u003c/h2\\u003e\\n \\u003cp\\u003eAs shown in Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e8\\u003c/span\\u003e, aromaticity is a parameter used to describe the concentration of aromatic rings in the total asphaltene. The shape factor of the asphaltene molecules, which can be calculated by dividing the ambient aromatic carbons by the total aromatic carbons, approximates the number of destroyed/vaporized aromatic rings. According to these observations, microwaves in the vicinity of acidic solutions weaken the potential for breaking aromatic rings. and acidic solutions alone are not able to break aromatic rings. Cracking of the aromatic nucleus in asphaltenes modified by microwaves in the vicinity of acidic solutions, including distilled water, is usually high. The average number of carbons in the linked alkyl chains was calculated using Dickinson\\u0026rsquo;s equation.\\u003c/p\\u003e\\n \\u003cp\\u003e\\u0026nbsp;\\u003c/p\\u003e\\n \\u003cp\\u003eIn general, by using microwaves in the vicinity of acidic solutions, the length of carbon-containing aliphatic chains increases to the center of the core of aromatic rings, and the accumulation of carbons increases in some way around the aromatic rings, indicating that the length of aliphatic chains is the asphaltene structure.\\u003c/p\\u003e\\n \\u003cp\\u003eBoth the aliphatic and aromatic parts of asphaltene are cracked due to microwaves and acidic solutions. According to the total number of aliphatic carbon, radiation and acidic solutions will not change this process.\\u003c/p\\u003e\\n \\u003cp\\u003eNote that the asphaltene mass decreased after modification with microwaves and acid solutions, which indicates the cracking of some of the asphaltene molecules into lighter hydrocarbons. These observations are somewhat consistent with the structural parameters calculated from the NMR and FTIR spectra.\\u003c/p\\u003e\\n \\u003cp\\u003eAs mentioned earlier, electromagnetic waves are composed of electric and magnetic fields that fluctuate on the basis of wave frequency, and microwaves are attributed to a part of the electromagnetic spectrum that has a wave frequency between 300 MHz and 300 GHz. Because of the electrical origin of microwaves, functional groups/materials with higher polarity are better candidates for absorbing microwave energy. While the dielectric constant of the asphaltene fraction is in the range of 4\\u0026ndash;5, the dielectric constant of alkanes is in the range of 1\\u0026ndash;2. Therefore, asphaltene is the best candidate for absorbing microwave radiation. In Fig.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e16\\u003c/span\\u003e\\u0026ndash;\\u003cspan class=\\\"InternalRef\\\"\\u003e19\\u003c/span\\u003e, we observe that the chemical shifts of crude, acid-treated, and microwave-treated asphaltenes are remarkably similar. Although both the HNMR and CNMR spectra of asphaltenes exhibit comparable peaks, slight differences in the integral area suggest changes in the concentration of specific compounds within the asphaltene molecules.\\u003c/p\\u003e\\n \\u003cp\\u003eWithin the CNMR spectra, the peaks within certain ranges indicate various carbon types: 3-18.5 ppm for terminal CH\\u003csub\\u003e3\\u003c/sub\\u003e, 18.5\\u0026ndash;23 ppm for \\u0026alpha; methyl carbons near aromatic rings, and 23\\u0026ndash;50 ppm for CH/CH\\u003csub\\u003e2\\u003c/sub\\u003e paraffinic carbons. Amines and sulfur groups are evident in the 50\\u0026ndash;60 ppm range, while \\u0026alpha; carbons near OH groups fall within 60\\u0026ndash;76 ppm. Ethers, alcohols, and esters are represented by carbons within 78\\u0026ndash;100 ppm, and aromatic carbons span 100\\u0026ndash;170 ppm. These ranges help determine the asphaltene shape factor by estimating the average number of fused aromatic rings. Peripheral aromatic carbons typically shift within 100\\u0026ndash;129 ppm, whereas quaternary aromatic carbon signals lie in the 129\\u0026ndash;170 ppm range. Carbonyl compounds exhibit distinctive shifts, C\\u0026thinsp;=\\u0026thinsp;O bonds in carboxylic acids (170\\u0026ndash;190 ppm), Quinolinic carbons (190\\u0026ndash;200 ppm), and C\\u0026thinsp;=\\u0026thinsp;O bonds in aldehydes and ketones (\\u0026gt;\\u0026thinsp;200 ppm). NMR shifts suggest the presence of amine and alcohol functional groups in the asphaltene structure, corroborated by FTIR spectra showing C-O vibration from ethers, esters, and alcohols. For a detailed breakdown of chemical shifts in the HNNMR and CNMR spectra, please refer to Tables\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e6\\u003c/span\\u003e\\u0026ndash;\\u003cspan