{"paper_id":"04e9b077-32c9-48a8-b42e-fab0f837fdee","body_text":"Sodion Induced Interfacial Polarization and π‒π Synergy Enable Irreversible Dye Adsorption in g‒C3N4 Quantum Dot–Embedded Hydrogels | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Sodion Induced Interfacial Polarization and π‒π Synergy Enable Irreversible Dye Adsorption in g‒C 3 N 4 Quantum Dot–Embedded Hydrogels Qi Cui, Xiang Li, Xiaochuan Li, Wenjian Fang This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-8429060/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 10 Apr, 2026 Read the published version in Journal of Polymers and the Environment → Version 1 posted 11 You are reading this latest preprint version Abstract Hydrogel-based composites have attracted increasing attention for dye removal owing to their tunable porous networks and excellent recyclability. In this study, two quantum dot/polyacrylamid·e (PAM) hydrogels, g‒C 3 N 4 quantum dot (CNQD/PAM) and TiO 2 quantum dot (TDQD/PAM), were synthesized and systematically compared in terms of their adsorption–desorption behavior toward methylene blue (MB). CNQD/PAM exhibited a significantly higher adsorption capacity, slower desorption rate, and stronger dye retention than TDQD/PAM. Kinetic fitting using a dual-site diffusion–adsorption model revealed that CNQD/PAM possesses a greater fraction of strong and irreversible adsorption sites, while both hydrogels exhibit comparable diffusion resistance. Spectroscopic and pH-dependent analyses further demonstrated that the superior performance of CNQD/PAM originates from the synergistic effects of π‒π stacking, hydrogen bonding, and Na + induced electrostatic attraction. These findings elucidate the mechanism by which alkali-metal-modified g‒C 3 N 4 enhances dye binding in hydrogel composites and provide valuable insights for designing durable, high-capacity, and recyclable adsorption materials. g‒C3N4 quantum dots Hydrogel Interfacial polarization π‒π interaction Electrostatic adsorption Irreversible dye retention Adsorption kinetics Full Text Additional Declarations No competing interests reported. Supplementary Files SI.docx Cite Share Download PDF Status: Published Journal Publication published 10 Apr, 2026 Read the published version in Journal of Polymers and the Environment → Version 1 posted Editorial decision: Revision requested 30 Jan, 2026 Reviews received at journal 25 Jan, 2026 Reviews received at journal 13 Jan, 2026 Reviews received at journal 07 Jan, 2026 Reviewers agreed at journal 05 Jan, 2026 Reviewers agreed at journal 04 Jan, 2026 Reviewers agreed at journal 03 Jan, 2026 Reviewers invited by journal 02 Jan, 2026 Editor assigned by journal 25 Dec, 2025 Submission checks completed at journal 25 Dec, 2025 First submitted to journal 22 Dec, 2025 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {\"props\":{\"pageProps\":{\"initialData\":{\"identity\":\"rs-8429060\",\"acceptedTermsAndConditions\":true,\"allowDirectSubmit\":false,\"archivedVersions\":[],\"articleType\":\"Research Article\",\"associatedPublications\":[],\"authors\":[{\"id\":569063973,\"identity\":\"13bbfbc8-7959-4a1c-bd82-aa907e728065\",\"order_by\":0,\"name\":\"Qi Cui\",\"email\":\"\",\"orcid\":\"\",\"institution\":\"Yangzhou University\",\"correspondingAuthor\":false,\"prefix\":\"\",\"firstName\":\"Qi\",\"middleName\":\"\",\"lastName\":\"Cui\",\"suffix\":\"\"},{\"id\":569063974,\"identity\":\"55fed11b-66ab-42f6-b837-3ea37a26f1a5\",\"order_by\":1,\"name\":\"Xiang Li\",\"email\":\"\",\"orcid\":\"\",\"institution\":\"Yangzhou University\",\"correspondingAuthor\":false,\"prefix\":\"\",\"firstName\":\"Xiang\",\"middleName\":\"\",\"lastName\":\"Li\",\"suffix\":\"\"},{\"id\":569063975,\"identity\":\"41ec89eb-ae45-4b20-9c97-fb3fc78f03ed\",\"order_by\":2,\"name\":\"Xiaochuan Li\",\"email\":\"\",\"orcid\":\"\",\"institution\":\"Yangzhou University\",\"correspondingAuthor\":false,\"prefix\":\"\",\"firstName\":\"Xiaochuan\",\"middleName\":\"\",\"lastName\":\"Li\",\"suffix\":\"\"},{\"id\":569063976,\"identity\":\"0016a40b-e7c1-4270-b1e9-81e927d2a61e\",\"order_by\":3,\"name\":\"Wenjian Fang\",\"email\":\"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAAy0lEQVRIie3QsQrCMBCA4SuFdrnB8aRQn0AIFJykfZUEQVfHbrYI8Rl8CyfnKx261N2xfYM+gZpubskomH87yJcjAfD5frC4AsVluU2Lrq7HyYUgg+S+32fQt+eMHAnwQ7eqeh70Ap0IyYE5CoP6OmogyNN1ZSeSGaMwTJQejrDLNmwhRSJlOxFGUaIugoDV3UYwmbcIQlw2mtCdSEFEgStZDYYYI1CZTxYOb0Hs1dC83qdb3I3jVOaplRgkvwZhPT4X22/1+Xy+P+8DxTZI94ow58sAAAAASUVORK5CYII=\",\"orcid\":\"\",\"institution\":\"Yangzhou University\",\"correspondingAuthor\":true,\"prefix\":\"\",\"firstName\":\"Wenjian\",\"middleName\":\"\",\"lastName\":\"Fang\",\"suffix\":\"\"}],\"badges\":[],\"createdAt\":\"2025-12-23 01:38:26\",\"currentVersionCode\":1,\"declarations\":\"\",\"doi\":\"10.21203/rs.3.rs-8429060/v1\",\"doiUrl\":\"https://doi.org/10.21203/rs.3.rs-8429060/v1\",\"draftVersion\":[],\"editorialEvents\":[{\"content\":\"https://doi.org/10.1007/s10924-026-03807-5\",\"type\":\"published\",\"date\":\"2026-04-10T15:59:04+00:00\"}],\"editorialNote\":\"\",\"failedWorkflow\":false,\"files\":[{\"id\":99516367,\"identity\":\"ad32edbd-9350-4d8a-999a-c82f9a4ed72d\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:38\",\"extension\":\"docx\",\"order_by\":0,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2455173,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"text.docx\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/4b082c18f829fddaf4260979.docx\"},{\"id\":99516375,\"identity\":\"1c0544ca-b67c-40a3-9066-434ae0126e7e\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:38\",\"extension\":\"json\",\"order_by\":1,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":5445,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"76382d3723c249a5859bcc47948ed975.json\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/94fcccb9977571b6d4b8f8af.json\"},{\"id\":99792348,\"identity\":\"c0d17ee8-9f99-4672-9b23-3081c78cb513\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:18:27\",\"extension\":\"docx\",\"order_by\":2,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":5446655,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"SI.docx\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/64beb9aceb93d28ef7e70189.docx\"},{\"id\":99791244,\"identity\":\"e68b0c1a-1b29-4025-b035-31f10ab76774\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:21\",\"extension\":\"xml\",\"order_by\":3,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":154626,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"76382d3723c249a5859bcc47948ed9751enriched.xml\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/bb97a815ffdd74819974f8c3.xml\"},{\"id\":99790646,\"identity\":\"6f014a7d-1856-4a73-97df-9723dff8129f\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:29\",\"extension\":\"png\",\"order_by\":4,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":251528,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage1.