class=\\\"InternalRef\\\"\\u003e7\\u003c/span\\u003e. (Scotti and Montanari, 1998; Ancheyta et al., 2002; Sheremata et al., 2004; Mullins et al., 2012; Poveda J., 2016; Molina, Ariza and Poveda, 2017; Joonaki et al., 2018; Karami, Hossein and Dehaghani, 2022a). Based on the NMR chemical shifts, the C-O vibration in the FTIR spectrum could be attributed to ethers, esters, and alcoholic compounds. According to the NMR shifts, both amine and alcoholic functional groups are expected in the asphaltene structure, a fact that was also shown in the FTIR spectra. More detailed information about the chemical shifts in the HNMR and CNMR spectra is shown in Tables\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e6\\u003c/span\\u003e and \\u003cspan class=\\\"InternalRef\\\"\\u003e7\\u003c/span\\u003e.\\u003c/p\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Tab6\\\" border=\\\"1\\\"\\u003e\\n \\u003ccaption\\u003e\\n \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 6\\u003c/div\\u003e\\n \\u003cdiv class=\\\"CaptionContent\\\"\\u003e\\n \\u003cp\\u003eThe assignments of chemical shifts in CNMR of crude, microwave-treated, and ultrasonic-treated asphaltenes (Scotti and Montanari, 1998; Ancheyta \\u003cem\\u003eet al.\\u003c/em\\u003e, 2002; Sheremata \\u003cem\\u003eet al.\\u003c/em\\u003e, 2004; Mullins \\u003cem\\u003eet al.\\u003c/em\\u003e, 2012; Poveda J., 2016; Molina, Ariza and Poveda, 2017; Joonaki \\u003cem\\u003eet al.\\u003c/em\\u003e, 2018; Karami, Hossein and Dehaghani, 2022a).\\u003c/p\\u003e\\n \\u003c/div\\u003e\\n \\u003c/caption\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eChemical shifts (ppm)\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAssignments\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e3-18.5\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eTerminal CH3 at the alkyl chains\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e18.5\\u0026ndash;23\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eMethyl carbons in \\u0026alpha; position to aromatic rings.\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e23\\u0026ndash;50\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCH2 and CH-type naphthenic and paraffinic carbons\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e50\\u0026ndash;60\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCH and C in paraffinic carbons; C-N in amine groups; C-S; C-S\\u0026thinsp;=\\u0026thinsp;O\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e60\\u0026ndash;76\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eParaffinic and naphthenic carbon \\u0026alpha; to OH\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e78\\u0026ndash;100\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eEther/alcohol/ester\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e100\\u0026ndash;129\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003ePeripheral aromatics\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e129\\u0026ndash;170\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eQuaternary aromatic carbon\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e170\\u0026ndash;190\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026thinsp;=\\u0026thinsp;O in Carboxylic acid\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e190\\u0026ndash;200\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eQuinolinic carbons\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e\\u0026gt;\\u0026thinsp;200\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u0026thinsp;=\\u0026thinsp;O in the aldehyde and ketone\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Tab7\\\" border=\\\"1\\\"\\u003e\\n \\u003ccaption\\u003e\\n \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 7\\u003c/div\\u003e\\n \\u003cdiv class=\\\"CaptionContent\\\"\\u003e\\n \\u003cp\\u003eThe assignments of chemical shifts in HNMR of crude, microwave-treated, and ultrasonic-treated asphaltenes (Scotti and Montanari, 1998; Ancheyta \\u003cem\\u003eet al.\\u003c/em\\u003e, 2002; Sheremata \\u003cem\\u003eet al.\\u003c/em\\u003e, 2004; Mullins \\u003cem\\u003eet al.\\u003c/em\\u003e, 2012; Poveda J., 2016; Molina, Ariza and Poveda, 2017; Joonaki \\u003cem\\u003eet al.\\u003c/em\\u003e, 2018).\\u003c/p\\u003e\\n \\u003c/div\\u003e\\n \\u003c/caption\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eChemical shifts (ppm)\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAssignments\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e0.1-1\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eParaffinic hydrogens, \\u0026gamma; and more aromatics, CH\\u003csub\\u003e3\\u003c/sub\\u003e groups.