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/bea9818ee44d8160449d4981.png\"},{\"id\":99791230,\"identity\":\"520e03ba-150d-479a-a1a9-56a753f54a01\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:20\",\"extension\":\"png\",\"order_by\":5,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":216670,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage2.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/3de06505a70a4de2f6ec45b5.png\"},{\"id\":99791780,\"identity\":\"4a97e94b-6fb8-4427-aa74-61f7073eac6d\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:10:03\",\"extension\":\"png\",\"order_by\":6,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":767834,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage3.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/0cb2a9f1ed3654b10b1faaea.png\"},{\"id\":99516365,\"identity\":\"0fea4b66-1b53-48a6-9b3e-5a3b59cd04bf\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:38\",\"extension\":\"png\",\"order_by\":7,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":181225,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage4.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/cec1305d7f28219f97f0e1c9.png\"},{\"id\":99516372,\"identity\":\"2d79c622-72f2-42e8-a499-b759dbcfac80\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:38\",\"extension\":\"png\",\"order_by\":8,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":309166,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage5.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/f63cc48ca0abdb3d9cc00e8c.png\"},{\"id\":99791655,\"identity\":\"6cab3960-dbd3-4113-8604-af9a2c5aeeb9\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:07:02\",\"extension\":\"png\",\"order_by\":9,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":193667,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage6.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/af3bf6952386f34912106fe8.png\"},{\"id\":99790671,\"identity\":\"28514341-df17-4738-a6a5-7afeb46754b0\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:32\",\"extension\":\"jpeg\",\"order_by\":10,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":820282,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"floatimage7.jpeg\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/fea1944e41d7a68b6a4fa83f.jpeg\"},{\"id\":99791265,\"identity\":\"697402d5-94b3-46d8-9b20-bba51994fab7\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:22\",\"extension\":\"wmf\",\"order_by\":11,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":3400,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image1.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/d7733b93a6036b92460cdac4.wmf\"},{\"id\":99791069,\"identity\":\"7add8924-5030-43ef-b9f3-e2c1ec4d765c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:03\",\"extension\":\"wmf\",\"order_by\":12,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":10194,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image10.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/b2dce86bb46bda4656a78f47.wmf\"},{\"id\":99791067,\"identity\":\"5fd1aca9-564e-4cdb-a601-d46c755d4288\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:03\",\"extension\":\"wmf\",\"order_by\":13,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1738,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image11.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/cca2a34874f9b5d2f712e9b1.wmf\"},{\"id\":99791683,\"identity\":\"13e53487-7283-4026-991e-a55f8f53c335\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:07:46\",\"extension\":\"wmf\",\"order_by\":14,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":3420,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image12.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/d56e4ed02ad3419d948f5bec.wmf\"},{\"id\":99516377,\"identity\":\"b9d746cd-c863-45f7-897c-6d3565777f48\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:38\",\"extension\":\"wmf\",\"order_by\":15,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2908,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image13.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/ad2fb4f096c3f969bad88266.wmf\"},{\"id\":99791247,\"identity\":\"4662e153-5885-40e6-9920-5cfa52cf15e2\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:21\",\"extension\":\"wmf\",\"order_by\":16,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":12650,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image14.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/cb38e274294de63f01ca15fe.wmf\"},{\"id\":99791708,\"identity\":\"a53bc255-0bb1-4391-a3cf-31132046fc0c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:08:54\",\"extension\":\"wmf\",\"order_by\":17,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":12274,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image15.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/566d4fa3fbbfae579f603472.wmf\"},{\"id\":99516381,\"identity\":\"8699304a-4884-4249-af73-af74e60890de\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":18,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":646,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image16.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/00f5d9a6574f16238e406f79.wmf\"},{\"id\":99516391,\"identity\":\"38e7d15a-4640-4da9-890e-267801b33b2d\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":19,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":902,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image17.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/a760210e83faff23a7239824.wmf\"},{\"id\":99791786,\"identity\":\"5e304f71-051c-4028-8ee0-849558d38f82\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:10:18\",\"extension\":\"wmf\",\"order_by\":20,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1620,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image18.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/dd7fdd7f94fde42efdeffeef.wmf\"},{\"id\":99792059,\"identity\":\"6ff63dc1-bac9-42b8-aa60-8a0b1352cdfe\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:13:16\",\"extension\":\"wmf\",\"order_by\":21,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2070,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image19.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/931e129fedf59898ef89c108.wmf\"},{\"id\":99516385,\"identity\":\"47e5857b-152b-46d3-aa05-bdf2788d8834\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":22,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":3496,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image2.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/06dc5ece4dfa680df7b607dc.wmf\"},{\"id\":99516387,\"identity\":\"19ce72bb-50fe-4026-b2c2-2d63889348f9\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":23,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2304,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image20.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/414363cd85cb33c9068367fa.wmf\"},{\"id\":99516393,\"identity\":\"ee27e414-534b-4de7-a603-a08bd5e52301\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":24,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1008,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image21.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/0983d10bc035f912b7709de3.wmf\"},{\"id\":99791274,\"identity\":\"67262d10-c51b-4c9c-9bf5-39bbea281110\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:23\",\"extension\":\"wmf\",\"order_by\":25,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":11610,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image22.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/bb2726c2833b953e20fe3568.wmf\"},{\"id\":99791303,\"identity\":\"308df53c-af9e-4b24-b031-5a170d2f5ceb\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:25\",\"extension\":\"wmf\",\"order_by\":26,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":10334,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image23.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/478a51be240b0c5bf8b4f80c.wmf\"},{\"id\":99790802,\"identity\":\"60ec8dfa-b390-47c3-b3bd-680dec7af5b7\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:43\",\"extension\":\"wmf\",\"order_by\":27,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2494,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image24.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/3d972191587b70e787304e0e.wmf\"},{\"id\":99791278,\"identity\":\"398b2ebc-4270-49f8-a91f-bd64d91f6734\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:23\",\"extension\":\"wmf\",\"order_by\":28,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2886,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image25.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/1056f3d5eeba9c303f0eb21f.wmf\"},{\"id\":99791213,\"identity\":\"cab000c5-a335-48a9-abb7-35f801e1a18e\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:19\",\"extension\":\"wmf\",\"order_by\":29,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2982,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image26.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/4ddd1995f1c01e2063e7f8c3.wmf\"},{\"id\":99791085,\"identity\":\"52f2e417-e782-46e8-a8cc-671f733c3bd7\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:06\",\"extension\":\"wmf\",\"order_by\":30,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2582,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image27.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/1a20097d634a8f5b5d5b4ae4.wmf\"},{\"id\":99516396,\"identity\":\"87c3452b-1cb9-42fb-8b9b-6c153a929722\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":31,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":5892,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image28.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/51370581624f77ffc9add394.wmf\"},{\"id\":99516394,\"identity\":\"56dab7a3-bed9-4638-a9bd-ca207b7c3190\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":32,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":6816,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image29.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/16fe2f3a8e44b428cad8ffec.wmf\"},{\"id\":99516407,\"identity\":\"24de4b1c-9f83-4c9f-8110-e59b9d1a051a\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":33,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":936,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image3.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/ef0af17d2705e3ef4f697f66.wmf\"},{\"id\":99791099,\"identity\":\"3ce2362b-076e-4c21-b94b-a1116b0317b6\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:06\",\"extension\":\"wmf\",\"order_by\":34,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2690,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image30.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/f7e4e139ccd4e4a5e5c97bbd.wmf\"},{\"id\":99516411,\"identity\":\"5f8d6748-c2f3-4f24-b932-2798b0d8d098\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":35,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2284,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image31.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/245ce15b4bb0dca2ccea9328.wmf\"},{\"id\":99790933,\"identity\":\"616a7d90-6952-499d-ae94-c8e75ce0a19c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:52\",\"extension\":\"wmf\",\"order_by\":36,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2282,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image32.