\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1\\u0026ndash;2\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eParaffinic hydrogens, \\u0026beta; to aromatics, CH\\u003csub\\u003e3\\u003c/sub\\u003e, and CH\\u003csub\\u003e2\\u003c/sub\\u003e groups.\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e2-4.5\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eCH, CH\\u003csub\\u003e2\\u003c/sub\\u003e, and CH\\u003csub\\u003e3\\u003c/sub\\u003e type, \\u0026alpha; to aromatics.\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e4.5\\u0026ndash;6.2\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eOlefinic carbons in CH and CH\\u003csub\\u003e2\\u003c/sub\\u003e\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e6.2-9\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eHydrogens in the aromatic\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e9\\u0026ndash;12\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAldehyde and carboxylic hydrogens.\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n \\u003cp\\u003eAccording to the investigations of FTIR tests, the increase in the aliphatic index is consistent with the increase in the length parameter of aliphatic chains obtained from NMR. Therefore, the proposed asphaltene structure in the hybrid method has more aliphatic chains. In other words, it can be said that by applying the hybrid method, Aliphatic chains increase.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e8\\u003c/span\\u003e, the increase in the average length apart from cracking of the aromatic core indicates that the ring opening probably occurred due to radiation and the presence of acidic solutions. Note that cracking of the aliphatic chain cannot be fixed using the length of the aliphatic chain. This is because the length of the aliphatic chain does not provide information about the cracking of the aliphatic chain. To check whether the aliphatic chains are cracked or not, the total aliphatic carbon number should be considered. By knowing the number of aromatic rings destroyed, the number of aromatic carbons can be approximated.\\u003c/p\\u003e\\n \\u003cp\\u003eAccording to Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e8\\u003c/span\\u003e,Tthe asphaltene sample (crude oil) shows a moderate aliphatic chain length of 4.93, accompanied by a significant fraction of aromatic carbon (fa\\u0026thinsp;=\\u0026thinsp;0.52356). The presence of 7 fused rings suggests a complex structure that likely contributes to its stability and reactivity. The high aromatic content (Car\\u0026thinsp;=\\u0026thinsp;0.91) indicates that this asphaltene may have strong interactions with other aromatic compounds, potentially affecting its solubility in various solvents. The average diameter (\\u0026Oslash; = 0.637363) suggests that these molecules or aggregates are relatively large, which can impact their behavior in petroleum systems, particularly in terms of flow and separation processes.\\u003c/p\\u003e\\n \\u003cp\\u003eThis compound (100%MW-ADW-1min) exhibits a longer aliphatic chain (6.886364) compared to the asphaltene sample, suggesting enhanced hydrophobicity. The fraction of aromatic carbon (fa\\u0026thinsp;=\\u0026thinsp;0.515464) remains significant, indicating a robust aromatic character. The presence of 7 fused rings, similar to the asphaltene, suggests stability and potential for strong intermolecular interactions. The average diameter (\\u0026Oslash; = 0.585106) indicates a slightly smaller size than the asphaltene, which may influence its flow characteristics in mixtures. The high aromatic content (Car\\u0026thinsp;=\\u0026thinsp;0.94) suggests that this compound may also exhibit strong interactions with other aromatic materials, which could affect its solubility and reactivity.\\u003c/p\\u003e\\n \\u003cp\\u003eThis sample(100% MW -ASW-1min) features the longest aliphatic chain (7.097561) among the analyzed compounds, indicating a potential for increased hydrophobicity and solubility challenges in polar solvents. The fraction of aromatic carbon is the highest at fa\\u0026thinsp;=\\u0026thinsp;0.581395, suggesting a strong aromatic character that could enhance stability. The presence of 6 fused rings indicates a slightly less complex structure compared to the previous samples, which may influen ce its reactivity. The average diameter (\\u0026Oslash; = 0.513889) is smaller than that of the asphaltene and MW100-ADW-1min, which could result in different behavior in terms of aggregation and flow characteristics. The lower contribution of non-aromatic carbon (Cp\\u0026thinsp;=\\u0026thinsp;0.37) suggests a more aromatic-rich structure, which may enhance interactions with other