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/d29d4b7d038d9c399c2a0ec5.wmf\"},{\"id\":99516415,\"identity\":\"3bbd39bf-b0c1-46a3-96b2-bd0f73c670d3\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"wmf\",\"order_by\":37,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":12412,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image33.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/ae882d5891bf6845275db654.wmf\"},{\"id\":99792060,\"identity\":\"863f868f-1589-437a-a430-8a6c4b5d5206\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:13:17\",\"extension\":\"wmf\",\"order_by\":38,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":818,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image4.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/063bc4c63bbf1dbbf0abf528.wmf\"},{\"id\":99790860,\"identity\":\"b1283ffd-f621-481f-b74f-13c58c393c64\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:47\",\"extension\":\"wmf\",\"order_by\":39,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":830,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image40.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/bddf25c8d3851216ea321b29.wmf\"},{\"id\":99516400,\"identity\":\"b4858921-82a7-4ee4-ac85-a71896fd4dcd\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":40,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1372,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image41.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/6558e9a4b08c527de7fd54c1.wmf\"},{\"id\":99791933,\"identity\":\"ca6ca6ec-e063-40cd-80ca-505b9b412230\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:11:48\",\"extension\":\"wmf\",\"order_by\":41,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1822,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image42.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/3a53948c95dfb2f12727c282.wmf\"},{\"id\":99516414,\"identity\":\"9bd659ac-9162-4296-bd6c-a9e1a09ecc2b\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"wmf\",\"order_by\":42,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2056,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image43.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/cda884699581d9e0099501ab.wmf\"},{\"id\":99792125,\"identity\":\"964a4192-25d3-44a4-93a0-31209cd59d15\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:15:33\",\"extension\":\"wmf\",\"order_by\":43,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1468,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image44.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/72c1149b1aea8fc93aa011a6.wmf\"},{\"id\":99516422,\"identity\":\"adf0bce5-23ab-4316-bcf5-fd655817fe39\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"wmf\",\"order_by\":44,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1918,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image45.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/80d4b4441cc720759c6ce3d5.wmf\"},{\"id\":99790724,\"identity\":\"d72ea5f6-1e93-4ea6-a117-12c82208c228\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:38\",\"extension\":\"wmf\",\"order_by\":45,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":2152,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image46.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/8bc290a8ea48094190140deb.wmf\"},{\"id\":99791326,\"identity\":\"ff12c44d-d166-4e15-bc37-379668298b54\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:29\",\"extension\":\"wmf\",\"order_by\":46,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":488,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image5.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/38a9e788fa92dbfe4602d6f7.wmf\"},{\"id\":99790846,\"identity\":\"a2b07392-9b8b-4001-9b2d-62ce1f106d01\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:45\",\"extension\":\"wmf\",\"order_by\":47,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1024,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image6.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/9dbe3d45a9aaded31fa0adef.wmf\"},{\"id\":99516402,\"identity\":\"91265f32-c716-4ccf-9683-cfcf51f4c92d\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"wmf\",\"order_by\":48,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":3616,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image7.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/8be2fb154d1864b1f8409faa.wmf\"},{\"id\":99516440,\"identity\":\"54e72444-cab8-4d56-93b1-a8102c01b064\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"wmf\",\"order_by\":49,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":630,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image8.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/28687f6de488ec66a2cb228e.wmf\"},{\"id\":99791844,\"identity\":\"4c60a8f1-afe9-4bcf-905d-b6cc2707bdf1\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:11:07\",\"extension\":\"wmf\",\"order_by\":50,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":680,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"image9.wmf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/79c4f00637ecd6e9df707578.wmf\"},{\"id\":99516432,\"identity\":\"47d83c54-b147-4145-9a7f-fc544cc7ebb5\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":51,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":85349,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage1.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/6d84c2c1187e643c95146664.png\"},{\"id\":99516444,\"identity\":\"d9d62817-7719-4235-9b53-16c0abd10896\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":52,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":86223,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage2.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/49e3cf28806347c51ec9bc9b.png\"},{\"id\":99516412,\"identity\":\"362d68e5-cb26-4715-a268-90c285282103\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"png\",\"order_by\":53,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":109946,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage3.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/53d84b109838bb812584dbf7.png\"},{\"id\":99516442,\"identity\":\"5e88d950-5347-452e-a6f3-39cdec92cea9\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":54,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":70185,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage4.