aromatic compounds. This sample (MW100-AFW-1min ) also shows a significant aliphatic chain length (6.651163) and the highest fraction of aromatic carbon (fa\\u0026thinsp;=\\u0026thinsp;0.588235) among the analyzed compounds. The presence of 6 fused rings suggests a stable structure, although slightly less complex than the asphaltene (crude) and 100%MW-ADW-1min. The average diameter (\\u0026Oslash; = 0.514286) indicates a size that may facilitate different interactions in mixtures. The relatively lower contribution of non-aromatic carbon (Cp\\u0026thinsp;=\\u0026thinsp;0.36) further emphasizes the aromatic nature of this compound, which may affect its stability and interactions with other hydrocarbons.\\u003c/p\\u003e\\n \\u003cp\\u003eThe data presented in the table provides significant insights into the structural characteristics of asphaltenes and related compounds. All samples exhibit substantial aromatic character, which is crucial for predicting behavior in petroleum systems. The higher the fraction of aromatic carbon, the more stable and reactive the compound may be. The length of the aliphatic chains influences solubility and hydrophobicity. Compounds with longer chains may exhibit different behaviors in solvent interactions, potentially complicating extraction and refining processes.\\u003c/p\\u003e\\n \\u003cp\\u003eThe number of fused rings is a critical factor in determining the stability and reactivity of these compounds. Higher numbers of fused rings generally correlate with increased stability, which is essential for understanding how these materials will behave during processing and in environmental contexts.\\u003c/p\\u003e\\n \\u003cp\\u003eThe average diameter of the molecules or aggregates can significantly impact their flow characteristics and separation behavior in mixtures. Larger aggregates may settle or separate more readily, while smaller ones may remain suspended.\\u003c/p\\u003e\\n \\u003cp\\u003eCalculation of the integral areas in Table\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e8\\u003c/span\\u003e provides clues for interpreting any alteration to the asphaltene structural parameters (Poveda J., 2016; Joonaki \\u003cem\\u003eet al.\\u003c/em\\u003e, 2018). Eqs.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e7\\u003c/span\\u003e\\u0026ndash;\\u003cspan class=\\\"InternalRef\\\"\\u003e9\\u003c/span\\u003e were used to characterize the molecular structure of the asphaltenes. Eq.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e7\\u003c/span\\u003e describes the shape factor of the asphaltene molecules by dividing the peripheral aromatic carbons, which cover the chemical shifts of 100\\u0026ndash;129 ppm, by the whole aromatic carbons, which lie in the range of 100\\u0026ndash;170 ppm (Sheremata \\u003cem\\u003eet al.\\u003c/em\\u003e, 2004). Eq.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e8\\u003c/span\\u003e describes the aromaticity of the asphaltene molecules by dividing the aromatic carbons by all of the aromatic and aliphatic carbons, which lie in the range of 3\\u0026ndash;60 ppm (Poveda J., 2016). Eq.\\u0026nbsp;\\u003cspan class=\\\"InternalRef\\\"\\u003e9\\u003c/span\\u003e, which is the Dickson equation, employs \\u0026alpha;, \\u0026beta;, and \\u0026gamma; hydrogens (respect to the aromatic rings) to approximate the length of the associated alkyl group attaching to the fused aromatic rings.\\u003c/p\\u003e\\n \\u003cdiv id=\\\"Equ3\\\" class=\\\"Equation\\\"\\u003e\\n \\u003cdiv id=\\\"FileID_Equ3\\\" class=\\\"mathdisplay\\\"\\u003e$$\\\\varphi =\\\\frac{{{C_p}}}{{{C_a}}}$$\\u003c/div\\u003e\\n \\u003cdiv class=\\\"EquationNumber\\\"\\u003e7\\u003c/div\\u003e\\n \\u003c/div\\u003e\\n \\u003cdiv id=\\\"Equ4\\\" class=\\\"Equation\\\"\\u003e\\n \\u003cdiv id=\\\"FileID_Equ4\\\" class=\\\"mathdisplay\\\"\\u003e$${f_a}=\\\\frac{{{C_{ar}}}}{{{C_{ar}}+{C_{al}}}}$$\\u003c/div\\u003e\\n \\u003cdiv class=\\\"EquationNumber\\\"\\u003e8\\u003c/div\\u003e\\n \\u003c/div\\u003e\\n \\u003cdiv id=\\\"Equ5\\\" class=\\\"Equation\\\"\\u003e\\n \\u003cdiv id=\\\"FileID_Equ5\\\" class=\\\"mathdisplay\\\"\\u003e$$n=\\\\frac{{{H_1}\\\\left( {0.1 - 1} \\\\right)+{H_2}\\\\left( {1 - 2} \\\\right)+{H_3}\\\\left( {2 - 4.5} \\\\right)~}}{{{H_3}\\\\left( {2 - 4.5} \\\\right)~}}~$$\\u003c/div\\u003e\\n \\u003cdiv class=\\\"EquationNumber\\\"\\u003e9\\u003c/div\\u003e\\n \\u003c/div\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"char\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003e\\n \\u003ctable id=\\\"Tab8\\\" border=\\\"1\\\"\\u003e\\n \\u003ccaption\\u003e\\n \\u003cdiv class=\\\"CaptionNumber\\\"\\u003eTable 8\\u003c/div\\u003e\\n \\u003cdiv class=\\\"CaptionContent\\\"\\u003e\\n \\u003cp\\u003eparameters calculated from the NMR spectra\\u003c/p\\u003e\\n \\u003c/div\\u003e\\n \\u003c/caption\\u003e\\n \\u003cthead\\u003e\\n \\u003ctr\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eParameters\\u003c/p\\u003e\\n \\u003cp\\u003eSubject\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAliphatic chain length\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cdiv class=\\\"gridtable\\\"\\u003e\\n \\u003cdiv class=\\\"colspec\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/div\\u003eAliphatic chain length\\n \\u003c/div\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003ef\\u003csub\\u003ea\\u003c/sub\\u003e\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eFused ring number\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e\\u0026Oslash;\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u003csub\\u003eal\\u003c/sub\\u003e\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u003csub\\u003ep\\u003c/sub\\u003e\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003cth align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eC\\u003csub\\u003ear\\u003c/sub\\u003e\\u003c/p\\u003e\\n \\u003c/th\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/thead\\u003e\\n \\u003ctbody\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eAliphatic chain length\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd colspan=\\\"8\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003easphaltene(oil)\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e4.932432\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e0. 52356\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e7\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.637363\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.58\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.91\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd colspan=\\\"1\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eMW100-ADW-1min\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e6.886364\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e0.515464\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e7\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.585106\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.55\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.94\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd colspan=\\\"1\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eMW100-ASW-1min\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e7.097561\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e0.581395\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e6\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.513889\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.37\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.72\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd colspan=\\\"1\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003ctr\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003eMW100-AFW-1min\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e6.651163\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e0.588235\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e6\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.514286\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"left\\\"\\u003e\\n \\u003cp\\u003e1\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.36\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd align=\\\"char\\\"\\u003e\\n \\u003cp\\u003e0.7\\u003c/p\\u003e\\n \\u003c/td\\u003e\\n \\u003ctd colspan=\\\"1\\\" align=\\\"left\\\"\\u003e\\u0026nbsp;\\u003c/td\\u003e\\n \\u003c/tr\\u003e\\n \\u003c/tbody\\u003e\\n \\u003c/table\\u003e\\n \\u003c/div\\u003e\\n\\u003c/div\\u003e\"},{\"header\":\"4. Conclusion\",\"content\":\"\\u003cp\\u003e1- According to FTIR tests, polar functional groups increase compared to other crude oil compounds, and the reason for this is the direct effect of microwaves on polar compounds, as well as the effect of acidic solutions through reaction with polar components of crude oil.\\u003c/p\\u003e \\u003cp\\u003e2- The tests related to fluid and fluid (surface tension and densitometry, etc.) will be by hybrid method alternately (increasing and decreasing) and the reason for that is the direct effect of microwave waves as well as the polarity of the waves. The solution is acidic and the pH fluctuates, but over time, this trend generally increases.\\u003c/p\\u003e \\u003cp\\u003e3- The amount of asphaltene resulting from the above hybrid method will decrease, but this decrease will be minor. Moreover, according to the NMR experiment, there are more carbons attached to aromatic rings in the asphaltene structure compared to carbons attached to aliphatic chains.\\u003c/p\\u003e \\u003cp\\u003e4- The results show that microwave radiation in the vicinity of acid solutions causes the cutting of carbon chains with high molecular weight, but after a long period of radiation, it seems that the lower hydrocarbon chains are recombined and the carbon chains are larger, longer and more branched. form. Asphalt sludge is reduced under microwaves.\\u003c/p\\u003e \\u003cp\\u003e5- With increasing salinity, the amount of water ions increases, which leads to a further increase in the absorption capacity of microwaves, which is different according to the dielectric of the target solutions.\\u003c/p\\u003e \\u003cp\\u003e6- Microwaves in the vicinity of acid solutions can change the viscosity of heavy oil. This change increases completely at some power levels and decreases at others during a certain period of radiation. There are no general rules for predicting this behavior. But in cases where the breaking of heavy asphaltene particles has a greater effect on the release of light gases, the viscosity of the oil decreases.\\u003c/p\\u003e\"},{\"header\":\"Declarations\",\"content\":\"\\u003ch2\\u003eAuthor Contribution\\u003c/h2\\u003e\\u003cp\\u003eAll authors reviewed the manuscript.\\u003c/p\\u003e\\u003ch2\\u003eData Availability\\u003c/h2\\u003e\\u003cp\\u003eThe datasets generated and/or analysed during the current study are not publicly available due to privacy concerns regarding patient confidentiality, but are available from the corresponding author on reasonable request.\\u003c/p\\u003e\"},{\"header\":\"References\",\"content\":\"\\u003col\\u003e\\u003cli\\u003e\\u003cspan\\u003eAbdollahi, R., Shadizadeh, S. R., Zargar, G., 2014. Experimental investigation of acid-induced sludge precipitation: using acid additives in Iran. Energy Sources, Part A. 36, 1793\\u0026ndash;1799.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eAkbazadeh, K., Hammani, A., Kharrat, A., 2007. Asphaltenes: problematic but rich in potential. Oilfield Rev.19 (summer 2), 22\\u0026ndash;43.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eAlmehaideb, R.A., 2004. Asphaltene precipitation and deposition in the near wellbore region: a modeling approach. J. Petrol. Sci. Eng. 42 (2\\u0026ndash;4), 157\\u0026ndash;170.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eAl-Mubarak, T. A., Al-Khaldi, M. H., Al-Ibrahim, et al., 2015. Investigation of acid-induced emulsion formation and asphaltene precipitation in low permeability carbonate reservoirs. Paper presented at the SPE Saudi Arabia Section Annual Technical Symposium and Exhibition, Al-Khobar, Saudi Arabia, SPE-178034, Apr. 21\\u0026ndash;23\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eBancroft, W.D., 1913. Theory of Emulsification. Phys. Chem. 17, 501.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eBarker, K. M. and Newberry, M. E., 2007. Inhibition and removal of low-pH fluid-induced asphaltic sludge fouling of formations in oil and gas wells. Paper presented at the SPE International Symposium on Oil Field Chemistry, Houston, Texas, USA, SPE 102738, Feb. 28 \\u0026ndash; Mar.https://doi.org/10.2118/102738-MS. PTED MANUSCRIPT\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eBobra, M.A., 1990. A Study of the Formation of Water-in-Oil Emulsions. Proceedings of the 13th Arctic and Marine Oil Spill Program Technical Seminar, Edmonton, Alberta, Canada, June 6\\u0026ndash;8, 485 p.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eBulletin RP-42, Laboratory Testing of Surface Active Agents for Well Stimulation, Second Edition, API, Washington, DC, Dallas (January 1977, Reaffirmed February 1990) .\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eCarbognani, L., Orea, M., Fonseca M. 1999. Complex nature of the separated solid phases from crude oils. Energy Fuels 13, 351\\u0026ndash;358.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eChen, H.S. \\u003cem\\u003eet al.\\u003c/em\\u003e (2020) \\u0026lsquo;Research on Treatment of Oily Sludge from the Tank Bottom by Ball Milling Combined with Ozone-Catalyzed Oxidation\\u0026rsquo;, \\u003cem\\u003eACS Omega\\u003c/em\\u003e, 5(21). Available at https://doi.org/10.1021/acsomega.0c00958.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eCheng, S. \\u003cem\\u003eet al.\\u003c/em\\u003e (2017) \\u0026lsquo;Effect of steam and oil sludge ash additive on the products of oil sludge pyrolysis\\u0026rsquo;, \\u003cem\\u003eApplied Energy\\u003c/em\\u003e, 185. Available at https://doi.org/10.1016/j.apenergy.2016.10.055.