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/082e2da3b4e24c43380a4e91.png\"},{\"id\":99516408,\"identity\":\"6c6891b3-3301-44a2-b0e3-d18d4350d2e3\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"png\",\"order_by\":55,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":57778,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage5.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/5fe6743de8145416852ce9a8.png\"},{\"id\":99790852,\"identity\":\"624cb405-0376-4cf1-a92b-d57af775fd89\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:45\",\"extension\":\"png\",\"order_by\":56,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":50753,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage6.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/5f9a62d27f4e196f29208216.png\"},{\"id\":99516405,\"identity\":\"df83a3a2-f42b-4535-ab98-87c850cc86ee\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"png\",\"order_by\":57,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":44409,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlinefloatimage7.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/c7ee630c4463eafbd216ef18.png\"},{\"id\":99516434,\"identity\":\"5080f126-acb3-49b9-a8f5-0b0aa04b686f\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":58,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":415,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage1.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/ff3daa50200ed01c178e9eb9.png\"},{\"id\":99790641,\"identity\":\"e58870c7-1476-48f7-aeed-7c9af73724d9\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:29\",\"extension\":\"png\",\"order_by\":59,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":737,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage10.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/a8b5d7690ea43b00987edbc5.png\"},{\"id\":99516428,\"identity\":\"9a4d73ef-449a-46be-8535-8bfdf89ad572\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":60,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":240,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage11.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/c5df360c7190cf01dabf18ad.png\"},{\"id\":99790913,\"identity\":\"c32b4b8b-417f-49bf-a978-aeb9f3c33103\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:51\",\"extension\":\"png\",\"order_by\":61,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":273,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage12.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/52e946df48db75f957733613.png\"},{\"id\":99516410,\"identity\":\"8728315f-0eee-486d-a1b4-59a5a7035006\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:39\",\"extension\":\"png\",\"order_by\":62,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":263,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage13.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/8874b30b3b228112273f65a8.png\"},{\"id\":99792116,\"identity\":\"b533c3ba-e35e-4e5e-ae1c-08b1a791d76f\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:15:31\",\"extension\":\"png\",\"order_by\":63,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1075,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage14.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/6e6e5e8b44c59357a7b2e69e.png\"},{\"id\":99790749,\"identity\":\"bfe2c477-3632-4bd5-9d8f-1b8d85c8c5e7\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:39\",\"extension\":\"png\",\"order_by\":64,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":904,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage15.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/6fc351be94b8e48aaea9ad09.png\"},{\"id\":99791469,\"identity\":\"dc783944-ea10-45d4-be86-54da84285717\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:57\",\"extension\":\"png\",\"order_by\":65,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":182,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage16.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/6494518c8d455d11e7c50047.png\"},{\"id\":99790905,\"identity\":\"4f893c71-8575-44b1-a2be-291bcf13ea8b\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:50\",\"extension\":\"png\",\"order_by\":66,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":192,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage17.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/bc1b0fcc3466446c49abcd36.png\"},{\"id\":99791052,\"identity\":\"8ca3c6e5-2108-401c-a41f-ea98367c1ce1\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:00\",\"extension\":\"png\",\"order_by\":67,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":205,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage18.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/7e77711535ee81a78b13d4f5.png\"},{\"id\":99791934,\"identity\":\"cccd3119-5f28-42e0-ae2a-99e76d87f403\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:11:48\",\"extension\":\"png\",\"order_by\":68,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":214,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage19.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/6da844f794bc8e9b71b0c8e8.png\"},{\"id\":99516455,\"identity\":\"81bf2b71-2917-4476-90b4-36e4c52cfb36\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:41\",\"extension\":\"png\",\"order_by\":69,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":418,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage2.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/03205ea0e6ef17d8d9d78e0a.png\"},{\"id\":99792135,\"identity\":\"74cb18e8-26c1-4792-9d47-7beaa6a032dc\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:15:33\",\"extension\":\"png\",\"order_by\":70,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":214,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage20.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/a4efe6cb36c5ccbc66eb6077.png\"},{\"id\":99516457,\"identity\":\"03b1252a-cdf7-4ec6-90d4-8e186c0d281f\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:41\",\"extension\":\"png\",\"order_by\":71,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":197,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage21.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/d07015427b8ece267efbedef.png\"},{\"id\":99791962,\"identity\":\"01fdce21-38f4-4efd-a386-39d37af77394\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:11:53\",\"extension\":\"png\",\"order_by\":72,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1244,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage22.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/54f5dc01c1b8d05eb0889f27.png\"},{\"id\":99791238,\"identity\":\"66ebba30-c706-4669-9e33-3ac879f2ae2f\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:21\",\"extension\":\"png\",\"order_by\":73,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1002,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage23.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/c4b4f17993d611e194d5a132.png\"},{\"id\":99516450,\"identity\":\"962ffe2c-907a-4db0-98d5-febe486f634c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":74,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":334,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage24.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/5c109ad7e4f507cfdb20986c.png\"},{\"id\":99791111,\"identity\":\"4e1be3ff-b48b-4fa7-9416-a1da1ca0aabf\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:07\",\"extension\":\"png\",\"order_by\":75,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":377,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage25.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/3fc5f225afa45ffbf2a6cab1.png\"},{\"id\":99791525,\"identity\":\"a6221933-9cf3-4cde-af59-7c9400a6bc50\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:01:07\",\"extension\":\"png\",\"order_by\":76,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":388,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage26.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/65933bb1f33d77536ea21fb0.png\"},{\"id\":99791335,\"identity\":\"34440e3e-a7b8-4cff-bafc-fde9bd2d8174\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:30\",\"extension\":\"png\",\"order_by\":77,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":354,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage27.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/4bad06aa83b8eac0b5503671.png\"},{\"id\":99791515,\"identity\":\"99bb9199-6810-4af2-82e3-39b87b09113c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:00:57\",\"extension\":\"png\",\"order_by\":78,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":491,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage28.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/b6763815d40a095b09de0124.png\"},{\"id\":100356258,\"identity\":\"88bfdf73-0966-43db-85fc-e1b08a0d2b96\",\"added_by\":\"auto\",\"created_at\":\"2026-01-16 06:58:35\",\"extension\":\"png\",\"order_by\":79,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":523,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage29.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/884d83afe3f523cf6e3b963e.png\"},{\"id\":99791095,\"identity\":\"c25f2806-7e74-4b22-9981-108ad1e76c37\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:06\",\"extension\":\"png\",\"order_by\":80,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":187,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage3.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/93f5679fc79aaae50136caec.png\"},{\"id\":99791333,\"identity\":\"a94d3664-c241-47fb-83d5-10664cdb4d4c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:30\",\"extension\":\"png\",\"order_by\":81,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":212,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage30.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/80795568a901147d079f2e13.png\"},{\"id\":99792037,\"identity\":\"9b7fa6ec-0f08-4891-8994-2f0c323bd138\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:12:46\",\"extension\":\"png\",\"order_by\":82,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":327,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage31.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/4a3704b1819e4c4f9ad292a4.png\"},{\"id\":99516452,\"identity\":\"ba429254-7bc4-406b-8c33-09f997a0d65c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":83,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":310,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage32.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/be6805ce1b341fb1c034d396.png\"},{\"id\":99516449,\"identity\":\"76171042-af61-4a4a-a62f-c141cde12ec2\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":84,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":1121,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage33.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/98addcd28f6cd0a9bb038f5d.png\"},{\"id\":99791090,\"identity\":\"e4300d88-22ac-41d2-adee-8debe26f669f\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:06\",\"extension\":\"png\",\"order_by\":85,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":179,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage4.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/0314d964beeffe141f67175c.png\"},{\"id\":99790892,\"identity\":\"ec70e875-1fd3-4401-822f-8c67946866c4\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:58:49\",\"extension\":\"png\",\"order_by\":86,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":179,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage40.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/047bc12247bc166a93e73560.png\"},{\"id\":99791922,\"identity\":\"00a91a93-398e-46f4-9eb9-cbb1becceaec\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:11:46\",\"extension\":\"png\",\"order_by\":87,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":199,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage41.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/a51f67fdbae50406547e5ab1.png\"},{\"id\":99516461,\"identity\":\"8a2b305c-1416-4b5b-8e57-99c157567d1c\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:41\",\"extension\":\"png\",\"order_by\":88,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":208,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage42.