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eDaaou, M. \\u003cem\\u003eet al.\\u003c/em\\u003e (2008) \\u0026lsquo;Characterization of the nonstable fraction of Hassi-Messaoud asphaltenes\\u0026rsquo;, \\u003cem\\u003eEnergy and Fuels\\u003c/em\\u003e, 22(5). Available at https://doi.org/10.1021/ef800078u.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eDavid, H., Resnick, R., \\u0026amp; Walker, J. (2015). Fundamental \\u003cem\\u003eof Physics\\u003c/em\\u003e. \\u003cem\\u003eJournal of Chemical Information and Modeling\\u003c/em\\u003e.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eDean, A., Morris, M., Stufken, J., Bingham, D., 2015. Handbook of Design and Analysis of Experiments. CRC Press. Taylor \\u0026amp; Francis, London\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eDelorey, J. R., Taylor, R. S., 1985. Recent studies on iron/surfactant /sludge interactions in acidizing. Paper presented at Petroleum Society Annual Meeting, Edmonton, Alberta, PETSOC-85-36-38, June 2\\u0026ndash;5, 85\\u0026ndash;89. https://doi.org/10.2118/85-36-38.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eFigueroa-Ortiz, V., Cazares-Robles, F., Fragachan, F. E., 1996. Controlling Organic deposits and sludge in a hostile environment. Paper presented at the Formation Damage Control Symposium, Lafayette. Louisiana, SPE 31124, Feb. 14\\u0026ndash;15 https://doi.org/10.2118/31124-MS.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eFingas, M.F., Fieldhouse, B., Bobra, M.A. et al., 1993 \\u0026ldquo;The Physics and Chemistry Of Emulsions. Proceedings of the Workshop on Emulsions, Marine Spill Response Corporation, Washington, D.C., 11 p.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eFredd, C. N., Fogler, H. S., 1998. Alternative stimulation fluids and their impact on carbonate acidizing. SPE J. 13, 34\\u0026ndash;41.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eGarrouch, A. A., Malallah, A. H., 2007. Empirical model for predicting crude Sludging potential caused by acidizing. IJPST 1 (1), 23\\u0026ndash;36.\\u003c/span\\u003e\\u003c/li\\u003e \\u003cli\\u003e\\u003cspan\\u003eHouchin, L. R. and Hudson, L. M. 1986. Prediction, evaluation, and treatment of Formation damage caused by organic deposition. 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Available at https://doi.org/10.1016/j.jhazmat.2011.12.016.\\u003c/span\\u003e\\u003c/li\\u003e\\u003c/ol\\u003e\"}],\"fulltextSource\":\"\",\"fullText\":\"\",\"funders\":[],\"hasAdminPriorityOnWorkflow\":false,\"hasManuscriptDocX\":true,\"hasOptedInToPreprint\":true,\"hasPassedJournalQc\":\"\",\"hasAnyPriority\":false,\"hideJournal\":false,\"highlight\":\"\",\"institution\":\"\",\"isAcceptedByJournal\":true,\"isAuthorSuppliedPdf\":false,\"isDeskRejected\":\"\",\"isHiddenFromSearch\":false,\"isInQc\":false,\"isInWorkflow\":false,\"isPdf\":false,\"isPdfUpToDate\":true,\"isWithdrawnOrRetracted\":false,\"journal\":{\"display\":true,\"email\":\"info@researchsquare.com\",\"identity\":\"scientific-reports\",\"isNatureJournal\":false,\"hasQc\":true,\"allowDirectSubmit\":false,\"externalIdentity\":\"scirep\",\"sideBox\":\"Learn more about [Scientific Reports](http://www.nature.com/srep/)\",\"snPcode\":\"\",\"submissionUrl\":\"\",\"title\":\"Scientific Reports\",\"twitterHandle\":\"\",\"acdcEnabled\":true,\"dfaEnabled\":true,\"editorialSystem\":\"stoa\",\"reportingPortfolio\":\"Scientific Reports\",\"inReviewEnabled\":true,\"inReviewRevisionsEnabled\":true},\"keywords\":\"Acidizing, production efficiency, microwave radiation, hybrid method, asphaltene hydrocarbons\",\"lastPublishedDoi\":\"10.21203/rs.3.rs-5327813/v1\",\"lastPublishedDoiUrl\":\"https://doi.org/10.21203/rs.3.rs-5327813/v1\",\"license\":{\"name\":\"CC BY 4.0\",\"url\":\"https://creativecommons.org/licenses/by/4.0/\"},\"manuscriptAbstract\":\"\\u003cp\\u003eAcidizing boosts well production, while microwave radiation techniques and hybrid methods are emerging to enhance hydrocarbon extraction and oil production efficiency. In this research, the interaction between microwave radiation and working acid on crude oil was systematically investigated. Crude oil samples were positioned adjacent to an acid solution and subsequently subjected to microwave radiation at power levels of 1300 watt(100% Microwave) and 780 watt (60% Microwave) for durations of 1, 2, and 3 minutes. A comprehensive suite of analyses was performed, including viscometric assessments, interfacial tension measurements, density measurements, asphaltene quantification via extraction tests, sludge analysis, nuclear magnetic resonance (NMR) spectroscopy, pH measurements, and Fourier transform infrared spectroscopy (FTIR). The results indicate that the polarity of both the crude oil and the acid solution enhances the absorption of microwave radiation. FTIR analysis revealed an increase in polar functional groups relative to non-polar groups, suggesting significant molecular interactions, which NMR test also proves this trend. Furthermore, viscometric and surface tension tests demonstrated that increased polarity correlates with enhanced microwave absorption. The combined method, which is characterized by the simultaneous presence of polar acid solution and an electromagnetic field, led to alternating fluctuations (increase and decrease) of surface tension, viscosity, density, pH, and sludge during the tested process. It also caused a decrease in the concentration of asphaltene hydrocarbons, The reason for these intermittent changes is the simultaneous effects of changes in the strength of acid solutions and increasing or decreasing the power of microwave radiation at a certain time.\\u003c/p\\u003e\",\"manuscriptTitle\":\"Investigating the improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwaves radiation during acidizing based on hydrochloric acid\",\"msid\":\"\",\"msnumber\":\"\",\"nonDraftVersions\":[{\"code\":1,\"date\":\"2024-11-29 11:57:41\",\"doi\":\"10.21203/rs.3.rs-5327813/v1\",\"editorialEvents\":[{\"type\":\"communityComments\",\"content\":0},{\"type\":\"decision\",\"content\":\"Revision requested\",\"date\":\"2024-12-23T06:34:19+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"editorInvitedReview\",\"content\":\"\",\"date\":\"2024-12-12T16:18:08+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"editorInvitedReview\",\"content\":\"\",\"date\":\"2024-11-23T20:31:15+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewerAgreed\",\"content\":\"32005306668077291223837994078322196135\",\"date\":\"2024-11-19T18:38:32+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewerAgreed\",\"content\":\"27551813660377848580332988244377436900\",\"date\":\"2024-11-19T13:20:42+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewersInvited\",\"content\":\"\",\"date\":\"2024-11-19T12:52:35+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"editorAssigned\",\"content\":\"\",\"date\":\"2024-11-16T06:57:41+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"editorInvited\",\"content\":\"\",\"date\":\"2024-11-12T17:37:19+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"checksComplete\",\"content\":\"\",\"date\":\"2024-11-12T05:15:05+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"submitted\",\"content\":\"Scientific Reports\",\"date\":\"2024-10-24T18:01:09+00:00\",\"index\":\"\",\"fulltext\":\"\"}],\"status\":\"published\",\"journal\":{\"display\":true,\"email\":\"info@researchsquare.com\",\"identity\":\"scientific-reports\",\"isNatureJournal\":false,\"hasQc\":true,\"allowDirectSubmit\":false,\"externalIdentity\":\"scirep\",\"sideBox\":\"Learn more about [Scientific Reports](http://www.nature.com/srep/)\",\"snPcode\":\"\",\"submissionUrl\":\"\",\"title\":\"Scientific Reports\",\"twitterHandle\":\"\",\"acdcEnabled\":true,\"dfaEnabled\":true,\"editorialSystem\":\"stoa\",\"reportingPortfolio\":\"Scientific Reports\",\"inReviewEnabled\":true,\"inReviewRevisionsEnabled\":true}}],\"origin\":\"\",\"ownerIdentity\":\"704192a5-5abc-4acc-b59d-7a7ca2bb52e5\",\"owner\":[],\"postedDate\":\"November 29th, 2024\",\"published\":true,\"recentEditorialEvents\":[],\"rejectedJournal\":[],\"revision\":\"\",\"amendment\":\"\",\"status\":\"published-in-journal\",\"subjectAreas\":[{\"id\":40664427,\"name\":\"Physical sciences/Engineering\"},{\"id\":40664428,\"name\":\"Physical sciences/Engineering/Chemical engineering\"}],\"tags\":[],\"updatedAt\":\"2025-03-10T20:03:01+00:00\",\"versionOfRecord\":{\"articleIdentity\":\"rs-5327813\",\"link\":\"https://doi.org/10.1038/s41598-025-91932-x\",\"journal\":{\"identity\":\"scientific-reports\",\"isVorOnly\":false,\"title\":\"Scientific Reports\"},\"publishedOn\":\"2025-03-03 15:58:23\",\"publishedOnDateReadable\":\"March 3rd, 2025\"},\"versionCreatedAt\":\"2024-11-29 11:57:41\",\"video\":\"\",\"vorDoi\":\"10.1038/s41598-025-91932-x\",\"vorDoiUrl\":\"https://doi.org/10.1038/s41598-025-91932-x\",\"workflowStages\":[]},\"version\":\"v1\",\"identity\":\"rs-5327813\",\"journalConfig\":\"researchsquare\"},\"__N_SSP\":true},\"page\":\"/article/[identity]/[[...version]]\",\"query\":{\"redirect\":\"/article/rs-5327813\",\"identity\":\"rs-5327813\",\"version\":[\"v1\"]},\"buildId\":\"qtupq5eGEP_6zYnWcrvyt\",\"isFallback\":false,\"isExperimentalCompile\":false,\"dynamicIds\":[84888],\"gssp\":true,\"scriptLoader\":[]}","source_license":"CC-BY-4.0","license_restricted":false}