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/7b3b4cf1209bddab2af87299.png\"},{\"id\":99516447,\"identity\":\"eb5bcedb-c6b8-457a-b42f-43845482b45b\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":89,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":216,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage43.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/0f9434b3e1e21792f3fee9ba.png\"},{\"id\":99791484,\"identity\":\"4173ea63-1c27-4a47-8b4d-044f2660f920\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:00:22\",\"extension\":\"png\",\"order_by\":90,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":205,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage44.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/14976b6257addf2929cb5821.png\"},{\"id\":99791348,\"identity\":\"da184df4-3bb3-403d-9744-f1022ddd4e45\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:31\",\"extension\":\"png\",\"order_by\":91,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":216,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage45.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/dd32901cc7ca2fb3183a6c17.png\"},{\"id\":99516438,\"identity\":\"ba35382e-67c0-49a2-9992-a955eba96323\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":92,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":223,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage46.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/5a361102dfbfb9b72033cb45.png\"},{\"id\":99516426,\"identity\":\"a15a2459-3ac8-44f3-a7c1-6b5bdc6407e1\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:40\",\"extension\":\"png\",\"order_by\":93,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":180,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage5.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/49855fc9cd09e4660ea13274.png\"},{\"id\":99516465,\"identity\":\"b59e82ab-abb8-4fd6-9b68-b6133806d9e7\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:41\",\"extension\":\"png\",\"order_by\":94,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":193,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage6.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/a94531df11cf62180c7cf065.png\"},{\"id\":99792033,\"identity\":\"91dabdb2-6af4-4082-a767-0ef838063f38\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:12:46\",\"extension\":\"png\",\"order_by\":95,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":438,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage7.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/3c2ed21f719a52229f5d463c.png\"},{\"id\":99516463,\"identity\":\"2573f06e-3259-4953-af6c-2f2c4524f9e9\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:41\",\"extension\":\"png\",\"order_by\":96,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":176,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage8.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/d2c76ac1527f560b391aebf4.png\"},{\"id\":99792092,\"identity\":\"95680cd5-c709-43af-ab69-f2181998f548\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 13:14:33\",\"extension\":\"png\",\"order_by\":97,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":180,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"Onlineimage9.png\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/81c7c81736e3de881f672378.png\"},{\"id\":99516458,\"identity\":\"e3cfbb4b-eb77-413d-90b5-aeca897d6496\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:41\",\"extension\":\"xml\",\"order_by\":98,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":153856,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"76382d3723c249a5859bcc47948ed9751structuring.xml\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/c945168553f6284d845e87e6.xml\"},{\"id\":99791240,\"identity\":\"f22c67f9-5b5c-42d4-95af-682e3c1765c7\",\"added_by\":\"auto\",\"created_at\":\"2026-01-08 12:59:21\",\"extension\":\"html\",\"order_by\":99,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"acdc-reference\",\"size\":163473,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"earlyproof.html\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/e9f78c5db21299bb91facb10.html\"},{\"id\":106809391,\"identity\":\"73957cd1-7c06-48a9-84b7-5041d64d7c4d\",\"added_by\":\"auto\",\"created_at\":\"2026-04-13 16:10:15\",\"extension\":\"pdf\",\"order_by\":1,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"manuscript-pdf\",\"size\":1241283,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"text.pdf\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1_covered_b893e96d-fb56-493e-9e64-a24387065578.pdf\"},{\"id\":99516380,\"identity\":\"9a7bcc76-7c26-45f5-afbc-fe87a826cfbb\",\"added_by\":\"auto\",\"created_at\":\"2026-01-05 10:22:38\",\"extension\":\"docx\",\"order_by\":0,\"title\":\"\",\"display\":\"\",\"copyAsset\":false,\"role\":\"supplement\",\"size\":5446655,\"visible\":true,\"origin\":\"\",\"legend\":\"\",\"description\":\"\",\"filename\":\"SI.docx\",\"url\":\"https://assets-eu.researchsquare.com/files/rs-8429060/v1/32f31b720e95fb2360ce0786.docx\"}],\"financialInterests\":\"No competing interests reported.\",\"formattedTitle\":\"\\u003cp\\u003eSodion Induced Interfacial Polarization and π‒π Synergy Enable Irreversible Dye Adsorption in g‒C\\u003csub\\u003e3\\u003c/sub\\u003eN\\u003csub\\u003e4\\u003c/sub\\u003e Quantum Dot–Embedded Hydrogels\\u003c/p\\u003e\",\"fulltext\":[],\"fulltextSource\":\"\",\"fullText\":\"\",\"funders\":[],\"hasAdminPriorityOnWorkflow\":false,\"hasManuscriptDocX\":false,\"hasOptedInToPreprint\":true,\"hasPassedJournalQc\":\"\",\"hasAnyPriority\":false,\"hideJournal\":false,\"highlight\":\"\",\"institution\":\"\",\"isAcceptedByJournal\":true,\"isAuthorSuppliedPdf\":true,\"isDeskRejected\":\"\",\"isHiddenFromSearch\":false,\"isInQc\":false,\"isInWorkflow\":false,\"isPdf\":true,\"isPdfUpToDate\":true,\"isWithdrawnOrRetracted\":false,\"journal\":{\"display\":true,\"email\":\"info@researchsquare.com\",\"identity\":\"journal-of-polymers-and-the-environment\",\"isNatureJournal\":false,\"hasQc\":true,\"allowDirectSubmit\":false,\"externalIdentity\":\"jooe\",\"sideBox\":\"Learn more about [Journal of Polymers and the Environment](https://www.springer.com/journal/10924)\",\"snPcode\":\"10924\",\"submissionUrl\":\"https://submission.nature.com/new-submission/10924/3\",\"title\":\"Journal of Polymers and the Environment\",\"twitterHandle\":\"\",\"acdcEnabled\":true,\"dfaEnabled\":true,\"editorialSystem\":\"em\",\"reportingPortfolio\":\"Springer Hybrid\",\"inReviewEnabled\":true,\"inReviewRevisionsEnabled\":false},\"keywords\":\"g‒C3N4 quantum dots, Hydrogel, Interfacial polarization, π‒π interaction, Electrostatic adsorption, Irreversible dye retention, Adsorption kinetics\",\"lastPublishedDoi\":\"10.21203/rs.3.rs-8429060/v1\",\"lastPublishedDoiUrl\":\"https://doi.org/10.21203/rs.3.rs-8429060/v1\",\"license\":{\"name\":\"CC BY 4.0\",\"url\":\"https://creativecommons.org/licenses/by/4.0/\"},\"manuscriptAbstract\":\"\\u003cp\\u003eHydrogel-based composites have attracted increasing attention for dye removal owing to their tunable porous networks and excellent recyclability. In this study, two quantum dot/polyacrylamid\\u0026middot;e (PAM) hydrogels, g‒C\\u003csub\\u003e3\\u003c/sub\\u003eN\\u003csub\\u003e4\\u003c/sub\\u003e quantum dot (CNQD/PAM) and TiO\\u003csub\\u003e2\\u003c/sub\\u003e quantum dot (TDQD/PAM), were synthesized and systematically compared in terms of their adsorption\\u0026ndash;desorption behavior toward methylene blue (MB). CNQD/PAM exhibited a significantly higher adsorption capacity, slower desorption rate, and stronger dye retention than TDQD/PAM. Kinetic fitting using a dual-site diffusion\\u0026ndash;adsorption model revealed that CNQD/PAM possesses a greater fraction of strong and irreversible adsorption sites, while both hydrogels exhibit comparable diffusion resistance. Spectroscopic and pH-dependent analyses further demonstrated that the superior performance of CNQD/PAM originates from the synergistic effects of π‒π stacking, hydrogen bonding, and Na\\u003csup\\u003e+\\u003c/sup\\u003e induced electrostatic attraction. These findings elucidate the mechanism by which alkali-metal-modified g‒C\\u003csub\\u003e3\\u003c/sub\\u003eN\\u003csub\\u003e4\\u003c/sub\\u003e enhances dye binding in hydrogel composites and provide valuable insights for designing durable, high-capacity, and recyclable adsorption materials.\\u003c/p\\u003e\",\"manuscriptTitle\":\"Sodion Induced Interfacial Polarization and π‒π Synergy Enable Irreversible Dye Adsorption in g‒C3N4 Quantum Dot–Embedded Hydrogels\",\"msid\":\"\",\"msnumber\":\"\",\"nonDraftVersions\":[{\"code\":1,\"date\":\"2026-01-05 10:22:28\",\"doi\":\"10.21203/rs.3.rs-8429060/v1\",\"editorialEvents\":[{\"type\":\"communityComments\",\"content\":0},{\"type\":\"decision\",\"content\":\"Revision requested\",\"date\":\"2026-01-30T09:11:15+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"editorInvitedReview\",\"content\":\"\",\"date\":\"2026-01-25T10:50:49+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"editorInvitedReview\",\"content\":\"\",\"date\":\"2026-01-13T11:40:06+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"editorInvitedReview\",\"content\":\"\",\"date\":\"2026-01-07T09:28:14+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewerAgreed\",\"content\":\"134935063706791496337616957297890332755\",\"date\":\"2026-01-05T08:00:18+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewerAgreed\",\"content\":\"33377638210492484220026890432880876317\",\"date\":\"2026-01-04T15:49:52+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewerAgreed\",\"content\":\"51676049762455308551899651358220521921\",\"date\":\"2026-01-03T12:00:38+00:00\",\"index\":\"hide\",\"fulltext\":\"\"},{\"type\":\"reviewersInvited\",\"content\":\"\",\"date\":\"2026-01-02T14:13:28+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"editorAssigned\",\"content\":\"\",\"date\":\"2025-12-25T21:11:47+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"checksComplete\",\"content\":\"\",\"date\":\"2025-12-25T21:11:20+00:00\",\"index\":\"\",\"fulltext\":\"\"},{\"type\":\"submitted\",\"content\":\"Journal of Polymers and the Environment\",\"date\":\"2025-12-23T01:28:39+00:00\",\"index\":\"\",\"fulltext\":\"\"}],\"status\":\"published\",\"journal\":{\"display\":true,\"email\":\"info@researchsquare.com\",\"identity\":\"journal-of-polymers-and-the-environment\",\"isNatureJournal\":false,\"hasQc\":true,\"allowDirectSubmit\":false,\"externalIdentity\":\"jooe\",\"sideBox\":\"Learn more about [Journal of Polymers and the Environment](https://www.springer.com/journal/10924)\",\"snPcode\":\"10924\",\"submissionUrl\":\"https://submission.nature.com/new-submission/10924/3\",\"title\":\"Journal of Polymers and the Environment\",\"twitterHandle\":\"\",\"acdcEnabled\":true,\"dfaEnabled\":true,\"editorialSystem\":\"em\",\"reportingPortfolio\":\"Springer Hybrid\",\"inReviewEnabled\":true,\"inReviewRevisionsEnabled\":false}}],\"origin\":\"\",\"ownerIdentity\":\"90bead2a-f00c-48c4-af4e-62a0dd26bba2\",\"owner\":[],\"postedDate\":\"January 5th, 2026\",\"published\":true,\"recentEditorialEvents\":[],\"rejectedJournal\":[],\"revision\":\"\",\"amendment\":\"\",\"status\":\"published-in-journal\",\"subjectAreas\":[],\"tags\":[],\"updatedAt\":\"2026-04-13T16:06:14+00:00\",\"versionOfRecord\":{\"articleIdentity\":\"rs-8429060\",\"link\":\"https://doi.org/10.1007/s10924-026-03807-5\",\"journal\":{\"identity\":\"journal-of-polymers-and-the-environment\",\"isVorOnly\":false,\"title\":\"Journal of Polymers and the Environment\"},\"publishedOn\":\"2026-04-10 15:59:04\",\"publishedOnDateReadable\":\"April 10th, 2026\"},\"versionCreatedAt\":\"2026-01-05 10:22:28\",\"video\":\"\",\"vorDoi\":\"10.1007/s10924-026-03807-5\",\"vorDoiUrl\":\"https://doi.org/10.1007/s10924-026-03807-5\",\"workflowStages\":[]},\"version\":\"v1\",\"identity\":\"rs-8429060\",\"journalConfig\":\"researchsquare\"},\"__N_SSP\":true},\"page\":\"/article/[identity]/[[...version]]\",\"query\":{\"redirect\":\"/article/rs-8429060\",\"identity\":\"rs-8429060\",\"version\":[\"v1\"]},\"buildId\":\"XKTyCvWXoU3ODBz1xrDgd\",\"isFallback\":false,\"isExperimentalCompile\":false,\"dynamicIds\":[84888],\"gssp\":true,\"scriptLoader\":[]}","source_license":"CC-BY-4.0","license_restricted":false}